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산소부화 압축착화기관을 이용한 메탄으로부터 수소 생산

Hydrogen Gas Production from Methane Reforming Using Oxygen Enriched Compression Ignition Engine

  • 임문섭 (조선대학교 환경공학부.BK21 바이오가스기반수소생산 사업팀) ;
  • 홍성인 (조선대학교 기계공학과) ;
  • 홍명석 (조선대학교 기계공학과) ;
  • 전영남 (조선대학교 환경공학부.BK21 바이오가스기반수소생산 사업팀)
  • Lim, Mun-Sup (BK21 Team for Hydrogen Production.Department of Environmental Engineering, Chosun University) ;
  • Hong, Sung-In (Department of Mechanical Engineering, Chosun University) ;
  • Hong, Myung-Seok (Department of Mechanical Engineering, Chosun University) ;
  • Chun, Young-Nam (BK21 Team for Hydrogen Production.Department of Environmental Engineering, Chosun University)
  • 발행 : 2007.10.31

초록

The purpose of this paper is to investigate the reforming characteristics and maximum operating condition for the hydrogen production by methane reforming using the compression ignition engine induced partial oxidation. An dedicated compression engine used for methane reforming was decided operating range. The partial oxidation reforming was investigated with oxygen enrichment which can improve hydrogen production, compared to general reforming. Parametric screening studies were achieved as $O_2/CH_4$ ratio, total flow rate, and intake temperature. When the variations of $O_2/CH_4$ ratio, total flow rate, and intake temperature were 1.24, 208.4 L/min, and $400^{\circ}C$, respectively, the maximum operating conditions were produced hydrogen and carbon monoxide. Under the condition mentioned above, synthetic gas were $H_2\;22.77{\sim}29.22%,\;CO\;21.11{\sim}23.59%$.

키워드

참고문헌

  1. 곽지현, 전충환, 장영준 (2004) 산소부화공기가 동축 비예혼합 제트의 연소특성에 미치는 영향(I), 대한기계학회논문집 B권, 28(2), 160-166
  2. 전영남, 김성천, 송형운 (2005) 고온플라즈마 촉매 개질 특성연구, 한국대기환경학회 2005년 추계학술대회논문집, 245-247
  3. 전영남, 송형운, 김성천, 임문섭 (2006) Glidarc 개질기에 개질 특성 및 경제성, 한국대기환경학회 2006년 추계학술대회논문집, 496-497
  4. Assanis, D.N., R.B. Poola, R. Sekar, and G.R. Cataldi (2001) Study of using oxygen-enriched combustion air for locomotive diesel engines, Journal of Engineering for Gas Turbines and Power, 123, 157-166 https://doi.org/10.1115/1.1290590
  5. Beckhaus, P., A. Heinzel, J. Mathiak, and J. Roes (2004) Dynamic of $H_2$ production by steam reforming, J. Power Sources, 127, 294-299 https://doi.org/10.1016/j.jpowsour.2003.09.026
  6. Bharadwaj, S.S. and L.D. Schmidt (1995) Catalytic partial oxidation of natural gas to syngas, Fuel Processing Technology, 42, 109-127 https://doi.org/10.1016/0378-3820(94)00098-E
  7. Bromberg, L., A. Rabinovich, N. Alexeev, and D.R. Cohn (1999) Plasma reforming of diesel fuel, PSFC/JA-99-4
  8. Karim, G.A. and N.P.W. Moore (1963) The production of synthesis gas and power in a compression ignition engine, Journal of the Institute of Fuel, 98-105
  9. Lutz, A.E., R.W. Bradshaw, L. Bromberg, and A. Rabinovich (2004) Thermodynamic analysis of hydrogen production by partial oxidation reforming, Int. J. Hydrogen Energy, 29, 809-816 https://doi.org/10.1016/j.ijhydene.2003.09.015
  10. Wang, S.G., Y.W. Li, J.X. Lu, M.Y. He, and H. Jiao (2004) A detailed mechanism of thermal $CO_2$ reforming of $CH_4$, J. Molecular Structure, 673, 181-189 https://doi.org/10.1016/j.theochem.2003.12.013
  11. Zhu, J., D. Zhang and K.D. King (2001) Reforming of $CH_4$ by partial oxidation: thermodynamic and kinetic analyses, Fuel, 80, 899-905 https://doi.org/10.1016/S0016-2361(00)00165-4