Compressional Behavior of Carbon Nanotube Reinforced Mesophase Pitch-based Carbon Fibers

  • Ahn Young-Rack (Enviro-polymers Design Lab., Hyperstructured Organic Materials Research Center (HOMRC) and School of Materials Science and Engineering, Seoul National University) ;
  • Lee Young-Seak (Department of Fine Chemical Engineering & Chemistry, Chungnam National University) ;
  • Ogale A.A. (Department of Chemical Engineering and Center for Advanced Engineering Fibers and Films, Clemson University) ;
  • Yun Chang-Hun (School of Applied Chemistry and Chemical Engineering, Sungkyunkwan University) ;
  • Park Chong-Rae (Enviro-polymers Design Lab., Hyperstructured Organic Materials Research Center (HOMRC) and School of Materials Science and Engineering, Seoul National University)
  • Published : 2006.03.01

Abstract

The tensile-recoil compressional behavior of the carbon nanotube reinforced mesophase pitch (MP)-based composite carbon fibers (CNT-re-MP CFs) was investigated by using Instron and SEM. The CNT-re-MP CFs exhibited improved, or at least equivalent, compressive strength as compared with commercial MP-based carbon fibers. Particularly, when CNT of 0.1 wt% was reinforced, the ratios of recoil compressive strengths to tensile strength of CNT-re-MPCFs were much higher (the difference is at least 10 % or higher) than those for the commercial counterparts and even than those for PAN-based commercial carbon fibers. FESEM micrographs showed somewhat different fractography from that of a typical shear failure as the CNT content increased.

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References

  1. C. R. Park, Ph.D. Dissertation, University of Leeds, 1987
  2. M. G. Dobb, D. J. Johnson, and C.R. Park, J. Mater. Sci., 25, 829 (1990) https://doi.org/10.1007/BF03372169
  3. M. G. Dobb, H. Guo, D. J. Johnson, and C. R. Park, Carbon, 33, 1553 (1995) https://doi.org/10.1016/0008-6223(95)00114-S
  4. M. Nakatani, M. Shioya, and J. Yamashita, Carbon, 37, 601 (1999) https://doi.org/10.1016/S0008-6223(98)00230-9
  5. D. J. Johnson, J. Phys. D; Appl. Phys., 20, 286 (1987) https://doi.org/10.1088/0022-3727/20/3/007
  6. T. Cho, Y. S. Lee, R. Rao, A. M. Rao, D. D. Edie, and A. A. Ogale, Carbon, 41, 1419 (2003) https://doi.org/10.1016/S0008-6223(03)00086-1
  7. T. Natsuki, K. Tantrakam, and M. Endo, Appl. Phys. A: Mater. Sci. & Proc., 79, 117 (2004) https://doi.org/10.1007/s00339-003-2492-y
  8. R. Andrews, D. Jacques, A. M. Rao, F. Derbyshire, D. Qian, and X. Fan, Chem. Phys. Lett., 303, 467 (1999) https://doi.org/10.1016/S0009-2614(99)00282-1
  9. R. Andrews, D. Jacques, A. M. Rao, T. Rantell, F. Derbyshire, and Y. Chen, Appl. Phys. Lett., 75, 1329 (1999) https://doi.org/10.1063/1.124683
  10. N. H. Tai, M. K. Yeh, and J. H. Liu, Carbon, 42, 2774 (2004) https://doi.org/10.1016/j.carbon.2004.06.002
  11. M. Jung and J. W. Cho, J. Korean Fiber Soc., 41(5), 75 (2004)