한국대기환경학회지 (Journal of Korean Society for Atmospheric Environment)

  • 제23권5호
  • /
  • Pages.575-584
  • /
  • 2007
  • /
  • 1598-7132(pISSN)
  • /
  • 2383-5346(eISSN)
한국대기환경학회 (Korean Society for Atmospheric Environment)
권호 표지
DOI QR코드

DOI QR Code

철 프탈로시아닌 유도체에 의한 아민 및 황 화합물의 흡착

Adsorption of Amine and Sulfur Compounds by Iron Phthalocyanine Derivatives

  • 이정세 (울산대학교 생명화학공학부) ;
  • 박진도 (울산과학대학 환경생활화학과) ;
  • 이학성 (울산대학교 생명화학공학부)
  • Lee, Jeong-Se (School of Chemical Engineering and Bioengineering, University of Ulsan) ;
  • Park, Jin-Do (Department of Environmental & Life Chemistry, Ulsan College) ;
  • Lee, Hak-Sung (School of Chemical Engineering and Bioengineering, University of Ulsan)
  • 발행 : 2007.10.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The adsorption capability of iron phthalocyanine derivatives were investigated by means of X-ray diffractometor (XRD), IR (infrared) spectroscopy, scanning electron microscopy (SEM) and temperature programmed desorption (TPD). According to TPD results, iron phthalocyanine derivatives showed two desorption peaks at low temperature ($100{\sim}150^{\circ}C$) and high temperature ($350{\sim}400^{\circ}C$) indicating that there were two kinds of acidities. Tetracarboxylic iron phthalocyanine (Fe-TCPC) have a stronger desorption peak (chemical adsorption) at the high temperature and a weaker desorption peak (physical adsorption) at the low temperature than iron phthalocyanine (Fe-PC). The specific surface areas of Fe-TCPC and Fe-PC were $26.46\;m^2/g\;and\;11.77\;m^2/g$, respectively. The pore volumes of Fe-TCPC and Fe-PC were $0.14\;cm^3/g\;and\;0.06\;cm^3/g$, respectively. The adsorption capability of triethyl amine calculated by breakthrough curve at 220 ppm of equilibrium concentration was 29.2 mmoL/g for Fe-TCPC and 0.8 mmoL/g for Fe-PC. The removal efficiency of dimethyl sulfide of Fe-TCPC and Fe-PC in batch experiment of 225 ppm of initial concentration were 44.9% and 28.9%, respectively. The removal efficiency of trimethyl amine of Fe-TCPC and Fe-PC in batch experiment of 118 ppm of initial concentration were approximately 100.0% and 33.9%, respectively.

키워드

참고문헌

  1. 김공수, 이영우, 김영준(1988) Co(II)-프탈로시아닌이 결합된 아크릴로니트릴-아크릴산공중합체의 합성 및 촉매특성, 산업과학기술연구소, 2(2), 31-40
  2. 김공수, 전용철, 이영우, 이상호(1989) 고분자에 결합된 금속프탈로시아닌의 과산화수소수 분해반응에 대한 촉매활성, 대한화학회지, 33(6), 662-668
  3. 김대중, 서성규, 김상채(2005) 산으로 개질된 활성탄을 이용한 메틸 메르캅탄 악취물질 제거, 한국대기환경학회지, 21(2), 155-160
  4. 심춘희, 이우근(2005) 질산을 이용한 Fly Ash 흡착제의 표면 활성화에 따른 VOCs 흡착 특성의 변화, 한국대기환경학회지, 21(4), 471-471
  5. 이민재, 남석우, 이화영, 이현구, 성벽파정(1987) IR 및 TPD기법을 이용한 불균일계 촉매의 특성 연구, 한국화학공학회지, 25(1), 71-80
  6. 이정세, 이학성(2007) 분쇄방법에 따른 구리 프탈로시아닌 입자크기 및 결정구조 변화, 한국공업화학회지, 18(1), 41-47
  7. 조동련, 최창남, 김현진, 김애경(1999) 금속 프탈로시아닌 유도체 합성에 의한 촉매기능성 소취제의 제조, 한국섬유공학회지, 36(12), 943-948
  8. 최창남, 홍성학(1996) 소취기능의 원리와 섬유에의 응용, 한국섬유공학회지, 33(12), 1164-1171
  9. Choe, J.W. and C.S. Lee (2004) FTIR and TPD spectroscopic studies of the catalytic hydrodeoxygenation reation of furan, J. Ind. Eng. Chem., 10, 239-246
  10. Cullity, B.D. (1978) Elements of X-ray diffraction, Addison Wesley, 284-285
  11. Girenko, E.G., S.A. Borisenkova, and O.L. Kaliya (2002) Oxidation of ascorbic acid in the presence of phthalocyanine metal complexes. Chemical aspects of catalytic anticancer therapy. 1. Catalysis of oxidation by cobalt octacarboxyphthalocyanine, Russian Chemical Bulletin, 51(7), 1231-1236 https://doi.org/10.1023/A:1020900529609
  12. Herbst, W. and K. Hunger (1993) Industrial Organic Pigments, VCH, New York, 418-420
  13. Kitamura, T., K. Kanai, T. Yamaoka, K. Sato, and K. Toyofuku (1990) Hydrophilic treatment of organic photoconductive layer by surface photografting polymerization, Journal of Imaging Science, 34(6), 230-233
  14. Lee, Y., C. Hsiao, and R. Hsiao (2004) Annealing effects on the gas sensing properties of copper phthalocyanine films, Thin Solid Films, 468, 280-286 https://doi.org/10.1016/j.tsf.2004.04.060
  15. McKewon, N.B. (1998) Phthalocyanine materials synthesis, structure and function, Cambridge University Press, 12-31
  16. Shirai, H. and T. Yokozeki (1985) Deodorizing activity and effect of deodorizing fibers, Fragrance Journal, 13, 83-91
  17. Tadros, T.F. (1987) Solid-Liquid Dispersion, Academic Press, London, 186-191