한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)

  • 제23권2호
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  • Pages.160-168
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  • 2006
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  • 1225-9098(pISSN)
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  • 2288-1069(eISSN)
한국응용과학기술학회 (The Korean Society of Applied Science and Technology)
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Conductivity and Surface Tension Behavior for Binary Mixtures over a Various Concentration of TTAB

  • 발행 : 2006.06.30
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초록

The conductances of trimethyltetradecylammonium bromide (TTAB) plus triphenyltetradecyl phosphonium bromide (TTPB) and TTAB plus trimethylhexadecylammonium bromide (HTAB) over the entire mole fraction range of TTAB were measured in water and in cyclodextrin plus water mixtures at fixed 4 and 8 mM of cyclodextrin at $30^{\circ}C$. The conductivity plot for both binary mixtures shows a single break from which the mixed critical micelle concentration and degree of micelle ionization were computed. From the slope of the conductivity curve, the equivalent ionic conductivities of the monomeric, associated, and the micelle states were calculated and discussed with respect to the surfactant-cyclodextrin complexation in the whole mole fraction range of both surfactant binary mixtures. The association constant K between the respective monomeric surfactant and cyclodextrin cavity of fixed 4 mM cyclodextrin was computed by considering 1:1 association from the surface tension measurement. A comparison among the K values for HTAB-cyclodetrin, TTAB-cyclodextrin, and TTPB-cyclodextrin shows that the former complexation is significantly stronger in comparison to the other ones due to the longer hydrophobic tail.

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참고문헌

  1. H. B. Shim, M. K. Seo, and S. J. Park, Thermal Conductivity and Emchanical Properties of Various Types Fiber Rainforced Composites, J. Mat. Sci., 37, 1881 (2002) https://doi.org/10.1023/A:1014959603892
  2. J. Taniguchi, C. K. Lim, and M. Wakihara, Morphology and Electrochemical Performances of Spinel Powders, Solid State Ionics, 146, 239 (2002) https://doi.org/10.1016/S0167-2738(01)01016-5
  3. S. W. Oh, S. H. Park, and Y. K. Sun, Structural and Electrochemical Properties of Layered Particles, Siold State Ionics, 171, 167 (2001)
  4. P. D. Battle, M. A. Green, and J. F. Vente, Equilibrium Structure of Micelles, Phys. Rev. B, 54, 15967 (1996) https://doi.org/10.1103/PhysRevB.54.15967
  5. G. A. Peterson, D. K. Malik, W. G. Wilson, and M. J. Flish, Enthalpies and Heat Capacities of Micellization of Some Surfactants, J. Chem. Phys., 109, 10570 (1998) https://doi.org/10.1063/1.477794
  6. Z. L. Wang and L. A. Laysed, Acid Catalyzed Hydloysis of Hydrophobic Ketals in Aqueous Surfactants, Surf. Sci., 380, 302 (1997) https://doi.org/10.1016/S0039-6028(97)05180-7
  7. M. A. Zolfighal and S. E. Mallakpour, Luminescent Probe Study of Water in Oil Microemulsions, Synth. Commun, 30, 2573 (2000) https://doi.org/10.1080/00397910008087422
  8. J. G. Lavin, D. R. Boington, and J. P. Issl, The Correlation of Thermal Conductivity with Electrical Resistivity, Carbon (Letters to the editor), 1001 (1993)
  9. J. K. Pal, D. Godhole, and K. Shrama, Staing of Proteins on Gels and on Membranes by Alta, J. of Biochem and Biophys, 61, 339 (2004) https://doi.org/10.1016/j.jbbm.2004.06.008
  10. W. A. deMheet, W. S. Bacsa, and T. Gerfin, Carbon Nanotube Films; Production and Electronic Properties, Science, 268, 845 (1995) https://doi.org/10.1126/science.268.5212.845
  11. H. Dai, W. Wong, and C. M. Liver, Electrical Transport Nanomaterial Conductivity of Individual Nanotube, Science, 272, 523 (1996) https://doi.org/10.1126/science.272.5261.523
  12. T. Kato and T. Semiya, Thermodymics of Intermicellar Interactions, J. Colloid. Interface Sci., 130, 439 (1989) https://doi.org/10.1016/0021-9797(89)90121-5
  13. T. Jesionoski and A. Krysztafkiewicz, Prepartion of Hydrophilic and Hydrophobic Silica Particles, Colloides and Surfaces, 207, 49 (2002) https://doi.org/10.1016/S0927-7757(02)00137-1
  14. D. Stoye and W. Freitag, Paintings, Coatings, and Solvents, 2nd edition, John Wiely (1998)
  15. D. J. Jung, H. J. Jou, M. S. Kim, and H. S. Park, Optimum Synthesis Condition of Acrylic Resis for High Solid Coatings, J. Kor. Oil. Chem., 21(3), 197 (2004)
  16. B. R. Midmore, Synergy between Silica and Polyethylene Surfactants in the Formation of O/W Emulsion, Colloids and Surfaces, 145, 133 (1998) https://doi.org/10.1016/S0927-7757(98)00577-9
  17. M. Rikukawa and K. Sanui, Protoconducting Polymer Electrolyte Membrane based on Hydrocarbon Polymers, Progress in Polymer Sci., 25, 1463 (2000) https://doi.org/10.1016/S0079-6700(00)00032-0
  18. C. J. Brinker and W. S. George, The Physics and Chemistry of Sol-Gel Processing pp 25-40, Academic Press, (1990)