Bulletin of the Korean Chemical Society

  • 제28권9호
  • /
  • Pages.1567-1572
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  • 2007
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis and Properties of Pyrrolidinium and Piperidinium Bis(trifluoromethanesulfonyl)imide Ionic Liquids with Allyl Substituents

  • Yim, Tae-Eun (Department of Chemical and Biological Engineering, Research Center for Energy Conversion & Storage, Seoul National University) ;
  • Lee, Hyun-Yeong (Department of Chemical and Biological Engineering, Research Center for Energy Conversion & Storage, Seoul National University) ;
  • Kim, Hyo-Jin (Department of Chemical and Biological Engineering, Research Center for Energy Conversion & Storage, Seoul National University) ;
  • Mun, Jun-Young (Department of Chemical and Biological Engineering, Research Center for Energy Conversion & Storage, Seoul National University) ;
  • Kim, Sang-Mi (Department of Chemical and Biological Engineering, Research Center for Energy Conversion & Storage, Seoul National University) ;
  • Oh, Seung-M. (Department of Chemical and Biological Engineering, Research Center for Energy Conversion & Storage, Seoul National University) ;
  • Kim, Young-Gyu (Department of Chemical and Biological Engineering, Research Center for Energy Conversion & Storage, Seoul National University)
  • 발행 : 2007.09.20
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초록

New pyrrolidinium and piperidinium bis(trifluoromethanesulfonyl)imide (TFSI) ionic liquids (ILs) having allyl substituents were synthesized and characterized. All of them are liquid at room temperature and stable up to 300 oC. The pyrrolidinium-based ILs showed better conductivities and lower viscosities than the corresponding piperidinium-based ILs. Among them, 1-allyl-1-methylpyrrolidinium TFSI showed the lowest viscosity of 52 cP, the highest conductivity of 5.7 mS cm?1, and the most negative cathodic voltage window of ?3.2 V (vs. Fc/Fc+) on a platinum electrode, which are the improved results compared to the corresponding analogue having a saturated substituent, 1-methyl-1-propylpyrrolidinium TFSI.

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