DOI QR코드

DOI QR Code

Preparation of Organic Dye-Inorganic Silica Hybrid Pigment and It's Application for Inkjet Dispersion Ink

유기 염료-무기 실리카 하이브리드 안료의 제조와 분산잉크로서 응용

  • Published : 2006.07.27

Abstract

Studies were performed on preparation of organic-inorganic hybrid silica dye in a dispersing ink system. The silica was subjected to surface modification using 3-aminopropyltrimethoxysilane (APTMS) in order to promote the chemical reactivity of the raw silica. On the surfaces of the aminosilane-functionalised silica, red vinylsulfone-containing azo dye was adsorbed. The dye was found to have chemically reacted with the aminosilane-grafted silica surface, which was proven by FT-IR spectra. Studies on morphology and microstructure were performed employing scanning electron microscopy. The SEM micrographs and particle size distributions showed that a homogeneous pigment can be obtained employing silica as a core. Particle size distribution was also examined using the technique of dynamic light scattering. The ensuing pigment was subjected to various physicochemical evaluation such as inkjet property, storage stability, color change as inkjet ink using printer, spectrophotometric, microscopic techniques. Studies on hybrid dyes from the silica surface demonstrated that, in general, stable pigments for inkjet dispersion ink were obtained.

Keywords

References

  1. A. P. Legrand, The Surface Properties of Silicas, John Wiley & Sons, New York, 145 (1998)
  2. E. F. Vansant, P. Van Der Voort and K. C. Vrancken, Characterization and Chemical Modification of the Silica Surface, Elsevier, Amsterdam, (1995)
  3. K. I. Mittel, Silane and Other coupling Agents, VSP, Urecht, (1992)
  4. N. R. E. N. Impens, P. Van Der Voort and E. F. Vansant, Microporous and Mesoporous Materials, 28, 217 (1999) https://doi.org/10.1016/S1387-1811(98)00239-X
  5. R. K. Iler, The chemistry of silica. John Wiley & Sons, New York, 462 (1979)
  6. H. E. Bergana The colloid chemistry of silica, Advances in Chemistry Series 234, ACS, Washington, D.C., (1994)
  7. E. Matijevic, J. Eur. Ceram. Soc., 18, 1357 (1998) https://doi.org/10.1016/S0955-2219(98)00065-X
  8. A. Krysztafkiewicz, S. Binkovski and I. Wyscoka, Powder Technol., 132, 190 (2003) https://doi.org/10.1016/S0032-5910(03)00073-1
  9. D. Lo, J. E. Parris and J. L. Lawless, Appl. Phys. B, 56, 385 (1993) https://doi.org/10.1007/BF00324537
  10. S. K. Parida and B. K. Mishra, J Colloid. Interf. Sci., 182, 473 (1996) https://doi.org/10.1006/jcis.1996.0490
  11. S. K. Parida and B. K, Mishra, Colloid. Surf. A, 134, 249 (1998) https://doi.org/10.1016/S0927-7757(97)00114-3
  12. R. Ledger and E. J. Stellwagen. Chrornatogr., 299, 175 (1984) https://doi.org/10.1016/S0021-9673(01)97830-6
  13. H. Giesche and E. Matijevic, Dyes and Pigments, 17, 323 (1991) https://doi.org/10.1016/0143-7208(91)80024-4
  14. G. Wu, A. Koliadima, Y. S. Her and E. Matijevic. J. Colloid. Interf. Sci., 195, 222 (1997) https://doi.org/10.1006/jcis.1997.5156
  15. F. M. Winnik, B. Kecshkerian, J. R. Fuller and P. G. Hofstra, Dyes and Pigments, 14, 101 (1990) https://doi.org/10.1016/0143-7208(90)87010-Z
  16. T. Jesionowski, Dyes and Pigments, 55, 133 (2002) https://doi.org/10.1016/S0143-7208(02)00105-5
  17. T. Jesionowski, M. Pokora, W. Tylus, A. Dec and A. Krysztafkiewicz, Dyes and Pigments, 57, 29 (2003) https://doi.org/10.1016/S0143-7208(03)00006-8
  18. T. Jesionowski, A. Krysztafkiewicz and S. Binkovski, Dyes and Pigments, 65, 267 (2005) https://doi.org/10.1016/j.dyepig.2004.08.002
  19. US Patent 4,566,908 (1986)
  20. US Patent 4,576,888 (1986)
  21. US Patent 4,877,451 (1989)
  22. F. M. Winnik, B. Kecshkerian, J. R. Fuller and P. G. Hofstra, Dyes and Pigments, 14, 101 (1990) https://doi.org/10.1016/0143-7208(90)87010-Z
  23. W. P. Hsu, R. Yu and E. Matijevic, Dyes and Pigments 19, 222 (1992) https://doi.org/10.1016/0143-7208(92)80024-H
  24. A. Tentoririo, E. Matijevic and J. P. Kratohvil, J. Colloid. & Interf. Sci., 77, 418 (1980) https://doi.org/10.1016/0021-9797(80)90312-4
  25. E. Matijevic, B. Aiken and W. P. Hsu, J. Am. Ceram. Soc., 71, 845 (1988) https://doi.org/10.1111/j.1151-2916.1988.tb07534.x
  26. Z. Rappoport, 'Advances in Physical Organic Chemistry', Vol. 7, Academic Press, London & New York, (1969)
  27. C. K Ingold, Structure and Mechanism in Organic Chemistry, Cornell Univ. Press, (1953), p 193
  28. P. Nobler, Jr. T. G. Borgardt and W. L. Reed, Chem. Rev., 64, 19 (1964) https://doi.org/10.1021/cr60227a003
  29. S. Patai and Z. Rappoport, The Chemistry of Alkenes, Ch.8, John Wiley & Sons. New York, (1964)

Cited by

  1. Spectroscopic Analysis on Michael Addition Reaction of Secondary Amino Groups on Silica Surface with 3-(Acryloyloxy)-2-hydroxypropyl Methacrylate vol.38, pp.2, 2014, https://doi.org/10.7317/pk.2014.38.2.257
  2. Quantitative Analysis of Grafted Methacrylate Groups by Michael Addition Reaction between Primary and Secondary Amino Groups on the Silica Nanoparticle Surface with 3-(Acryloyloxy)-2-Hydroxypropyl Methacrylate vol.39, pp.2, 2015, https://doi.org/10.7317/pk.2015.39.2.300