Journal of Korean Society on Water Environment (한국물환경학회지)

Korean Society on Water Environment (한국물환경학회)
권호 표지

Preparation of Fe(III)-Coated Starfish and Evaluation of the Removal Capacity of Copper

3가철 코팅 불가사리 흡착제 제조 및 구리 제거 특성 평가

  • Yang, Jae-Kyu (School of Civil and Environmental Engineering, Kwandong University) ;
  • Yu, Mok-Ryun (School of Civil and Environmental Engineering, Kwandong University) ;
  • Lee, Seung-Mok (School of Civil and Environmental Engineering, Kwandong University)
  • 양재규 (관동대학교 토목.환경학부) ;
  • 유목련 (관동대학교 토목.환경학부) ;
  • 이승목 (관동대학교 토목.환경학부)
  • Received : 2005.11.23
  • Accepted : 2005.12.19
  • Published : 2006.01.30
Download PDF
⟨ Previous Next ⟩

Abstract

Fe(III)-Coated Star Fish (ICSF) was prepared by reaction of calcined Star Fish (SF) with Fe(III) solution at an elevated temperature. To investigate the stability of ICSF at acidic condition, dissolution of Fe was studied at pH 2 as a function of time. Extracted iron was negligible over the entire reaction time. This stability test suggests the applicability of ICSF in the treatment of wastewater even at low pH. Adsorption capacity of Cu(II) onto SF and ICSF was investigated in a batch and a column test. In the pH-edge adsorption, adsorption of copper onto SF and ICSF was quite similar over the entire pH range due to the presence of an important amount of Fe in SF itself. From the adsorption isotherm obtained with variation of the concentration of Cu(II), ICSF showed 1.6 times greater adsorption capacity than SF. Also, ICSF showed a greater removal capacity of Cu(II) in the column test.

Keywords

Acknowledgement

Supported by : 산업자원부

References

  1. 김근한, 신인수, 최봉종, 이승목, 양재규, $TiO_2$에 의한 Cu(II)-EDTA 흡착에서 음이온물질 및 pH의 영향, 대한환경공학회지, 25(5), pp. 644-649 (2003a)
  2. 김근한, 이일영, 최봉종, 이승목, 김승호, 수산폐기물과 불가 사리를 이용한 폐광폐수처리, 대한환경공학회지, 24(3), pp. 489-497 (2002)
  3. 김명진, 안규흥, 정예진, 토양에서의 비소흡착: 반응속도 및 흡착평형, 대한환경공학회지, 25(4), pp. 407-414 (2003b)
  4. 장암, 김원태, 김인수, Fly ash를 이용한 폐광산 광미의 중금속 고정화, 한국폐기물학회지, 15( 3 ), pp. 169-177 (1999)
  5. 장윤영, 김광섭, 정재현, 이승목, 양재규, 박준규, 철코팅 모 래흡착제 제조 및 비소 흡착, 대한환경공학회지, 27(7), pp. 697-703 (2005)
  6. 양재규, 유대환, 이성일, 권혁기, 조주환, 성준용, Iron Coated Sand 의 독성 3 가 비소 홉착성능, 대한환경공학회지, 25(7), pp. 853-859 (2003)
  7. 유대현, 이재광, 이면주, 불가사리를 이용한 하수 소화슬러 지 탈수보조제 제조에 관한 연구, 대한환경공학회지, 26(1), pp. 64-68 (2004)
  8. 이일영, 김근한, 최봉종, 이승목, 수산폐슬러지 및 불가사리 를 이용한 인 제거 연구, 대한환경공학회지, 24(1), pp. 79-87 (2002)
  9. Peacock, C. L. and Sherman, D. M., Copper Sorption onto Goethite, Hematite and Lepidocrocite: A Surface Complexation Model Based on ab Initio Molecular Geometries and EXAFS Spectroscopy, Geochim. Cosmochim. Acta, 68, pp. 2623-2637 (2004) https://doi.org/10.1016/j.gca.2003.11.030
  10. Reed, B. E., Vaughan, R. L. and Jiang, L., As(III), As(V), Hg, and Pb Removal by Fe-oxide Impregnated Activated Carbon, Journal of Environmental Engineering, 126(9), pp. 869-873 (2000) https://doi.org/10.1061/(ASCE)0733-9372(2000)126:9(869)
  11. Vaughan, R. L. and Reed, B. E., Modeling As(V) Removal by a Iron Oxide Impregnated Activated Carbon Using the Surface Complexation Approach, Water Research, 39(6), pp. 1005-1014 (2005) https://doi.org/10.1016/j.watres.2004.12.034