메탄올-글리세린을 이용한 재흡수 열펌프의 열역학적 모사 연구

A Study on a Resorption Beat Pump Using Methanol-Glycerine

  • 민병훈 (수원대학교 화공생명공학과)
  • Min, Byong-Hun (Department of Chemical & Bio-Chemical Engineering, University of Suwon)
  • 발행 : 2006.12.31

초록

냉 난방 수요에서 일어나는 환경오염의 최소화와 화석연료 소비를 감소시키기 위해서 에너지 회수를 개선시키는 것은 필수적이다. 이러한 점에서 흡수식 열펌프기술은 에너지 절약을 위해서 많은 가능성을 가지고 있다. 흡수식 열펌프는 에너지를 주입하지 않고 폐열의 이용을 높일 수 있는 방법이다. 본 연구에서는 에너지 회수를 위한 재흡수 열펌프 연군를 메탄올-글리세린을 이용하여 수행하였다. 이 물질의 열역학 데이터를 이용하여 재흡수 열펌프의 이론적 열효율 값을 각 기관의 조업 조건에 따라서 계산하였다. $70{\sim}80^{\circ}C$의 산업 폐열 온도를 가지고 $40{\sim}50^{\circ}C$ 승온 시킬 때 열효율 값 0.4 이상을 얻을 수 있었다.

The improvement of energy recovery is mandatory to decrease consumption of fossil fuels and to minimize negative impacts on the environment which originates from large cooling and heating demand. The absorption heat pump technology has a large potential for energy saving in this respect. Absorption heat pump is a means to upgrade waste heat without addition of extra thermal energy. In this study, resorption heat pump for energy recovery has been investigated using methanol-glycerine. The simulated calculation of theoretical thermal efficiency was performed based on the thermodynamic properties of the working fluid over various operating conditions. The thermal efficiency of higher than 0.4 was obtained by raising industrial waste heat, $70{\sim}80^{\circ}C$, by $40^{\circ}C$ in this system.

키워드

참고문헌

  1. Whitlow, E.P. 'An improved absorption refrigeration cycle'. Gas Age, 1958, 30, 19-27
  2. Cacciola, G.; Restuccia, G.; Rizzo, G. 'Theoretical performance of an absorption heat pump using ammonia-water-potassium hydroxide solution', Heat Recovery Systems & CHP, 1990, 10, 177-185 https://doi.org/10.1016/0890-4332(90)90001-Z
  3. Izquierdo, M.; Aroca, S. 'Lithium bromide high temperature absorption heat pump: coefficient of performance and exergetic efficiency', Int. J. Energy Research, 1990, 14, 281-291 https://doi.org/10.1002/er.4440140304
  4. Jemqvist, A.; Abrahamsson K; Aly, G. 'On the efficiencies on absorption heat pumps', Heat Recovery Systems & CHP, 1992, 12, 469-480 https://doi.org/10.1016/0890-4332(92)90015-A
  5. Ziegler, F.; Riesch, P. 'Absorption cycles. A review with regard to energetic efficiency', Heat Recovery System & CHP, 1993, 13, 147-159 https://doi.org/10.1016/0890-4332(93)90034-S
  6. Agnew, B.; Alaktiwi, A.; Anderson, A; Potts, I. 'Simulation of a combined Rankine-absorption cycle', Applied Thermal Engineering, 2004, 24, 1501-1511 https://doi.org/10.1016/j.applthermaleng.2003.11.013
  7. Romero, R.J.; Guillen, L.; Pilatowski, I. 'Monomethylamine- water vapor absorption refrigeration system', Applied Thermal Engineering, 2005, 24, 867-876
  8. Squires, R.G.; Aker, J.E.; Albright, L.E. 'An evaluation of alcohol-salt mixures as absorption refrigeration solutions', ASHRAE Trans., 1965. 71, 14-22
  9. Tyagi, K.P. Heat Recovery System & CHP, 1992, 12(3), 283 https://doi.org/10.1016/0890-4332(92)90056-N
  10. Uemura, T.; Hasaba, S. 'Investigation of absorption refrigerating machine operating on solution of methanol and lithium bromide', Refrigeration, 1968, 43(2), 784-792
  11. Gabsi, P. 'Contribution a l'etude des pompes a chaleur a absorption analyse des performance d'une installation fonctionnant avec le systeme eau-LiBr', Ph.. D. Dissertation, 1981, I.N.P.T, Toulouse, France
  12. Vasiliev, L,L.; Mishkinis, D.A.; Antukh, A.A; Kulakov, A.G. 'Resorption Heat Pump', Applied Thermal Engineering, 2004, 24, 1893-1903 https://doi.org/10.1016/j.applthermaleng.2003.12.018
  13. Eisa, M.A.R.; Devotta S.; Holland, F.A. 'Thermodynamic design data for absorption heat pump systems operating on water-lithium bromide : simultaneous cooling and heating', Applied Energy, 1986, 25, 83-96 https://doi.org/10.1016/0306-2619(86)90068-1
  14. Narodoslawski, M.; Otter, G.; Moser, F. 'Thermodynamic criteria for optimal absorption heat pump media', Heat Recovery System & CHP, 1988, 8, 221-233 https://doi.org/10.1016/0890-4332(88)90058-0
  15. Castro, J.B.; Corberian. J.M.; Gonzalvez, J. 'Optimized design of a heat exchanger for an air-to-water reversible heat pump working with propane as refrigerant: modelling analysis and experimental observations', Applied Thermal Engineering, 2005, 25, 2450-2462 https://doi.org/10.1016/j.applthermaleng.2004.12.009
  16. Youbi-Idrissi, M.; Bonjour. J.; Meunier, F. 'Local shifts of the fluid composition in a simulated heat pump using R-470C', Applied Thermal Engineering, 2005, 25, 2827-2841 https://doi.org/10.1016/j.applthermaleng.2005.02.005
  17. Eisa, M.A.R.; Best, R.; Holland, F.A. 'Thermodynamic design data for absorption heat pump systems operating on water-calcium chloride', Applied energy, 1987, 28, 69-81 https://doi.org/10.1016/0306-2619(87)90042-0
  18. Grover, G.S.; Eisa M.A.R.; Holland, F.A. 'Thermodynamic design data for absorption heat pump systems operating on water-lithium chloride-part 1 cooling', Heat Recovery System & CHP, 1988, 8, 33-41 https://doi.org/10.1016/0890-4332(88)90039-7
  19. Patil, K.R.; Eisa M.A.R.; Kim, M.N. 'Experimental evaluation of aqueous lithium halides as single- and double-salt systems in absorption heat pump', Applied Energy, 1989, 34, 99-111 https://doi.org/10.1016/0306-2619(89)90023-8
  20. Won, S.H.; Lee, W.Y. 'Thermodynamic design data for double effect absorption heat pump systems using water-lithium chloride-cooling', Heat Recovery System & CHP, 1991, 11, 41-48 https://doi.org/10.1016/0890-4332(91)90186-8
  21. Mohanty, B. 'Contribution a l'etude de la gestioh optimale d'energie solaire en vue de la production de froid par cycle a absorption', Ph. D. Dissertation, 1985, I.N.P.T, Toulouse, France
  22. Dan, P.D.; Murthy, S.S. 'A comparative thermodynamic study of fluorocarbon refrigerant based vapor absorption heat pump', Int. J. of Energy Research, 1989, 13, 1-21 https://doi.org/10.1002/er.4440130102
  23. Bennani, N.; Prevost, M.; Coronas, A. 'Absorption heat pump cycles: Performance analysis of waterglycerol mixture', Heat Recovery System & CHP, 1989, 9, 257-263 https://doi.org/10.1016/0890-4332(89)90009-4
  24. Greek, J. 'Thermodynamic properties of solution of glycol in methanol and lithium-chloride in methanol', Ph. D. Dissertation, 1975, South Illinois university, U.S.A