DOI QR코드

DOI QR Code

Luminescent Properties of $SrTiO_3:Pr^{3+}$ Phosphor Coated with $SiO_2$ and $Al_2O_3$ by Sol-Gel Method

졸-겔법에 의한 $SrTiO_3:Pr^{3+}$ 형광체의 $SiO_2$$Al_2O_3$ 코팅에 따른 발광특성

  • Lee, Dong-Kyu (Department of Industrial Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Lim, Mun-Hyuk (Department of Industrial Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Lee, Jin-Hwa (Department of Industrial Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Kim, Tae-Young (Department of Environmental Engineering, Chungbuk Provincial University of Science & Technology)
  • 이동규 (충북대학교 공과대학 공업화학과) ;
  • 임문혁 (충북대학교 공과대학 공업화학과) ;
  • 이진화 (충북대학교 공과대학 공업화학과) ;
  • 김태영 (청주과학대학 환경생명과학과)
  • Published : 2006.09.30

Abstract

Field emission display(FED) is actively investigated in view of the development of full color flat-panel display, which can replace some cathode-ray tube(CRT). Thus, the development of new phosphors appropriate for FED is urgently needed and has been actively investigated. In this work, $SrTiO_3:Pr^{3+}$ phosphor was prepared by sol-gel method and the coating was applied by sol-gel method combined with sonication on these phosphor's surface into diluted precursor solution. It was found that very fine particles of coating material were formed on phosphor's surface. The luminescent intensity of $SrTiO_3:Pr^{3+}$ phosphor coated with $SiO_2$ and $Al_2O_3$ was considerably increased without any noticeable change in color chromaticity. The optimum concentration of coating material was found to be 1wt% and the optimum pH value of the solution was 10.

Keywords

References

  1. S. M. Jacobsen, M. Herren and H. U. Gudel, Energy Transfer in Titanium (II) Doped Magnesium Chloride, J. Lumines., 45, 369 (1990) https://doi.org/10.1016/0022-2313(90)90197-J
  2. Shinji Okamoto, Shosaku Tanaka, and Hajime Yamamoto, Defect Reduction in $SrTiO_3$ by Al Addition J. Lumines., 87, 577 (2000) https://doi.org/10.1016/S0022-2313(99)00300-2
  3. H. Yamamoto and S. Okamoto, Efficiency Enhancement by Aluminum Addition to Some Oxide Phosphors for Field Emission Displays, Displays, 21, 93 (2000) https://doi.org/10.1016/S0141-9382(00)00034-2
  4. K. H. Kim, J. K. Park, C. H. Kim, II. D. Park, H. Chang, and S. Y. Choi, Synthesis of $SrTiO_3$:Pr, Al by Ultrasonic Spray Pyrolysis, Ceram Int. 28, 29 (2002) https://doi.org/10.1016/S0272-8842(01)00054-2
  5. Y. Arai, H. Kominami, Y. Nakanishi, and Y. Hatanaka, Luminescent Properties of $SrGa_2S_4:Eu$ Thin Film Phosphors Deposited by Two Electron Beam Evaporation, Appl. Surf. Sci., 244, 473 (2005) https://doi.org/10.1016/j.apsusc.2004.09.153
  6. H. X. Zhang, C. H. Kam, Y. Zhou, X. Q. Han, Q. Xiang, S. Buddhudu, Y. L. Lam, and Y. C. Chan, Photoluminescence at 1.54 ${\mu}m$ in Sol-Gel-Derived, Er-Doped $BaTiO_3$ Films, J. Alloy. Compd, 308, 134 (2000) https://doi.org/10.1016/S0925-8388(00)00915-4
  7. J. Li and M. Kuwabara, Preparation and Luminescent Properties of Eu-doped $BaTiO_3$ Thin Films by Sol-Gel process, Sci. Tech Adv. Mater., 4, 143 (2003) https://doi.org/10.1016/S1468-6996(03)00027-5
  8. Y. C. Kang, J. S. Choi, S. B. Park, S. H. Cho, J. S. Yoo, and J. D. Lee, Preparation of $CaTiO_3:Pr$ Phosphor by Spray Pyrolysis Using Filter Expansion Aerosol Generator, J. Aerosol Sci., 28, 541 (1997) https://doi.org/10.1016/S0021-8502(97)85270-6
  9. T. Hasegawa, M. Shirai, and K. Tanaka, Localizing Nature of Photo-Excited States in $SrTiO_3$, J. Lumines., 87, 1218 (2000)
  10. J. K. Park, H. J. Ryu, H. D. Park, and S. Y. Choi, Synthesis of $SrTiO_3:Al$, Pr Phosphors from a Complex Precursor Polymer and their Luminescent Properties, J. European Ceram. Soc, 21, 535 (2001) https://doi.org/10.1016/S0955-2219(00)00238-7
  11. W. Park, K. Yasuda, B. K. Wagner, C. J. Summers, Y. R. Do, and H. G. Yang, Uniform and Continuous Y2O3 Coating on ZnS Phosphors, Mater. Sci. Eng., B, 76, 122 (2000) https://doi.org/10.1016/S0921-5107(00)00426-8