Bulletin of the Korean Chemical Society

  • 제27권8호
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  • Pages.1206-1210
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  • 2006
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Novel Two-dimensional Network Based on Amino-acid-octamolybdate Bridged by Second Metals: {M(H2O)3(pro)Mo4O13}2·2H2O (pro = proline, M = Co, Ni, Cu, Zn)

  • 발행 : 2006.08.20
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초록

Four isostructural amino-acid-based polyoxomolybdates, {$M(H_2O)_3(pro)Mo_4O_{13}$}$_2{\cdot}2H_2O$ (pro = proline, M = Co (1), Ni (2), Cu (3), Zn (4)), have been synthesized and structurally characterized by single crystal X-ray diffraction, elemental analysis, IR spectrum, TG analysis. The structures of 1-4 are layered networks built up from {$Mo_8O_{26}(pro)_2$}$^{4-}$ units and {$M(H_2O)_3O_3$} octahedra, the uncoordinated water molecules occupying the interlayer regions.

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  3. A survey of the different roles of polyoxometalates in their interaction with amino acids, peptides and proteins vol.46, pp.21, 2017, https://doi.org/10.1039/C7DT00894E
  4. Synthesis, characterization and reactions of some short chain alkoxycarbonyl molybdenum compounds [M][Mo(CO)5(COOR)] (M=PPN, Et4N and R=Me, Et, iPr) and [Ph vol.383, pp.None, 2006, https://doi.org/10.1016/j.ica.2011.10.039
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