Source Apportionment and the Origin of Asian Dust Observed in Korea by Receptor Modelling (CMB)

수용모델(CMB)을 이용한 한반도에서 관측된 황사의 발원지 추정과 기여도에 대한 연구

  • Shin S.A. (Department of Environmental Engineering, University of Seoul) ;
  • Han J.S. (Air Quality Division, Notional Institute of Environmental Research) ;
  • Kim S.D. (Department of Environmental Engineering, University of Seoul)
  • 신선아 (서울시립대학교 환경공학부) ;
  • 한진석 (국립환경과학원 대기환경과) ;
  • 김신도 (서울시립대학교 환경공학부)
  • Published : 2006.04.01

Abstract

Ambient TSP at four sites in Korea and soil samples from the source regions of Asian Dust in northern China were collected and analyzed for 15 metal components and 6 water-soluble ions to conduct a chemical mass balance (CMB). CMB receptor model was used to estimate the source contribution of TSP during the Asian Dust period, and the model results showed that China soil was the largest source contributor, accounting for 81% of TSP ($458.2{\mu}g/m^3$). Vehicle emission and geological sources contributed to about 8.8% and 4.4% of aerosol mass, followed by sea salt (1.5%) and secondary aerosol (2.9%). Fuel combustion and industrial process sources were found to be relatively minor contributors to TSP (${\leq}1%$). In addition to source contribution estimates, this study tried to identify the origin of Asian Dust observed in Korea. Among all 13 China soil profiles presented in this study, the most adoptable profile which can project the case well was selected and considered as the origin of the applied case.

Keywords

References

  1. 국립환경연구원(1987) 대기중 입자상 물질의 생성 및 동태에 관한 연구, 국립환경연구원, p57
  2. 국립환경연구원 (2003) 대기환경연보, 국립환경연구원, 환경부, p117-211
  3. 신은상 (2001) 서울지역의 황사발생시 대기 부유분진중 미량원소의 특성평가, 건국대학교 환경공학과 박사학위논문, p68
  4. 한진석, 신선아, 공부주, 박문수, 박순웅, 김수진 (2004) 황사발생지역에서 토양입자의 화학적 특성, 한국환경영향평가학회지, 13(6), 277-284
  5. 한진석, 신선아, 홍유덕, 문광주, 이석조, 김신도 (2005) 2000-2002년 우리나라에서 관측된 황사의 화학조성 및 특성, 한국대기환경학회지, 21(1), 119-129
  6. Chan, Y.C., R.W. Simpson, G.H. Matainsh, P.D. Vowles, D.D. Cohen, and G.M. Biley (1999) Source apportioment of PM2.5 and PM10 aerosols in Brisbane (Australia) by receptor modelling, Atmos. Environ., 33, 3251-3268 https://doi.org/10.1016/S1352-2310(99)00090-4
  7. Chen, S.J., L.T. Hsieh, M.J. Kao, W.Y. Lin, K.L. Huang, and C.C. Lin (2004) Characteristics of particles sampled in southern Taiwan during the Asian dust storm periods in 2000 and 2001, Atmos. Environ., 38, 5925-5934 https://doi.org/10.1016/j.atmosenv.2004.07.006
  8. Choi, J.C., M.H. Lee, Y.S. Chun, J.Y. Kim, and S.G. Oh (2001) Chemical composition and source signature of spring aerosol in seoul, Korea, J. Geophys. Res., 106(D16), 18067-18074 https://doi.org/10.1029/2001JD900090
  9. Chow, J.C., G. Watson John, and H. Lowenthal Douglas (1996) Sources and chemistry of PM10 aerosol in Santa Barbara county, CA, Atmos. Environ., 30, 1489-1499 https://doi.org/10.1016/1352-2310(95)00363-0
  10. Gao, Y., R. Arimoto, J.T. Merill, and R.A. Duce (1992) Relationships between the dust concentrations over eastern Asia and the remote North Pacific, J. Geophys. Res., 97(D9), 9867-9872 https://doi.org/10.1029/92JD00714
  11. Guo, Z.G., J.L. Feng, Fang Ming, H.Y. Chen, and K.H. Lau (2004) The elemental and organic charateristics of PM2.5 in Asian dust episodes in Qingdao, China, 2002, Atmos. Environ., 38, 909-919 https://doi.org/10.1016/j.atmosenv.2003.10.034
  12. Kim, K.H., G.H. Choi, C.H. Kang, J.H. Lee, J.Y. Kim, Y.H. Youn, and S.R. Lee (2003) The chemical composition of fine and coarse particles in relation with the Asian Dust events, Atmos. Environ., 37, 753-765 https://doi.org/10.1016/S1352-2310(02)00954-8
  13. Kiyotaka, W., K. Yumoto, T. Koyama, Y. Sekine, and Y. Hashimoto (1989) Relationship of tellurium and selenium concentrations in airbone particulates to major emission sourced, J. Japan Soc. Air Pollut., 24(3), 208-213
  14. Merrill, J.T., M. Uemastsu, and R. Bleck (1989) Meteorological analysis of long-range transport of mineral aerosol over the North Pacific, J. Geophys. Res.,90, 12927-12936 https://doi.org/10.1029/JD090iD07p12927
  15. Mori, I., M. Nishikawa, H. Quan, and M. Morita (2002) Estimation of the concentration and chemical composition of kosa aerosols at their origin, Atmos. Environ., 36 (I29), 4569-4575 https://doi.org/10.1016/S1352-2310(02)00489-2
  16. Park, S.U., S.C. Lim, and E.H. Lee (2005) Directive radiative forcing due to aerosols in East Asia during a Hwangsa (Asian dust) event observed on 19-23 March 2002 in Korea, Atmos. Environ., 39, 2593-2606 https://doi.org/10.1016/j.atmosenv.2005.01.041
  17. Sun, Y., G.S. Zhuang, Y. Wang, L.H. Han, J.H. Guo, M. Dan, W.J. Zhang, Z.F. Wang, and Z.P. Hao (2004) The air-borne particulate pollution in Beijing-concentration, composition, distribution and sources, Atmos. Environ., 38, 5991-6004 https://doi.org/10.1016/j.atmosenv.2004.07.009
  18. U.S.EPA, Office of Air Quality Planning and Standards (1987) Protocol for applying and validating the CMB model
  19. U.S.EPA (1993) VOC/PM speciation data system User's Manual version 1.4
  20. Watson, J.G., J.C. Chow, and T.G. Pace (1991) Chemical mass balance, In: Hopke, P.K. (Ed.), Receptor Modeling for Air Quality Management, Elsevier, New York, pp. 83-116
  21. Watson, J.G., J.C. Chow, Z. Lu, E.M. Fujita, D.H. Lowenthal, D.R. Lawson, and L.L. Ashbaugh (1994) Chemical mass balance source apportionment of PM10 during the southern California air quality study, Aerosol Science and Technology, 21, 1-36 https://doi.org/10.1080/02786829408959693
  22. Watson, J.G., N.F. Robinson, C. Lewis, and T. Coulter (1997) Chemical Mass balance Receptor Model-Version 8 (CMB8) User's Manual, Document No. 1808 1D1, Desert Research Institute, Reno, NV
  23. Weast R.C. (1989) CRC handbook of chemistry and physics, 69th ed., Florida CRC press Inc., F-146
  24. http://www.yellow.metri.re.kr
  25. http://www.arl.noaa.gov/ready/hysplit4.html