Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Resolution of a Multi-Step Electron Transfer Reaction by Time Resolved Impedance Measurements: Sulfur Reduction in Nonaqueous Media

  • Park, Jin-Bum (Department of Chemistry and Center for Integrated Molecular Systems, Pohang University of Science and Technology) ;
  • Chang, Byoung-Yong (Department of Chemistry and Center for Integrated Molecular Systems, Pohang University of Science and Technology) ;
  • Yoo, Jung-Suk (Department of Chemistry and Center for Integrated Molecular Systems) ;
  • Hong, Sung-Young (Department of Chemistry and Center for Integrated Molecular Systems, Pohang University of Science and Technology) ;
  • Park, Su-Moon (Department of Chemistry and Center for Integrated Molecular Systems, Pohang University of Science and Technology)
  • Published : 2007.09.20
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Abstract

The first reduction peak of the cyclic voltammogram (CV) for sulfur reduction in dimethyl sulfoxide has been studied using time resolved Fourier transform electrochemical impedance spectroscopic (FTEIS) analysis of small potential step chronoamperometric currents. The FTEIS analysis results reveal that the impedance signals obtained during short potential steps can be resolved into electron transfer reactions of two different time constants in a high frequency region. The FTEIS method provides snap shots of impedance profiles during an earlier phase of the reaction, leading to time resolved EIS measurements. Our results obtained by the FTEIS analysis are consistent with a series of electron transfer and chemical equilibrium steps of a complex reaction, making up an ECE (electrochemical-chemical-electrochemical) mechanism postulated from the results of computer simulation.

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