The Effect of the Sn Amounts on the Microstructure of Rapidly Solidified Ag-Sn-In Alloys

급속응고한 Ag-Sn-In 미세조직에 미치는 Sn 함량 변화의 영향

  • Published : 2006.04.20

Abstract

Contact material is widely used as electrical parts. Ag-Cd alloy has a good wear resistance and stable contact resistance. But the disadvantages of Ag-Cd alloy are coarse Cd oxides and harmful metal, Cd. To solve the disadvantages of that, Ag-Sn alloy that has stable and fine Sn oxide at high temperature has been developed. In order to optimize Sn amount that affects the formation of the oxide layer on the surface, we worked for the microstructures and properties of Ag-Sn material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. We have shown that the optimized Sn amount for high hardness is 7.09 wt%Sn. Surface oxide layer forms when Sn amount is over 9.45 wt%. The size of Sn oxide is 20 nm.

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References

  1. D. N. Lee: J. Korean Ins. Met., 'The Internal Oxidation of Ag-Cd alloys', 14(1)(1976) 20-30
  2. G Bohm and M. Kahlweit: ACTA Met. 12 (1964) 641 https://doi.org/10.1016/0001-6160(64)90036-7
  3. Y. S. Shen, Edward J. Zdanuk, and Richard H. Krock: Met. Trans., 'The Effect of Additives from Gropps IA and IIA on the Morphology and Properties of Silver-Cadmium Oxide Contacts', 8(1) (1972) 16-25
  4. WEEE, Waste Electrical and Electronic Equipment
  5. RoHS, Restriction of Hazardous Substances
  6. H. Chang, C. H. Pitt, and G.G Alexander, Mat. Sci. eng., 'Electroless Silver Plating of Oxide Particles in Aqueous-Soulution', B8 (1991) 99
  7. A. Verma and T. R. Anantharaman, J. Mat. Sci. 'The internal oxidation behaviour of rapidly solidified silver-tin-indium (Ag-Sn-ln) alloy', 27 (1992) 5623 https://doi.org/10.1007/BF00541633
  8. M. Poniatowski, E. Schulz, and A. wirths, Proc. 8th Int. Conf. on Electrical Contact, 'Replacement of silver - cadmium oxide with silver-tin oxide in. low-voltage switching devices', 32 (1978) 30