Bulletin of the Korean Chemical Society

  • 제27권9호
  • /
  • Pages.1381-1385
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  • 2006
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Styrene Epoxidation over Cobalt Cyclam Immobilized SBA-15 Catalyst

  • Sujandi (Lab. of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry,Inha University) ;
  • Prasetyanto, Eko Adi (Lab. of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry,Inha University) ;
  • Han, Sang-Cheol (Lab. of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry,Inha University) ;
  • Park, Sang-Eon (Lab. of Nano-Green Catalysis and Nano Center for Fine Chemicals Fusion Technology, Department of Chemistry,Inha University)
  • 발행 : 2006.09.20
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초록

Cobalt (cyclam) complex has been successfully immobilized onto SBA-15, and proven to be an active catalyst for the epoxidation of styrene with tert-butyl hydroperoxide as a terminal oxidant. The selectivity for styrene oxide was observed to be up to 66% with 40% styrene conversion after 12h reaction time. The reversible redox cycle between Co(III) and Co(II) couple which was supposed to play key role during the epoxidation reaction was supported by a cyclic voltametry analysis. The textural properties of the catalyst was characterized by XRD, N2 adsorption-desorption, and TEM analysis.

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