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Gas sensing characteristics of thin film SnO2 sensors with different pretreatments

예비 처리 방법에 따른 박막 SnO2 센서의 가스 감응 특성

  • Yun, Kwang-Hyun (Department of Materials Science and Metallurgy, Kyungpook National University) ;
  • Kim, Jong-Won (Department of Nano-sience and Technology, Kyungpook National University) ;
  • Rue, Gi-Hong (School of Electrical Engineering and Computer Science, Kyungpook National University) ;
  • Huh, Jeung-Soo (Department of Materials Science and Metallurgy, Kyungpook National University)
  • 윤광현 (경북대학교 금속공학과) ;
  • 김종원 (경북대학교 나노과학기술과) ;
  • 류기홍 (경북대학교 전자전기컴퓨터학부) ;
  • 허증수 (경북대학교 금속공학과)
  • Published : 2006.09.30

Abstract

The $SnO_{2}$ thin film sensors were fabricated by a thermal oxidation method. $SnO_{2}$ thin film sensors were treated in $N_{2}$ atmosphere. The sensors with $O_{2}$ treatment after $N_{2}$ treatment showed 70 % sensitivity for 1 ppm $H_{2}S$ gas, which is higher than the sensors with only $O_{2}$ treatment. The Ni metal was evaporated on Sn thin film on the $Al_{2}O_{3}$ substrate. And the sensor was heated to grow the Sn nanowire in the tube furnace with $N_{2}$ atmosphere. Sn nanowire was thermally oxidized in $O_{2}$ environments. The sensitivity of $SnO_{2}$ nanowire sensor was measured at 500 ppb $H_{2}S$ gas. The selectivity of $SnO_{2}$ nanowire sensor compared with thin film and thick film $SnO_{2}$ was measured for $H_{2}S$, CO, and $NH_{3}$ in this study.

Keywords

References

  1. K. Y. Youl, G. Y. Cha, N. J. Choi, D. D. Lee, J. C. Kim, and J. S. Huh, 'Sensing properties of $ZrO_2-$ added $SnO_2$ for nerve and blister agent', Journal of the Korean Sensors Society, vol. 13, no. 5, pp. 323-328, 2004 https://doi.org/10.5369/JSST.2004.13.5.323
  2. N. J. Choi, T. H. Ban, J. H. Kwak, Y. T. Lim, B. S. Joo, J. C. Kim, 1. S. Huh, and D. D. Lee, 'Thin film gas sensors based on tin oxide for acetonitril', Journal of the Korean Sensors Society, vol. 13, no. 3, pp. 218-223, 2004 https://doi.org/10.5369/JSST.2004.13.3.218
  3. C. Xu, J. Tamaki, N. Miura, and N. Yamazoe, 'Grain size effects on gas sensitivity of porous $SnO_2$-based elements', Sensors and Actuators B, vol. 3, pp. 147-155, 1991 https://doi.org/10.1016/0925-4005(91)80207-Z
  4. G. Martinelli and M. C. Carotta, 'Sensitivity to reducing gas as a function of energy barrier in $SnO_2$ thick-film gas sensor', Sensors and Actuators B, vol. 7, pp. 717-720, 1992 https://doi.org/10.1016/0925-4005(92)80391-A
  5. J. D. Choi and G. M. Choi, 'Electrical and CO gas sensing properties of layered ZnO-CuO sensor', Sensors and Actuators B, vol. 69, pp. 120-126, 2000 https://doi.org/10.1016/S0925-4005(00)00519-0
  6. J. L. Solis, S. Saukko, L. Kish, C. G. Granqvist, and V. Lantto, 'Semiconductor gas sensors based on nanostructured tungsten oxide', Thin Solid Films, vol. 391, pp. 255-260, 2001 https://doi.org/10.1016/S0040-6090(01)00991-9
  7. N. Savage, B. Chwieroth, A. Ginwalla, B. Patton, S. Akbar, and P. Dutta, 'Composite n-p semiconducting titanium oxides as gas sensors', Sensors and Actuators B, vol. 79, pp. 17-27, 2001 https://doi.org/10.1016/S0925-4005(01)00843-7
  8. J. W. Dailey, J. Taraci, and T. Clement, 'Vapor-liquid- solid growth of germanium nanostructures on silicon', J. Appl. Phys., vol. 96, no. 12, pp. 7556-7567, 2004
  9. J. Wang, J. Sha, Q. Yang, X. Ma, H. Zhang, J. Yu, and D. Yang, 'Carbon-assisted synthesis of aligned ZnO nanowires', Materials Letters, vol. 59, pp. 2710-2714, 2005 https://doi.org/10.1016/j.matlet.2005.04.026
  10. D. Calestani, M. Zha, G. Salviati, L. Lazzarini, L. Zanotti, E. Comini, and G. Sbervegileri, 'Nucleation and growth of $SnO_2$ nanowires', Journal of Crystal Growth, vol. 275, pp. e2083-e2087, 2005 https://doi.org/10.1016/j.jcrysgro.2004.11.269
  11. S. V. Kalinin, J. Shin, S. Jesse, D. Geohegan, and A. P. Baddorf, 'Electronic transport imaging in a multiwire $SnO_2$ chemical field-effect transistor device', J. Appl. Phys., vol. 98, pp. 044503-1-044503-8, 2005 https://doi.org/10.1063/1.2001144
  12. Z. W. Pan, S. S. Xie, L. F. Sun, and G. Wang, 'Direct growth of aligned open carbon nanotubes by chemical vapor deposition', Chemical Physics Letters, vol. 299, no. 1, pp. 97-102, 1999 https://doi.org/10.1016/S0009-2614(98)01240-8
  13. C. J. Lee, J. H. Park, and J. Park, 'Synthesis of bamboo- shaped multiwalled carbon nanotubes using thermal chemical vapor deposition', Chemical Physics Letters, vol. 323, no. 6, pp. 560-565, 2000 https://doi.org/10.1016/S0009-2614(00)00548-0
  14. K. Yanagimoto, S. Sunada, K. Majima, and T. Sawada, 'Effects of $N_2$ mixed gas atomization on electrochemical properties of Mm(Ni,Co,Mn,Al)$_{0.5}$ alloy powder', Journal of Alloys and Compounds, vol. 372, pp. 208-212, 2004 https://doi.org/10.1016/j.jallcom.2003.08.099
  15. E. Atanassova, G. Tyuliev, A. Paskaleva, D. Spassov, and K. Kostov, 'XPS study of $N_2$ annealing effect on thermal $Ta_2O_2$ layers on Si', Applied Surface Science, vol. 225, pp. 86-99, 2004 https://doi.org/10.1016/j.apsusc.2003.09.040

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