Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Highly Selective Fluorescent Signaling for Al3+ in Bispyrenyl Polyether

  • Kim, Hyun-Jung (Department of Chemistry, Institute of Nanosensor & Biotechnology, Dankook University) ;
  • Kim, Su-Ho (Department of Chemistry, Institute of Nanosensor & Biotechnology, Dankook University) ;
  • Quang, Duong Tuan (Department of Chemistry, Institute of Nanosensor & Biotechnology, Dankook University) ;
  • Kim, Ja-Hyung (Department of Chemistry, Institute of Nanosensor & Biotechnology, Dankook University) ;
  • Suh, Il-Hwan (Department of Chemistry, Korea University) ;
  • Kim, Jong-Seung (Department of Chemistry, Institute of Nanosensor & Biotechnology, Dankook University)
  • Published : 2007.05.20
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Abstract

A series of bispyrenyl-polyether have been synthesized and investigated as a fluorescent chemosensor for metal ions. The results showed that bispyrenyl-polyether system is selective towards Al3+ ion over other ions tested. In free ligand, excited at 343 nm, it displays a strong excimer emission at around 475 nm with a weak monomer emission at 375 nm. A ratiometry of monomer (375 nm) increase and excimer (475 nm) quenching was shown only when Al3+ ion is bound to ligand, because two facing pyrene groups form a less efficient overlap of π?π stacking compared with that of free ligand.

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