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초정밀 스프레이 방법을 이용한 단일벽 탄소나노튜브 pH센서 개발

Development of single walled-carbon nanotubes based pH sensor using ultra-precision spray method

  • 권재홍 (고려대학교 공과대학 전자.전기공학과) ;
  • 이경수 (고려대학교 이과대학 물리학과) ;
  • 이윤희 (고려대학교 이과대학 물리학과) ;
  • 주병권 (고려대학교 공과대학 전자.전기공학과)
  • Kwon, Jae-Hong (School of Electrical Engineering, College of Engineering, Korea University) ;
  • Lee, Kyong-Soo (College of Science, Department of Physics, Korea University) ;
  • Lee, Yun-Hi (College of Science, Department of Physics, Korea University) ;
  • Ju, Byeong-Kwon (School of Electrical Engineering, College of Engineering, Korea University)
  • 발행 : 2006.03.31

초록

Recent studies demonstrated the ability of carbon nanotube (CNT) to promote electron transfer reactions of important compounds and to impart higher stability onto electrochemical sensors. CNT-based sensors measured by hydroxyl radical concentration or pH value suggest great promise for biosensors. This paper describes a new method for fabricating a very simple and inexpensive pH sensor compose of single walled-carbon nanotubes (SW-CNTs) using an ultra-precision spray. CNT-based sensor shows pH sensitivity in buffer solution at different pH range. Our experimental results show the sensor responses to pH buffer solution and the conductance of depends on the pH values. These results support application possibility of SW-CNTs based pH sensor for mass production.

키워드

참고문헌

  1. Iijima, S., 'Helical microtubules of graphitic carbon', Nature, vol. 354, pp. 56-58, 1991 https://doi.org/10.1038/354056a0
  2. M. Baxendale, 'The physics and applications of carbon nanotubes', Journal of Materials Science: Materials in Electronics, vol. 14, pp. 657-659, 2003 https://doi.org/10.1023/A:1026158432563
  3. B. Chung, H. Cho, S. Lee, T.-Y. Ko, J.-Y. Lee, D. Jeon, K.-R. Lee, B. K. Joo, and M. H. Oh, 'Silicon field emitters coated with diamond-like carbon', Journal de Physique IV, vol. 6, pp. C5/85-C5/89, 1996
  4. J. H. Sung, H. S. Kim, H.-J. Jin, H. J. Choi, and I.-.J. Chin, 'Nanofibrous membranes prepared by multiwalled carbon nanotube/poly(methyl methacrylate) composites', Macromolecules, vol. 37, no. 26, pp. 9899-9902, 2004 https://doi.org/10.1021/ma048355g
  5. Y. H. Lee, Y. T. Jang, D. H. Kim, J. H. Ahn, and B. K. Ju, 'Realization of gated field emitters for electrophotonic applications using carbon nanotube line emitters directly grown into submicrometer holes', Advanced Materials, vol. 13, no. 7, pp. 479-482, 2001 https://doi.org/10.1002/1521-4095(200104)13:7<479::AID-ADMA479>3.0.CO;2-H
  6. W. S. Cho, S. I. Moon, Y. D. Lee, Y. H. Lee, S. W. Kim, J. H. Park, and B. K. Ju, 'Multi-wall carbon nanotube gas sensor fabricated using thermomechanical structure', IEEE Electron Device Letters, vol. 26, pp. 498-500, 2005 https://doi.org/10.1109/LED.2005.851095
  7. M. M. Waje, X. Wang, W. Li, and Y. Yan, 'Deposition of platinum nanoparticles on organic functionalized carbon nanotubes grown in situ on carbon paper for fuel cells', Nanotechnology, vol. 16, no. 7, pp. S395-S400, 2005 https://doi.org/10.1088/0957-4484/16/7/013
  8. J. Appenzeller, J. Knoch, R. Martel, V. Derycke, S. J. Wind, and P. Avouris, 'Carbon nanotube electronics', IEEE Transactions On Nanotechnology, vol. 1, no. 4, pp. 184-189, 2002 https://doi.org/10.1109/TNANO.2002.807390
  9. A. S. Claye, J. E. Fischer, C. B. Huffman, A. G. Rinzler, and R. E. Smalley, 'Solid-state electrochemistry of the Li single wall carbon nanotube system', Journal of the Electrochemical Society, vol. 147, no. 8, pp. 2845-2852, 2000 https://doi.org/10.1149/1.1393615
  10. C. Nutzenadel, A. ZUttel, D. Chartouni, and L. Schlapbach, 'Electrochemical storage of hydrogen in nanotube materials', Electrochemical and Solid-State Letters, vol. 2, no. 1, pp. 30-32, 1999 https://doi.org/10.1149/1.1390724
  11. K. H. An, W. S. Kim, Y. S. Park, Y. C. Choi, S. M. Lee, D. C. Chung, D. J. Bae, S. C. Lim, and Y. H. Lee, 'Supercapacitors using single-walled carbon nanotube electrodes', Advanced Materials, vol. 13, no. 7, pp. 497-50, 2001 https://doi.org/10.1002/1521-4095(200104)13:7<497::AID-ADMA497>3.0.CO;2-H
  12. J. Martinez, T. D. Yuzvinsky, A. M. Fennimore, A. Zettl, R. Garcia, and C. Bustamante, 'Length control and sharpening of atomic force microscope carbon nanotube tips assisted by an electron beam', Nanotechnology, vol. 16, no. 11, pp. 2493-2497, 2005 https://doi.org/10.1088/0957-4484/16/11/004
  13. 나필선, 김효진, 이영화, 이정오, '단겹탄소나노튜브 트랜지스터의 나노습도센서 응용가능성 연구', 센서학회지, 제14권, 제5호, pp. 331-335, 2005 https://doi.org/10.5369/JSST.2005.14.5.331
  14. T. W. Odorn, J.-L. Huang, C. L. Cheung, and C. M. Lieber, 'Magnetic clusters on single-walled carbon nanotubes: The kondo effect in a one-dimensional host', Science, vol. 290, no. 5496, pp. 1549-1552, 2000 https://doi.org/10.1126/science.290.5496.1549
  15. M. Meyyappan, 'Carbon nanotubes science and application', New York CRC Press, 2005
  16. P. S. Patil, R. K. Kawar, and S. B. Sadale, 'Effect of substrate temperature on electrochromic properties of spray-deposited Ir-oxide thin films', Applied Surface Science, vol. 249, pp. 367-374, 2005 https://doi.org/10.1016/j.apsusc.2004.12.014
  17. M. Yuqing, C. Jianrong, and F. Kerning, 'New technology for the detection of pH', Journal of Bio-chemical and Biophysical Methods, vol. 63, no. 1, pp. 1-9, 2005 https://doi.org/10.1016/j.jbbm.2005.02.001
  18. 이정민, 이명, 이상학, 김영선, 김창진, 이부형, '실리카 졸-겔막을 이용한 pH 광학센서', 센서학회지, 제13권, 제3호, pp. 169-174, 2004 https://doi.org/10.5369/JSST.2004.13.3.169
  19. 이봉수, 홍주영, 황영묵, 조승현, '내시경용 광섬유 pH 측정 센서 개발을 위한 기초 연구', 센서학회지, 제13권, 제3호, pp. 213-217, 2004 https://doi.org/10.5369/JSST.2004.13.3.213
  20. K. Besteman, J.-O. Lee, F. G. M. Wiertz, H. A. Heering, and C. Dekker, 'Enzyme-coated carbon nanotubes as single-molecule biosensors', Nano Letters, vol. 3, no. 6, pp. 727-730, 2003 https://doi.org/10.1021/nl034139u
  21. T. Someya, J. Small, P. Kim, C. Nuckolls, and J. T. Yardley, 'Alcohol vapor sensors based on singlewalled carbon nanotube field effect transistors', Nano Letters, vol. 3, no. 7, pp. 877-881, 2003 https://doi.org/10.1021/nl034061h
  22. Q. Fu and J. Liu, 'Integrated single-walled carbon nanotube/microfluidic devices for the study of the sensing mechanism of nanotube sensors', Journal of Physical Chemistry B(Letter), vol. 109, no. 28, pp. 13406-13408, 2005 https://doi.org/10.1021/jp0525686
  23. H. Pan, Y. P. Feng, and J. Y. Lin, 'Ab initio study of OH-functionalized single-wall carbon nanotubes', Physical Review B, vol. 70, p. 245425-245429, 2004 https://doi.org/10.1103/PhysRevB.70.245425
  24. T. Hertel, R. E. Walkup, and P. Avouris, 'Deformation of carbon nanotubes by surface van der Waals forces', Physical Review B, vol. 58, pp. 13870-13873, 1998 https://doi.org/10.1103/PhysRevB.58.13870
  25. Q. Ngo, D. Petranovic, S. Krishnan, A. M. Cassell, Q. Ye, J. Li, M. Meyyappan, and C. Y. Yang, 'Electron transport through metal?multiwall carbon nanotube interfaces', IEEE Transactions on Nanotechnoloty, vol. 3, no. 2, pp. 311-317, 2004 https://doi.org/10.1109/TNANO.2004.828553
  26. R. Qiao and N. R. Aluru, 'Atypical dependence of electroosmotic transport on surface charge in a single-wall carbon nanotube', Nano Letters, vol. 3, no. 8, pp. 1013-1017, 2003 https://doi.org/10.1021/nl034236n
  27. G. H. Bolt, 'Determination of the charge density of silica sols', Journal of Physics Chemistry, vol. 61, pp. 1166-1169, 1957 https://doi.org/10.1021/j150555a007