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Analysis of Benzoxazolo Carbocyanine Compounds using FAB/Mass Spectrometry

FAB/MS를 이용한 Benzoxazolo Carbocyanine계 화합물의 분석

  • Published : 2006.06.30

Abstract

Benzoxazolo carbocyanine compounds were synthesized by condensation of a suitable ortho-ester with an appropriately substituted 2-methylbenzoxazole in the presence of triethylamine. This compounds used as green sensitizing dyes in photographic emulsions. The compounds are characterized by fast atom bombardment mass spectrometry. The values(m/z) of structurally significant ions observed in FAB spectra. It was showed tentative fragmentation pattern in FAB spectroscopy of $HN(C_2H_5)_3$ cations in glycerol/trifluoroacetic acid matrix.

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References

  1. J. W. Oh, 'Photographic Engineering', p. 107, Cheongmungak, Seoul (1991)
  2. Y. C. Kim and B. C. Sohn, The Spectral Sensitization and the Photographic Characteristics of Sensitizing Dye for Photographic Emulsion, J. Kor. Oil Chem. Soc., 13(1), 87-98 (1996)
  3. Y. C. Kim, Spectral Sensitization and Photographic Characteristics of 9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt, J. Kor. Oil Chem. Soc., 20(4), 366-371 (2003)
  4. K. I. Jacobson and R. E. Jacobson, 'Imaging Systems', 1st ed., pp. 37-39, John Wiley & Sons, New York (1976)
  5. X. F. Zhou, H. J. Geise, B. X. Peng, Z. X. Li, M. Yan, R. Dommisse, and R. Carleer, The Structures of Benzoxazole Cyanine Dye, Their Spectroscopy, and Their Performance in Photographic Emulsions, J. Imaging Sci. Technol., 38, 18-23 (1994)
  6. Y. C. Kim, T. S. Kang, and B. C. Sohn, The Synthesis of Sensitizing Dye for Photographic Emulsion, J. Kor. Oil Chem. Soc., 12(2), 5-11 (1995)
  7. Y. C. Kim, The Synthesis of Napthothiazolo Carbocyanine Dye, J. Kor. Oil Chem. Soc., 13(1), 31-39 (1996)
  8. Y. C. Kim, The Synthesis of 9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt, J. Kor. Oil Chem. Soc., 13(3), 73-81 (1996)
  9. Y. C. Kim, The Synthesis of Green - Sensitizing Dye for Photographic Emulsion, J. Kor. Oil Chem. Soc., 14(2), 57-64 (1997)
  10. Y. C. Kim, The Synthesis of Red - Sensitizing Dye for Color Photography, J. Kor. Oil Chem.. Soc., 18(2), 136-141 (2001)