Bulletin of the Korean Chemical Society

  • 제27권2호
  • /
  • Pages.203-207
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  • 2006
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Syntheses and Crystal Structures of Xylyl-Bridged NO2S2-Donor Macrocycles and Binuclear Mercury(II) Complex

  • Lee, Ji-Eun (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Jin, Yong-ri (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Seo, Joo-beom (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Yoon, Il (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Song, Mi-Ryoung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, So-Young (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Park, Ki-Min (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
  • 발행 : 2006.02.20
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초록

Isomeric series of dilinked $NO_2S_2$ macrocycles ($L^2$: para-, $L^3$: meta- and $L^4$: ortho-linked) capable of binuclear complexing ability were prepared from its monomeric analog $L^1$ in reasonable yields except ortho-type reaction, which led to mixture due to the formation of monomer-type macrocyclic quaternary ammonium bromide $L^5$. Moreover, L2 (as $2HNO_3$ form) and $L^5$ were confirmed by an X-ray crystallography. Reaction of $HgCl_2$ with $L^2$ yielded a binuclear complex $[Hg_2(L^2)Cl_4]$. In the complex, each mercury(II) has a distorted tetrahedral environment made up of S and N donors from an exodentate $L^2$ and two coordinated Cl atoms.

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  2. Extra Large Macrocycle: 40-Membered Macrocycle via 2:2 Cyclization and Its Dimercury(II) Complex vol.50, pp.17, 2011, https://doi.org/10.1021/ic2009607
  3. Selectivity vol.34, pp.5, 2013, https://doi.org/10.5012/bkcs.2013.34.5.1429
  4. Endo- and Exo-Coordinated Mercury(II) Complexes of O3S2 Macrocycles: Effect of Dibenzo-Substituents on Coordination Mode vol.28, pp.11, 2007, https://doi.org/10.5012/bkcs.2007.28.11.2041
  5. Discrete and Continuous Soft Metal Complexes of O2S2 and NO2S2 Macrocycles with Endo- or Exo-Coordination Mode vol.29, pp.1, 2006, https://doi.org/10.5012/bkcs.2008.29.1.241
  6. A Triple-Probe Channel NO2S2-Macrocycle: Synthesis, Sensing Characteristics and Crystal Structure of Mercury(II) Nitrate Complex vol.31, pp.7, 2006, https://doi.org/10.5012/bkcs.2010.31.7.2031
  7. Syntheses and Crystal Structures of Anthracene-Attached and Anthracene-Bridged NO2S2-Macrocycles as Fluoroionophores vol.32, pp.5, 2006, https://doi.org/10.5012/bkcs.2011.32.5.1761
  8. A double decker type complex: copper(I) iodide complexation with mixed donor macrocycles via [1 : 1] and [2 : 2] cyclisations vol.45, pp.11, 2006, https://doi.org/10.1039/c5dt03751d