[ $Ag^+$ ]-Chitosan Complex Membranes for Propylene/Propane Separation

  • Kim, Jeong-Hoon (Interface Materials and Engineering Lab, Division of Chemical Technology, Korea Research Institute of Chemical Technology) ;
  • Lee, Soo-Bok (Interface Materials and Engineering Lab, Division of Chemical Technology, Korea Research Institute of Chemical Technology) ;
  • Feng, Xianshe (Department of Chemical Engineering, University of Waterloo)
  • 발행 : 2006.12.31

초록

We have prepared new water-swollen chitosan-$Ag^+$ complex membranes and studied their permeation and separation behavior for propylene and propane gases. The $Ag^+$ containing chitosan complex membranes were prepared from chitosan and $AgNO_3$ aqueous solution. The $AgNO_3$ and water content in the membrane were controlled by adjusting $AgNO_3$ concentration of casting solution. The permeation properties of propylene and propane were investigated as a function of $AgNO_3$ concentration, and various operation conditions. High permeability of above 17 barrer and high selectivity of above 170 could be obtained with the membranes prepared from 3 M $AgNO_3$ aqueous solution. Periodic regeneration test confirmed these membranes could be very useful for the separation of propylene/propane and other olefin/paraffin separation.

키워드

참고문헌

  1. R. B. Eldridge, Olefin/Paraffin Separation Technology: Review, Ind. Eng. Chem. Res., 32, 2208-2212 (1993) https://doi.org/10.1021/ie00022a002
  2. J. D. Way and R. D. Noble, Facilitated transport, in: W. S. Ho, S. S. Sirkar (Eds), Membrane Handbook, Van Nostrand, New York (1992)
  3. E. L. Cusser, Facilitated and active transport, in: D. R. Paul, Y. P. Yanpol' skii (Eds), Polymeric Gas Separation Membranes, CRC Press, Boca Raton, FL, 1994 m pp. 274-300
  4. M. Teramoto, H. Matsuyama, T. Yamashiro, and Y. Katayama, Separation of ethylene from ethane by supported liquid membranes containing silver nitrate as a carrier, J. Chem. Eng. Jpn., 19, 419 (1986) https://doi.org/10.1252/jcej.19.419
  5. J. C. Davis, R. J. Valus, R. Eshraghi, and A. E. velikoff, Facilitated transport membrane hybrid systems for olefin purification, Sep. Sci. Technol., 28, 463 (1993) https://doi.org/10.1080/01496399308019500
  6. Mitsuyasu Kwaskami, Masaru Tatkeshi, Masakazu Iwamoto and Shuichi Kagawa, Selective permeation of ethylene and propylene through Rh+3-polyethylene glycohol liquid membranes, J. Memb. Sci., 30, 105 (1987) https://doi.org/10.1016/S0376-7388(00)83344-X
  7. R. D. Hughes, J. A. Mahoney, and E. F. Steigelmann, Olefin separation by facilitated transport membranes, in N > N Li and J. M. Calo (Eds.,) Recent Developments in SeparationScience, Vol. IX, CRC, Boca Raton, FL, pp. 173 (1986)
  8. W. S. Ho and D. C. Dalrymple, Facilitated transport of olefins in Ag+-containing polymer membranes, J. Memb. Sci., 91, 13-25 (1994) https://doi.org/10.1016/0376-7388(94)00008-5
  9. J.-S. Yang and G.-H. Hsiue, Swollen polymeric complex membranes for olefin/paraffin separation, J. Memb. Sci., 138, 203-211 (1998) https://doi.org/10.1016/S0376-7388(97)00231-7
  10. James C. Davis, Ronald, and J. Valus, Reza Eshraghi and Alex E. Velikoff, Facilitated transport membrane hybrid systems for olefin purification, Sep. Sci. and Technol., 28(1-3), 463-476 (1993) https://doi.org/10.1080/01496399308019500
  11. Hans H. Funke, Richard D. Noble, and Carl a. Koval, Separation of gases olefin isomers using facilitated transport membranes, J. Memb. Sci., 82 (1993)
  12. Odd I. Eriksen, Elin Akkxnes, and Ivar M. Dahl, Facilitated transport of ethane through Nafion membranes. Part I. Water swollen membranes, J. Memb. Sci., 85, 89-97 (1993), Part II. Glycerine treated, water swollen membranes, J. Memb. Sci., 85, 99-106 (1993) https://doi.org/10.1016/0376-7388(93)85009-L
  13. Takeo Yamaguchi, Chelsey Baertsch, Carl A. Koval, Richard D. Noble, and Christopher N. Bowman, Olefin separation using silver impregnated ion exchange membranes and silver salt/polymer blend membranes, J. Memb. Sci., 117, 151-161 (1996) https://doi.org/10.1016/0376-7388(96)00056-7
  14. I. Pinnau, L. G. Yoy, S. Sunderrajan, and B. D. Freeman, solid polymer electrolyte membranes for olefin/paraffin separation, Polym. Mater. Sci. Eng., 77, 269 (1997)
  15. Yosang Yoon, Jongok Won, and Yong Soo Kang, Polymer electrolyte membranes containing silver ion for facilitated olefin transport, Macromolecules, 33(9), 3185 (2000) https://doi.org/10.1021/ma0000226
  16. Dongkyum Ko, Jonghak Kim, Sung Taik Chung, and Yong Soo Kang, Analysis of facilitated olefin transport through polymer electrolyte membranes containing silver salts, Membrane J., 13(4), 239-245 (2003)
  17. Ingo Pinnau and Lora G. Toy, Solid polymer electrolyte composite membranes for olefin/paraffin separation, J. Memb. Sci., 184, 39-48 (2001) https://doi.org/10.1016/S0376-7388(00)00603-7
  18. Silver doped Nafion-poly(pyrrole)membranes for facilitated permeation of liquid-phase olefins, A. Sungpet, J, D. Way, A. A. Koval and M. E. Eberhart, J. Memb. Sci., 189, 271-279 (2001) https://doi.org/10.1016/S0376-7388(01)00419-7