Korean Chemical Engineering Research

  • 제44권3호
  • /
  • Pages.235-242
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  • 2006
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  • 0304-128X(pISSN)
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  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
권호 표지

분무열분해법에의한 형광체 입자의 제조

Preparation of Fluorescence Particles by Spray Pyrolysis

  • 강윤찬 (건국대학교 화학공학과) ;
  • 정경렬 (공주대학교 화학공학과) ;
  • 박승빈 (한국과학기술원 생명화학공학과)
  • Kang, Yun-Chan (Department of Chemical Engineering, Konkuk University) ;
  • Jung, Kyeong-Youl (Department of Chemical Engineering, Gongju National Univeristy) ;
  • Park, Seung-Bin (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology)
  • 투고 : 2006.06.21
  • 심사 : 2006.06.23
  • 발행 : 2006.06.30
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초록

분무 열분해법이란 전구체를 용해시킨 용액을 수 마이크론에서 수십 마이크론 크기의 액적으로 분무한 후, 용매를 증발시키고 석출된 전구체를 열분해하여, 입자 및 필름을 제조하는 공정이다. 이 분무 열분해법의 핵심 요소는 전구체,용매, 액적 제조 그리고 분해 반응기 등 4가지이다. 이 4가지 요소의 적절한 조합에 의해서 현존하는 거의 대부분의 입자와 필름을 제조할 수 있는 범용성이 높은 기술이다. 현재 기술 수준으로는 상업적인 성공을 거두기는 힘들지만 향후 다성분계의 입자나 필름, 혹은 고기능성 입자의 제조에 응용될 경우 매우 유용한 기술로 각광을 받을 전망이다. 본 총설에서는 이 분문 열분해법을 이용해서 만들어지는 입자 중에서 주로 형광체를 중심으로 지금까지 개발된 다양한 분무 열분해 공정 기술을 소개한다

Spray pyrosysis is a process to prepare particles and films by evaporating and decomposing droplets of precursor solutions in the order of 1-10 micrometer in diameter. Key elements of the spray pyrolysis process include precursor, solvent, droplet generator, and reactor. Various combination of these 4 elements produces wide range of particles and films. In general. the current status of the spray pyrolysis technology is not quite promising for commercial success. However, this process will be feasible to produce multicomponent functional materials of controlled morphology. In this paper, current status of the spray pyrolysis technology is introduced with the emphasis of production of fluorescence particles.

키워드

참고문헌

  1. Darabont, A., Names-Incze, P., Kertesz, K., Tapaszto, L., Koos, A. A., Osvath, Z., Sarkozi, Z., Vertesy, Z., Horvath, Z. E. and Biro, L. P., 'Synthesis of Carbon Nanotubes by Spray Pyrolysis and Their Investigation by Electron Microscopy,' J. Optoelectron. Adv. M., 7(2), 631-636(2005)
  2. Patil, P. S., 'Versatility of Chemical Spray Pyrolysis Technique,' Mater. Chem. Phys., 59(3), 185-198(1999) https://doi.org/10.1016/S0254-0584(99)00049-8
  3. Roh, H. S., Kim, E. J., Kang, H. S., Kang, Y. C., Park, H. D. and Park, S. B., 'Vacuum Ultraviolet Characteristics of Nano-sized $Gd_2O_3$:Eu Phosphor Particles,' Jpn. J. Appl. Phys., 42(5A), 2741-2745(2003) https://doi.org/10.1143/JJAP.42.2741
  4. Kang, Y. C., Roh, H. S. and Park, S. B., 'Use of LiCl Flux in the Preparation of $Y_2O_3$:Eu Phosphor Particles by Spray Pyrolysis,' J. Eur. Ceram. Soc., 22(9-10), 1661-1665(2002) https://doi.org/10.1016/S0955-2219(01)00462-9
  5. Shimomura, Y. and Kijima, N., 'High-Luminance $Y_2O_3:Eu^{3+}$ Phosphor Synthesis by High Temperature and Alkali Metal Ion-added Spray Pyrolysis,' J. Electrochem. Soc., 151(4), H86-92(2004) https://doi.org/10.1149/1.1652056
  6. Shimomura, Y. and Kijima, N., 'High-Temperature Spray Pyrolysis of $Y_2O_3:Eu^{3+}$ Red Phosphor,' Electrochem. Solid-State Lett., 7(2), H1-4(2004)
  7. Shimomura, Y. and Kijima, N., 'Formation Mechanisms and Control Method of Aluminum-Containing Impurity in High-Temperature Spray Pyrolysis of $Y_2O_3:Eu^{3+}$ Phosphor,' Electrochem. Solid-State Lett., 7(5), H18-22(2004)
  8. Shimomura, Y. and Kijima, N., 'Effect of Ammonium Chloride Addition on Spray Pyrolysis Synthesis of $BaMgAl_{10}O_{17}:Eu^{2+}$ Phosphor Without Post-Heating,' J. Electrochem. Soc., 151(8), H192-197(2004) https://doi.org/10.1149/1.1767160
  9. Kang, Y. C., Roh, H. S. and Park, S. B., 'Preparation of $Y_2O_3$:Eu Phosphor Particles of Filled Morphology at High Precursor Concentration by Spray Pyrolysis,' Adv. Mater., 12(6), 451-453(2000) https://doi.org/10.1002/(SICI)1521-4095(200003)12:6<451::AID-ADMA451>3.0.CO;2-S
  10. Kang, Y. C., Park, S. B., Lenggoro, I. W. and Okuyama, K., 'Preparation of Nonaggregated $Y_2O_3$:Eu Phosphor Particles by Spray Pyrolysis Method,' J. Mater. Res., 14(6), 2611-2615(1999) https://doi.org/10.1557/JMR.1999.0349
  11. Kang, Y. C., Roh, H. S. and Park, S. B., 'Morphology Control of Oxide Phosphor Particles by Colloidal Seed-Assisted Spray Pyrolysis,' J. Electrochem. Soc., 147(4), 1601-1603(2000) https://doi.org/10.1149/1.1393403
  12. Kang, Y. C., Seo, D. J., Park, S. B. and Park, H. D., 'Morphological and Optical Characteristics of $Y_2O_3$:Eu Phosphor Particles Prepared by Flame Spray Pyrolysis,' Jpn. J. Appl. Phys., 40(6A), 4083-4086(2001) https://doi.org/10.1143/JJAP.40.4083
  13. Lee, J. H., Kang, Y. C., Park, S. B. and Park, H. D., 'Luminescence Characteristics of Eu-doped strontium Halophospate Phosphor Particles Prepared by Spray Pyrolysis,' Jpn. J. Appl. Phys., 40(5A), 3222-3225(2001) https://doi.org/10.1143/JJAP.40.3222
  14. Kang, Y. C., Park, H. D. and Park, S. B., 'The Effect of Metal Chloride Fluxes on the Properties of Phosphor Particles in Spray Pyrolysis,' Jpn. J. Appl. Phys., 39(12B), 1305-1307(2000) https://doi.org/10.1143/JJAP.39.L1305
  15. Kang, Y. C., Chung, Y. S. and Park, S. B., 'Preparation of YAG: Europium Red Phosphors by Spray Pyrolysis Using a Filter-Expansion Aerosol Generator,' J. Am. Ceram. Soc., 82(8), 2056-2060(1999) https://doi.org/10.1111/j.1151-2916.1999.tb02040.x
  16. Kang, Y. C., Lenggoro, I. W., Okuyama, K. and Park, S. B., 'Luminescence Characteristics of $Y_2SiO_5$:Tb Phosphor Particles Directly Prepared by the Spray Pyrolysis Method,' J. Electrochem. Soc., 146(3), 1227-1230(1999) https://doi.org/10.1149/1.1391750
  17. Kang, Y. C., Lenggoro, I. W., Park, S. B. and Okuyama, K., '$Y_2SiO_5$:Ce Phosphor Particles 0.5-1.4 ${\mu}$m in Size with Spherical Morphology,' J. Solid State Chem., 146(1), 168-175(1999) https://doi.org/10.1006/jssc.1999.8325
  18. Cho, S. H., Yoo, J. S., Lee, J. D., Choi, J. S. and Park, S. B., The 3rd International Conference on the Science and Technology of Display Phosphors, 307(1997)
  19. Hong, G. Y., Kwon, S. H., Yoo, J. S. and Summers, C. J., The 5th International Conference on the Science and Technology of Display Phosphors, 187(1999)
  20. Park, I. W., Choi, C. K. and Yoo, J. S., The 6th International Conference on the Science and Technology of Display Phosphors, 175(2000)
  21. Kang, Y. C. and Park, H. D., 'Preparation Method of Red Phosphor Particles with Spherical Shape,' KR. Patent No. 2001-0015232 (2001)
  22. Kang, Y. C., Lee, D. Y. and Park, H. D., 'Preparation Method of Blue and Green Emitting Aluminate Phosphor Particle,' KR. Patent No. 2001-0023819(2001)
  23. Roh, H. S., Kang, Y. C. and Park, S. B., 'Morphology and Luminescence of $(GdY)_2O_3$:Eu Particles Prepared by Colloidal Seed- Assisted Spray Pyrolysis,' J. Colloid Inter. Sci., 228(2), 195-199 (2000) https://doi.org/10.1006/jcis.2000.6947