A Study on the Effect of Storing Temperature and Humidity upon the Self Life of Propellant KM30Al

추진제 KM30Al의 저장 온도/습도와 저장수명과 관계 고찰

  • Published : 2006.03.01

Abstract

A propellant mainly consisting of nitric ester including nitrocellulose and nitroglycerine is characteristic of being decomposed naturally. And this phenomenon is known as being affected mostly by its storing temperature and humidity. In this research, the effect of storing temperature and humidity on self life has been studied by measuring the contained quantity of residual stabilizer of propellant KM30Al, which are parts of 155MM propelling charge K676 and K677; the method for the measurement is acceleration aging test, and decomposition reaction equation, Eyring Equation and Berthlot Equation were used for the calculation. As result of this study, it was found that the storing temperature influenced seven times as large as the storing humidity upon the self life of the propellant KM30Al, Furthermore, especially in the high temperature region, the storing temperature had a dominant effect on the self life.

Keywords

References

  1. 윤근식, 고석일, 유승곤 '단기추진제 저장수명에 미치는 안정제(DPA, CaCO3) 첨가의 효과', 한국군사과학기술학회, 제6권 제2호(통권 제13호), 2003. 7, p.9-19
  2. Tadeusz Urbanski, 'Chemistry and Technology of Explosives', VOL. Ill, PWN-Polish Scientific Publishers, 1967
  3. 조연식, '복기 추진제의 안정제 경시 변화에 관한 연구', 국방과학연구소, 1989
  4. V. R. Pai Vemeker, K. Kishore, and C. B. V. Subhas, 'Mechanism of Thermal Decomposition of Double Base Propellants', Propellants, Explosives, Pyrotechnics 8, 1983
  5. 박병찬, 'KM67 추진장약의 변질특성과 변질 추진장약의 경제적 처리방안에 대한 연구', 1991
  6. Jean Quinchon, Jean Transcahant 'Nitrot.ellulose', ELLIS HORWOOD, 1986
  7. B. R. Bixon, 'Lifetime Prediction for Single Base Propellant Based on the Eyring Equation', 1991, p.233-239
  8. Gilbert W. Castellan, 'Physical Chemistry', Addison-Wesley, 1991
  9. KDS1320-3011, '추진제, KM30A1, 155MM 추진장약 K676용', 1999
  10. KDS1320-30l2, '추진제, KM30A1, 155MM 추진장약 K677용' 1999
  11. 조기홍, 장일호 '추진장약 K676 및 K677 저장 온도가 저장수명에 미치는 영향', 한국군사과학기술학회, 제8권 제1호(통권 제20호), 2005. 9, p. 14-24