Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Coordination Modes and Properties of Ag(I) Complex with N,N,N',N',N''-Pentamethyldiethylenetriamine

  • Chun, In-Sung (Department of Chemistry (BK21) and Center for Plastic Information System, Pusan National University) ;
  • Kwon, Jung-Ah (Department of Chemistry (BK21) and Center for Plastic Information System, Pusan National University) ;
  • Bae, Myung-Nam (Department of Chemistry (BK21) and Center for Plastic Information System, Pusan National University) ;
  • Lee, Sim-Seong (Department of Chemistry, Gyeongsang National University) ;
  • Jung, Ok-Sang (Department of Chemistry (BK21) and Center for Plastic Information System, Pusan National University)
  • Published : 2006.01.20
Download PDF
⟨ Previous Next ⟩

Abstract

The reaction of $AgClO_{4}$ with acyclic potential tridentate N,N,N',N',N''-pentamethyldiethylenetriamine (pmdeta) has given colorless crystals suitable for X-ray crystallography. The crystal structure ($P2_{1}$/n, a = 14.413(1) $\AA$, b = 25.270(2) $\AA$, c = 16.130(1) $\AA$, b = $103.012(1){^{\circ}}$, V = 5723.7(8) A$\AA^{3}$, Z = 4, R = 0.0349) has been solved and refined. Three silver(I) ions connect four pmdeta ligands to produce discrete complex of $[Ag_3(pmdeta)_4](ClO_4)_3$. A pmdeta ligand is bridged to three silver(I) ions, and three other pmdeta ligands are chelated to each silver(I) center in a tridentate mode. Thus, the product is a rare tri-nuclear silver(I) complex with two different chemical environments. $^{13}C$ NMR and $MAS\;^{13}$C NMR indicate that the tri-nuclear silver(I) complex is not rigid in solution. The contact angles and thermal analyses of the complex are measured and discussed.

Keywords

References

  1. Munakata, M.; Wu, L. P.; Kuroda-Sowa, T. Adv. Inorg. Chem. 1999, 46, 173
  2. Jung, O.-S.; Park, S. H.; Park, C. H.; Park, J. K. Chem. Lett. 1999, 923
  3. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Chae, H. K.; Jang, H. G.; Hong, J. K. Inorg. Chem. 2001, 40, 2105 https://doi.org/10.1021/ic001072u
  4. Jung, O.-S.; Kim, Y. J.; Kim, K. M.; Lee, Y.-A. J. Am. Chem. Soc. 2002, 124, 7906 https://doi.org/10.1021/ja026774s
  5. Lee, Y.-A.; Kim, S. A.; Jung, S. M.; Jung, O.-S.; Oh, Y. H. Bull. Korean Chem. Soc. 2004, 25, 581 https://doi.org/10.1007/s11814-008-0098-y
  6. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Kang, S. W.; Choi, S. N. Cryst. Growth & Des. 2004, 4, 23 https://doi.org/10.1021/cg0341048
  7. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Park, K.-M.; Lee, S. S. Inorg. Chem. 2003, 42, 844 https://doi.org/10.1021/ic025935q
  8. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Park, J. K.; Chae, H. K. J. Am. Chem. Soc. 2000, 122, 9921 https://doi.org/10.1021/ja001618b
  9. Benson, D. A.; Karsch-Mirrachi, I.; Lipman, D. J.; Ostell, J.; Rapp, B. A.; Wheeler, D. L. Nucl. Acids Res. 2000, 28, 15 https://doi.org/10.1093/nar/28.1.15
  10. Plappert, E. C.; Mingos, D. M. P.; Lawrence, S. E.; Williams, D. J. Dalton Trans. 1997, 2119
  11. Darr, J. A.; Poliakoff, M.; Li, W.-S.; Blake, A. J. Dalton Trans. 1997, 2869
  12. Zu, H.-L.; Wang, X.-J.; Liu, X.-Y.; Wang, D.-Q. Syn. React. Inorg. Met.-Org. Chem. 2003, 33, 1417 https://doi.org/10.1081/SIM-120024319
  13. Eisler, D. J.; Puddephatt, R. J. Inorg. Chem. 2005, 44, 4666 https://doi.org/10.1021/ic050095b
  14. Eisler, D. J.; Kirby, C. W.; Puddephatt, R. J. Inorg. Chem. 2003, 42, 7626 https://doi.org/10.1021/ic034717+
  15. Yoon, Y.; Won, J.; Kang, Y. Macromolecules 2000, 33, 3185 https://doi.org/10.1021/ma0000226
  16. Sheldrick, G. M. SHELXS-97: A Program for Structure Determination; University of Gottingen, Germany, 1997; Sheldrick, G. M. SHELXL-97: A Program for Structure Refinement; University of Gottingen, Germany, 1997
  17. Lee, S.-g. Chem. Comm. 2006, 1049
  18. Lee, S.-g. Chem. Comm. 2006, 1049

Cited by

  1. Syntheses and Structural Studies of 1:1 (M:L) Silver(I) and 1:2 Nickel(II) Complexes with Tripodal Amide Ligand vol.28, pp.12, 2006, https://doi.org/10.5012/bkcs.2007.28.12.2546
  2. Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2 vol.22, pp.21, 2006, https://doi.org/10.1039/d0gc02667k