DOI QR코드

DOI QR Code

수중 스트리머 방전용 플라즈마 반응기 구조에서 수소발생 특성

The Characteristic of Hydrogen Generation on the Structure of Plasma Reactor Using the Streamer Discharge in the Water

  • 박재윤 (경남대학교 전자전기공학과) ;
  • 김종석 (경남대학교 플라즈마응용 연구실)
  • 발행 : 2006.05.31

초록

본 논문에서는$CO_2$를 발생시키지 않고 물로부터 직접 수소를 제조하기 위하여 비열플라즈마를 이용하였다. 다중침-평판형(Multineedle-plate electrode geometry reacto: MPER)과 단일침-평판형(Needle-plate electrode geometry reactor: NPER) 두종류의 수소제조 반응기를 설계 제작하여 수소 발생에 미치는 영향에 대하여 실험하였다. 수소발생을 높이기 위해서는 강한 아크성 스트리머 방전 발생과 효과적인 수표면 방전을 위한 수표면 조건을 고려해야만 된다.

The effect of arc like streamer discharge is investigated on the hydrogen generation using the multineedle-plate electrode geometry plasma realtor(MPER) and the needle-plate electrode geometry plasma reactor(NPER). In order to restrict waves at the water surface when the high voltage applied, two kinds of the insulator such as the rectangular mesh or the hole mesh type are installed under the water surface. The discharge assistant of the two type(the saw type and the $TiO_2$ pellet type) was placed under the water surface to investigate the effect of the water surface conditions. The experimental results are compared in case of the reactor with and without the discharge assistant on the water surface.

키워드

참고문헌

  1. Mi-Sun Kim, '광 생물학적 물 분해 및 CO2 고정화에 의한 수소생산', J. of the Korean Hydrogen Energy Society Vol.12. No.1, 2001
  2. Shigeru Futamura, 'Hydrogen Generation From Water, Methane, and Methanol With Nonthermal Plasma', IEEE Transactions on Industry applications Vol. 39. No.2, 2003
  3. 한국화학공학회 著, '에너지공학', 교보문고, pp. 454 - 471 (1996)
  4. N. Nagai, M. Takeuchi et al., 'Existence of optimum space between electrodes on hydrogen production by water electrolysis' J. Hydrogen Energy, Vol. 28, No. 1, 35-41, 2003 https://doi.org/10.1016/S0360-3199(02)00027-7
  5. Tai Kyu Lee, 'Photocatalytic water splitting for hydrogen production,'J. Korean Hydrogen Energy Society, Vol. 11, No. 4, 23-27, 2000
  6. Sang-Gi Lee, Ho-In Lee, 'The Effect of alkali cationic ion for generating hydrogen gas over Pt/TiO2 such as photo-catalyst' J. Korean Industrial and Engineering Chemistry, Vol. 8, No. 3, 142-146, 1991
  7. Li Y, Lu G, Li S 'Photocatalytic production of hydrogen in single component and mixture systems of electron donors and monitoring adsorption of donors by in situ infrared spectrosopy.' Chemosphere 2003; 52 (5): 843-50 https://doi.org/10.1016/S0045-6535(03)00297-2
  8. Kida T. Guan GQ, Yamada N, Ma TL, Kimura K, Yoshida A 'Hydrogen production from sewage sludge solubilized in hot-compressed water using photocatalyst under light irradiation' International Journal Hydrogen Energy 2004; 29 (3): 269 -74 https://doi.org/10.1016/j.ijhydene.2003.08.007
  9. Costas Tsouris, 'A Pulseless Corona- Discharge Process for the Oxidation of Organic Compounds in Water', American Chemical Society, 2000, 39, 4408-4414
  10. J.S. Chang, P.C. Looy and K. Urashima, 'Pulsed Arc Discharge in water: Mechanism of Current Conduction and Pressure Wave Formations', IEEE, 0-7803-6413-9/00
  11. G.J. Kang and W.M. Lee, 'Polarity Dependence of Electrical Discharge across Water-Vapor Interface' J. of the Korean Hydrogen Energy Society, pp. 155-160, 1997
  12. H. Kabashima, H. Einaga, and S. Futamura, 'Hydrogen Generation From Water, Methane, and Methanol With Nonthermal Plasma,'IEEE Trans. Indus. Appl., Vol. 39, No. 2, 340-345, 2003 https://doi.org/10.1109/TIA.2003.808968
  13. G. Taylor, 'Disintegration of water drops in an electric field,' proc. R. S. Lond. A, Math. Phys. Sci., Vol. 280, pp. 383-397, Aug. 1964