Heme proton resonances assignments based on nuclear Overhauser effect

  • Li, Chun-Ri (Department of Chemistry and Centre for Innovative Bio.physio sensor Technology, Pusan National University) ;
  • Kim, So-Sun (Department of Chemistry and Centre for Innovative Bio.physio sensor Technology, Pusan National University) ;
  • Lu, Ming (Department of Chemistry and Centre for Innovative Bio.physio sensor Technology, Pusan National University) ;
  • Park, Jang-Su (Department of Chemistry and Centre for Innovative Bio.physio sensor Technology, Pusan National University)
  • Published : 2007.06.20

Abstract

NMR signals of two hemes were assigned to particular hemes in the crystal structures by nuclear Overhauser effect experiments. The results showed that the hemes with the highest and lowest redox potentials in the one-electron reduction process correspond to the hemes I and IV in the crystal structure.

Keywords