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The Effect of Chemical Vapor Infiltrated SiC Whiskers on the Change in the Pore Structure of a Porous SiC Body

  • Joo, Byoung-In (Department of Ceramic Engineering, Yonsei University) ;
  • Park, Won-Soon (Department of Ceramic Engineering, Yonsei University) ;
  • Choi, Doo-Jin (Department of Ceramic Engineering, Yonsei University) ;
  • Kim, Hai-Doo (Department of Materials Engineering, Korea Institute of Machinery and Materials)
  • Published : 2006.04.01

Abstract

In this study, SiC whiskers were grown on a porous SiC diesel particulate filter for nanoparticle filtering. To grow the whiskers at the inner pore without closing the pores, we used chemical vapor infiltration with a solution source and a dilute. As the deposition time increased, the whiskers grew and formed a network structure. After 180 min of deposition, the mean diameter of the whiskers was 174 nm and the compressive strength was 58.4 MPa. The pores shrank from $10{\mu}m\;to\;0.4{\mu}m$ and, because the whiskers filed the inner pores, the gradient of permeability decreased as the deposition time increased. However, by using the network structure of whiskers deposited for 120 min and 180 min, we obtained a diesel particulate filter with pores of $0.98{\mu}m\;and\;0.4{\mu}m$, respectively. Furthermore, the filter shows better permeability than a porous body with pores of $1{\mu}m$. In short, by filtering the nanoparticulate materials, the network structure of whiskers improves the strength, reduces the pore size and minimizes the permeability drop.

Keywords

References

  1. H. K. Lonsdate, 'The Growth of Membrane Technology,' J. Membr. Sci., 10 [81] 543-64 (1985)
  2. S. L. Cook and P. J. Richards, 'An Approach Towards Risk Assessment for the Use of a Synergistic Metallic Diesel Particulate Filter (DPF) Regeneration Additive,' Atmos. Environ., 36 [18] 2955-64 (2002) https://doi.org/10.1016/S1352-2310(02)00239-X
  3. J. H. Lee, 'Vehicle Standard Balance World Forum and Development and Popularization Plan of Japanese Low Emission Car,' Auto J., 23 [6] 48-51 (2001)
  4. Y. M. Jo, R. B. Hutchison, and J. A. Raper, 'Characterization of Ceramic Composite Membrane Filters for Hot Gas Cleaning,' Powder Tech., 91 [1] 55-62 (1997) https://doi.org/10.1016/S0032-5910(96)03246-9
  5. T. Fukasawa, Y. Goto, and M. Kato, 'Fracture Behavior of SiC Whisker/$Si_3N_4$ Multi-Layered Composites,' J. Mater. Sci. Lett., 16 [17] 1423-25 (1997) https://doi.org/10.1023/A:1018521713334
  6. H. S. Ahn and D. J. Choi, 'Fabrication of Silicon Carbide Whiskers and Whisker-Containing Composite Coatings without Using a Metallic Catalyst,' Surf. Coat. Tech., 154 276-81 (2002) https://doi.org/10.1016/S0257-8972(02)00009-9
  7. G. E. Youngblood, D. J. Senor, R. H. Jones, and S. Graham, 'The Transverse Thermal Conductivity of 2D-$SiC_f$/SiC Composites,' Compos. Sci. Tech., 62 [9] 1127-39 (2002) https://doi.org/10.1016/S0266-3538(02)00069-6
  8. D. C. Lim, H. S. Ahn, D. J. Choi, C. H. Wang, and H. Tomokage, 'The Filed Emission Properties of Silicon Carbide Whiskers Grown by CVD,' Surf. Coat. Tech., 168 [1] 37-42 (2003) https://doi.org/10.1016/S0257-8972(02)00924-6
  9. F. Loumagne, F. Langlais, and R. Naslain, 'Reactional Mechanisms of the Chemical Vapour Deposition of SiCBased Ceramics from $CH_3SiCl_3/H_2 $Gas Precursor,' J. Cryst. Growth, 155 [3] 205-13 (1995) https://doi.org/10.1016/0022-0248(95)00181-6
  10. W. S. Park, D. J. Choi, and H. D. Kim, 'Modification of Inner Pores with Silicon Carbide Whiskers onto the $Al_2O_3$ Substrate by CVI Process,' Key Eng. Mater., 287 212-19 (2005) https://doi.org/10.4028/www.scientific.net/KEM.287.212
  11. J. K. Lee, 'Mechanical Properties of Ceramics Car(in Korean),' Bando Publishing Company, 1 112-13 (1994)
  12. D. C. Lim and D. J. Choi, 'A Study of Growth Properties of SiC Whiskers at various Temperatures and Input Gas Ratios on Different Si Substrate,' J. Ceram. Proc. Res., 5 [2] 148-53 (2004)
  13. D. C. Lim, Y. J. Lee, and D. J. Choi, 'A Study of the Effect of Excessive Free Carbon on Mean Whisker Diameters by Chemical Vapor Deposition,' Surf. Coat. Tech., 192 247-51 (2005) https://doi.org/10.1016/j.surfcoat.2004.04.081

Cited by

  1. Microstructure and Properties of Porous SiC Ceramics Modified by CVI-SiC Nanowires pp.14381656, 2019, https://doi.org/10.1002/adem.201800653