부산,경남에서 판매되는 시너(Thinner)의 구성 성분 중 벤젠 등 일부 독성물질의 함량과 물질안전보건자료에 관한 연구

Compositions and Contents of Thinner and Reliability of MSDS sold in Busan and Gyeongnam Province

  • 김유영 (창원대학교 보건의과학과) ;
  • 양승혁 (창원대학교 보건의과학과) ;
  • 이정실 (창원대학교 보건의과학과) ;
  • 이형숙 (창원대학교 보건의과학과) ;
  • 장공화 (창원대학교 보건의과학과) ;
  • 진구원 (창원대학교 보건의과학과) ;
  • 이용일 (창원대학교 화학과) ;
  • 주우홍 (창원대학교 생물학과) ;
  • 백도현 (창원대학교 보건의과학과) ;
  • 강대욱 (창원대학교 보건의과학과) ;
  • 문자영 (창원대학교 보건의과학과) ;
  • 조용권 (창원대학교 보건의과학과) ;
  • 박동욱 (한국방송통신대학교 환경보건학과) ;
  • 윤충식 (대구가톨릭대학교 산업보건학과) ;
  • 하권철 (창원대학교 보건의과학과)
  • Kim, Yu Young (Changwon National University, Department of Biochemistry and Health Science) ;
  • Yang, Seung Hyuk (Changwon National University, Department of Biochemistry and Health Science) ;
  • Lee, Jung Sil (Changwon National University, Department of Biochemistry and Health Science) ;
  • Lee, Hyoung Sook (Changwon National University, Department of Biochemistry and Health Science) ;
  • Jang, Kong Hwa (Changwon National University, Department of Biochemistry and Health Science) ;
  • Jin, Koo Won (Changwon National University, Department of Biochemistry and Health Science) ;
  • Lee, Yong Il (Changwon National University, Department of Chemistry) ;
  • Joo, Woo Hong (Changwon National University, Department of Biology) ;
  • Paik, Do-Hyeon (Changwon National University, Department of Biochemistry and Health Science) ;
  • Kang, Dae-Ook (Changwon National University, Department of Biochemistry and Health Science) ;
  • Moon, Ja-Young (Changwon National University, Department of Biochemistry and Health Science) ;
  • Cho, Yong-Kweon (Changwon National University, Department of Biochemistry and Health Science) ;
  • Park, Dong Uk (Department of Environmental Health, Korea National Open University) ;
  • Yoon, Chung Sik (Department of Occupational Health, Catholic University of Daegu) ;
  • Ha, Kwon Chul (Changwon National University, Department of Biochemistry and Health Science)
  • 투고 : 2005.07.07
  • 심사 : 2006.09.29
  • 발행 : 2006.12.31

초록

This study was conducted to identify ingredients of thinners and to confirm reliability of material safety data sheets (MSDS) of thinners for public and workers' health. The 41 thinner products were collected from paint shops located in Busan and Gyeongnam province. The 12 thinner products among them were identified using product MSDS. GC-MSD was used to analyze 41 kinds of thinners qualitatively and quantitatively. The 12 products MSDS were compared with thinner's component through qualitative analysis to confirm MSDS. Chemical ingredients, such as Benzene, Toluene, and Xylene etc., of thinners were analysed in quantity. The 41 thinner products contained 17 disclosed specific, trade name, or generically described chemical solvent ingredients. These 17 ingredients came under 6 classes: alcohols, aromatic hydrocarbons, esters, glycol ethers, ketones, and mixtures. These 17 ingredients were important in the view of industrial hygiene and had occupational exposure limit in the ambient, such as toluene, xylene, acetone, nonane, EGEE, heptane, cumene, MIBK, indene, tri-methyl benzene, etc, were found in 41 kinds of thinners. Aromatic hydrocarbons were the most identified ingredient in thinners. Especially, the benzene, which induces leukemia, was found in 4 kinds of thinners. The content rates of benzene in thinners were 0.25~1.18%. The benzene in enamel thinner, which were 0.39~0.72%, was highest from chemical classification. The contents of toluene, which was found from 27 kinds of thinners, were 5.35~64.16%, which were highest in sobu thinner as 58.80%. Xylene was found from 22 kinds of thinners and contents of xylene were 4.61~72.42%. Acrylic thinner's contents of xylene were 12.06~51.05%, which was most high. It was found that contents of benzene were increased and frequency of detection was decreased through comparison with other study. The MSDS possession rate of paint shops was low as 29.27%. So it did not provide information with public or workers. Mean of agreement rate between MSDS and components of thinners through qualitative analysis was 42.01% and it has wide range from 8.3% to 75%. There are many deficiencies in MSDS about component of thinners. In some case of sample, expecially, despite containing benzene, information was not written it on MSDS.

키워드

과제정보

연구 과제 주관 기관 : 창원대학교

참고문헌

  1. 노동부. 물질안전보건자료의 작성.비치 등에 관한 기준. 노동부고시 제1997-27호, 1997
  2. 노동부. 화학물질 및 물리적인자의 노출기준. 노동부고시 제 2002-8호, 2002
  3. 박동욱, 임호섭, 김신범, 정다운. 모 자동차 도장공정에서 사 용한 신너의 성분과 공기 중 노출에 관한 연구. 한국환경위생학회지 1999;25(1):22-28
  4. 백남원, 윤충식, 조경이, 정회명. 우리나라에서 사용되고 있 는 일부 신나의 구성성분에 관한 연구. 한국산업위생학회지 1998;8(1):105-114
  5. 이권섭, 권현우, 한인수, 유일재, 이용묵. 도료희석제의 MSDS 신뢰성에 관한 연구. 한국산업위생학회지 2003;13(3):261-272
  6. 정회명. 한국에서 사용되는 신너의 구성성분에 관한 연구. 서울대학교 보건대학원 1996
  7. American Conference of Governmental Industrial Hygienist(ACGIH). Threshold Limit Values for Chemical and Physical Agents, and Biological Exposure Indices. ACGIH, Cincinnati, Ohio; 2004
  8. Ignatowski, A.J. and E.D. Weiler, Managing Material Safety Data Sheets World-Wide. American Industrial Hygiene Association(AIHA). 1995;56:698-705 https://doi.org/10.1080/15428119591016728
  9. Kolp, Paul W., Phillip Williams and Rupert Burtan. Assessment of the Accuracy of Material Safety Data Sheets. American Industrial Hygiene Association(AIHA). 1995;56:178-183 https://doi.org/10.1080/15428119591017213
  10. Winder Chris and Steven K. Ng. The problem of variable ingredients and concentration in solvent thinners. American Industrial Hygiene Association(AIHA). 1995;56:1225-1228 https://doi.org/10.1080/15428119591016250