Bulletin of the Korean Chemical Society

  • 제28권8호
  • /
  • Pages.1375-1382
  • /
  • 2007
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Determination of Cadmium(II) and Copper(II) by Flame Atomic Absorption Spectrometry after Preconcentration on Column with Pulverized Amberlite XAD-4 with Bismuthiol I

  • 발행 : 2007.08.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

A column preconcentration method with pulverized Amberlite XAD-4 loaded with bismuthiol I (BI) has been developed for the determination of trace Cd(II) and Cu(II) in various real samples by flame atomic absorption spectrophotometry. Various experimental conditions, such as the size of XAD-4, adsorption flow rate, amount of bismuthiol I, stirring time for adsorbing bismuthiol I on XAD-4, pH of sample solution, amount of XAD-4- BI, desorption solvent, and desorption flow rate, were optimized. Also, the adsorption capacity and the adsorption rate of Cd(II) and Cu(II) on XAD-4-BI were investigated. The interfering effects of various concomitant ions were investigated, Bi(III), Sn(II) and Fe(III) were found to affect the determination. But the interference by these ions was completely eliminated by adjusting the amount of XAD-4-BI resin to 0.70 g, although the adsorption flow rate was slower. For Cd(II) our proposed technique obtained a dynamic range of 0.5-40 ng mL-1, a correlation coefficient (R2) of 0.9913, and a detection limit of 0.3 ng mL-1. For Cu(II), the corresponding values were 2.0-120 ng mL-1, 0.9921 and 1.02 ng mL-1. To validate this proposed technique, the aqueous samples (stream water, reservoir water, tap water and wastewater), the diluted brass sample and the plastic sample, as real samples, were used. Recovery yields of 91-103% were obtained. These measured data were not different from ICP-MS data at 95% confidence level. Our proposed method was also validated using rice flour CRM (normal, fortified) samples. From the results of our experiment, we found that the technique we present here can be applied to the determination of Cd(II) and Cu(II) in various real samples.

키워드

참고문헌

  1. Sawyer, C. N.; McCarty, P. L.; Parkin, G. F. Chemistry for Environmental Engineering, 4th ed.; McGraw-Hill: New York, U. S. A., 1966; p 634
  2. Di, J.: Wu, Y.; Ma, Y. Spectrochim. Acta A 2005, 61, 937 https://doi.org/10.1016/j.saa.2004.04.021
  3. Yaman, M.; Akdeniz, I. Anal. Sci. 2004, 20, 1363 https://doi.org/10.2116/analsci.20.1363
  4. Cabon, J. Y. Spectrochim, Acta B 2002, 57, 939 https://doi.org/10.1016/S0584-8547(02)00025-3
  5. Karami, H.; Mousavi, M. F.; Yamini, Y.; Shamsipur, M. Anal. Chim. Acta 2004, 509, 89 https://doi.org/10.1016/j.aca.2003.12.022
  6. Li, P.; Jiang, S. Anal. Chim. Acta 2003, 495, 143 https://doi.org/10.1016/S0003-2670(03)00874-2
  7. Brainina, K. Z.; Stozhko, N. Y.; Belysheva, G. M.; Inzhevatova, O. V.; Kolyadina, L. I.; Cremisini, C.; Galletti, M. Anal. Chim. Acta 2004, 514, 227 https://doi.org/10.1016/j.aca.2004.03.047
  8. Lu, C.; Lin, J.; Huie, C. W.; Yamada, M. Anal. Sci. 2003, 19, 557 https://doi.org/10.2116/analsci.19.557
  9. Abbas, M. N.; Zahran, E. J. Electroanalytical Chem. 2005, 576, 205 https://doi.org/10.1016/j.jelechem.2004.10.017
  10. Kim, H.; Choi, H. Talanta 2001, 55, 163 https://doi.org/10.1016/S0039-9140(01)00405-2
  11. El-Hasani, S. R.; Al-Dhaheri, S. M.; El-Maazawi, M. S.; Kamal, M. M. Water Sci. Technol. 1999, 40, 67
  12. Chayama, K.; Sekido, E. Anal. Chim. Acta 1991, 248, 511 https://doi.org/10.1016/S0003-2670(00)84669-3
  13. Ferreira, S. L. C.; de Brito, C. F. Anal. Sci. 1999, 15, 189 https://doi.org/10.2116/analsci.15.189
  14. Daorattanachai, P.; Unob, F.; Imyim, A. Talanta 2005, 67, 59 https://doi.org/10.1016/j.talanta.2005.02.006
  15. Martins, A. O.; da Silva, E. L.; Carasek, E.; Gonçalves, N. S.; Laranjeira, M. C. M.; de Favere, V. T. Anal. Chim. Acta 2004, 521, 157 https://doi.org/10.1016/j.aca.2004.06.033
  16. Kim, Y. S.; In, G.; Choi, J. M. Bull. Korean Chem. Soc. 2006, 27, 1557 https://doi.org/10.5012/bkcs.2006.27.10.1557
  17. Pourreza, N.; Mousavi, H. Z. Anal. Chim. Acta 2004, 503, 279 https://doi.org/10.1016/j.aca.2003.10.024
  18. Zhang, S.; Lu, A.; Han, F.; Shan, X. Anal. Sci. 2005, 21, 651 https://doi.org/10.2116/analsci.21.651
  19. Yin, J.; Jiang, Z.; Chang, G.; Hu, B. Anal. Chim. Acta 2005, 540, 333 https://doi.org/10.1016/j.aca.2005.03.045
  20. Anthemidis, A. N.; Zachariadis, G. A.; Stratis, J. A. Talanta 2002, 58, 831 https://doi.org/10.1016/S0039-9140(02)00373-9
  21. Baytak, S.; Turker, A. R. Microchim. Acta 2005, 149, 109 https://doi.org/10.1007/s00604-004-0294-3
  22. Lemos, V. A.; Baliza, P. X. Talanta 2005, 67, 564 https://doi.org/10.1016/j.talanta.2005.03.012
  23. Ramesh, A.; Mohan, K. R.; Seshaiah, K. Talanta 2002, 57, 243 https://doi.org/10.1016/S0039-9140(02)00033-4
  24. Prabhakaran, D.; Subramanian, M. S. Anal. Bioanal. Chem. 2004, 379, 519 https://doi.org/10.1007/s00216-004-2600-7
  25. Kumar, M.; Rathore, D. P. S.; Singh, A. K. Talanta 2000, 51, 1187 https://doi.org/10.1016/S0039-9140(00)00295-2
  26. Tewari, P. K.; Singh, A. K. Talanta 2001, 53, 823 https://doi.org/10.1016/S0039-9140(00)00572-5
  27. Zhaoyi, X.; Quanxing, Z.; Changlong, W.; Liansheng, W. Chemosphere 1997, 35, 2269 https://doi.org/10.1016/S0045-6535(97)00305-6
  28. Skoog, D. A.; Holler, F. J.; Nieman, T. A. Principles of Instrumental Analysis, 5th ed.; Saunders College Publishing: Philadelphia, U. S. A., 1998; p 13
  29. Venkatesh, G.; Jain, A. K.; Singh, A. K. Microchim. Acta 2005, 149, 213 https://doi.org/10.1007/s00604-005-0320-0
  30. Hiraide, M.; Uchitomi, K. Anal. Sci. 1999, 15, 1051 https://doi.org/10.2116/analsci.15.1051
  31. Masi, A. N.; Olsina, R. A. Fresenius. J. Anal. Chem. 1997, 357, 65 https://doi.org/10.1007/s002160050112
  32. King, J. N.; Fritz, J. S. Anal. Chem. 1985, 57, 1016 https://doi.org/10.1021/ac00283a012
  33. Liu, Y.; Chang, X.; Wang, S.; Guo, Y.; Din, B.; Meng, S. Talanta 2004, 64, 160 https://doi.org/10.1016/j.talanta.2004.02.002

피인용 문헌

  1. Determination of Trace Copper with Sulfophenylazo Rhodanine by Catalytic Dynamic Spectrofluorimetry vol.710, pp.1662-8985, 2013, https://doi.org/10.4028/www.scientific.net/AMR.710.112
  2. Atomic spectrometry update. Environmental analysis vol.24, pp.2, 2009, https://doi.org/10.1039/b821579k