Pulping Features of Blue-stained and Fungicide-treated Woods

청변균 및 살균제처리재의 펄프화특성

  • Cho, Nam-Seok (Wood and Paper Science, Agricultural Life Science and Environment College, Chungbuk National University) ;
  • Jeong, Seon-Hwa (Wood and Paper Science, Agricultural Life Science and Environment College, Chungbuk National University)
  • 조남석 (충북대학교 농업생명환경대학 목재종이과학) ;
  • 정선화 (충북대학교 농업생명환경대학 목재종이과학)
  • Published : 2005.09.30

Abstract

This study was performed to understand the changes in wood extractives, mainly acetone extracts, in pine woods (Pinus densiflora and Pinus rigida) treated by three blue stain fungi (BSF) such as native BSF in Korea, Leptographium sp., screened Albino strain(BSFcs-1) and commercial Cartapip and fungicide, Wood guard. In addition their pulping and bleaching properties were investigated. BSF treatment has significantly reduced acetone extracts, $25.1{\sim}30.4%$ decreasing in red pine and $22.9{\sim}28.1%$ in pitch pine. Three week aging treatment showed about 20% decreasing in red pine and 19.3% in pitch pine. There were not so significant differences in extracts reduction among native BSF and Albino-type strains (Albino strain, BSFcs-1, and commercial Cartapip). But fungicide, Wood guard, treated wood showed relatively lower decreasing rates of extractives, 14% in red pine and 10.1% in pitch pine. Therefore it is understandable that the fungicide could protect the wood from blue stain fungi attack, but has no effect on its extractive reduction. Concerned to pulping properties of BSF and fungicide treated woods, red pine and pitch pine, optimum pulping condition was 20% active alkali, wood to liquor ratio 1 to 6, $170^{\circ}C$, and 2.5 hr. In the case of BSF woods, optimum pulping condition was same as the sound wood, $43.5{\sim}45%$ of pulp yields and $1.3{\sim}1.45%$ of rejects. Screened pulp yield of fungicide treated wood was lower than those of BSF treated woods. Rejects in pulps were higher in fungicide-treated wood than BSF treated woods. Bleaching pulp yields were ranged of 92 to 93.5%. BSF, Cartapip and fungicide treated woods resulted in lower brightness of $55{\sim}58%$, but Albino-type strain(BSFcs-1) $61.3{\sim}62.3%$, very similar to untreated one. Therefore bleaching chemicals could be saved in the processing of chemical pulping.

Keywords

References

  1. Murdoch, C.W., Alternatives to Petroleum-Based Biocides for Protecting Hardwood Lumber and Manufactured Products/Transferring Technologies for Industry No. 4, US National Agricultural Library Catalog. ISSN 1064-3451 (1992)
  2. Farrel, R.L., Mulcahy, J., and Nobbs, R., Research in progress: resin degradation and brightness increase of radiata pine with fungal treatment in lab and mill trials. In: Proceed. of Intern. Symp, On Environmentally Friendly and Emerging Technologies for a Sustainable Pulp and Paper Industry, April 25-27, 2000, Taipei, pp.279-284 (2000)
  3. Pashenova, N., Lee, Iong-Kyu, and Cho, Nam-Seok. Frequency of blue staining fungi isolated from pine trees of experimental forests in Kangwon National University and its resistance to fungicide, Wood guard. Mokchae Konghak 33(2): 56-64 (2005)
  4. Chakravarty, P., Trifonov, L., and Hutchison, L.J., Role of Sporormiella similis as a potential bioprotectant of Populus tremelloides wood against the blue-stain fungus Ophiostoma piliferum. Can. J, For. Res. 24: 2235-2239 (1994) https://doi.org/10.1139/x94-286
  5. Chidester, G.H., Bray, M.W., and Curran, C.E., Characteristics of sulfite and kraft pulps from blue-stained southern pine. Paper Trade J, 106(14): 43-46 (1938)
  6. Blanchette, R.A., Farrel, R.L., and Burness, T.A., Biological control of pitch in pulp and paper production by Ophiostoma piliferum. Tappi J. 75(12): 102 -106 (1992)
  7. Seifert, K.A., Hamilton, W.E., Breuil, C. and Best, M., Evaluation of Bacillus subtilis C186 as a potential biological control of sapstain and mould on unseasoned lumber. Can. J. Microbiol. 33(12): 1102 -1107 (1987) https://doi.org/10.1139/m87-192
  8. Seifert, K.A. Sapstain of commercial lumber by species of Ophiostorna and Ceratocystis. In: Ceratocystis and Ophiostoma: Taxonomy, Ecology, and Pathogenisity. M.J, Wiengfield, K.A. Seifert and J.F. Webber, eds. American Phytopathological Society, St. Paul, MN. pp.141 -151 (1983)
  9. Fischer, K., Akhtar, M., Blanchette, R.A., Burnes, T.A., Messner, K., and Kirk, T.K., Reduction of resin content in wood chips during experimental biological pulping processes. Holzforschung 48(3): 285-290 (1994) https://doi.org/10.1515/hfsg.1994.48.4.285
  10. Rocheleau, M.J., Sitbole, B.B., Allen, L.H., Iverson, S., Farrel, R.L., and Noel, Y., Fungal treatment of aspen chips for wood resm reduction: a laboratory evaluation. JPPS 24(2): 37 -42 (1998)
  11. Farrel, R.L., Blanchette, R.A., and Brush, T.S., Cartapip: a biopulping product for control of pitch and resin acid problems in pulp mills. J. Biotechnol. 30: 115-122 (1993) https://doi.org/10.1016/0168-1656(93)90032-I
  12. Chen T., Wang, Z., Gao, Y., Breuil, C., and Hatton, J.V., Wood extractives and pitch problems: analysis and partial removal by biological treatment. Appita 46: 463 -466 (1994)
  13. Martinez-Inigo, M.J., Immerzeel, P., Gutierrez, A., Rio, J.C. del, and Sierra- Alvarez, R., Biodegradability of extractives in sapwood and heartwood from Scots pine by sapstain and white rot fungi. Holzforschung 53(3): 247-252 (1999) https://doi.org/10.1515/HF.1999.042
  14. Dorado, J. Degradation and detoxification of softwood extractives by sapstain fungi. Bioresource Technol. 71: 13 -20 (2000) https://doi.org/10.1016/S0960-8524(99)00060-7
  15. Behrendt, C.J., and Blanchette, R.A, Biological processing of pine logs for pulp and paper production with Phlebiopsis gigantea. Appl. Environ. Microbiol. 63(5): 1995-2000 (1997)
  16. Behrendt C.J., Blanchette, R.A., and Farrel, R.L., Biological control of blue stain fungi in wood. Phytopathology. 85: 92-97 (1995) https://doi.org/10.1094/Phyto-85-92
  17. Behrendt, C.J., Blanchette, R.A., and Farrel, R.L., An integrated approach using biological and chemical control to prevent blue stain in pine logs. Can. J. Bot. 73: 613-619 (1995) https://doi.org/10.1139/b95-065
  18. Wall, M.B., Stafford, G., Noel, Y., Fritz, A, Iverson, S., and Farrell, R.L., Treatment with Ophiostoma piliferum improves chemical pulping efficiency. Proc. 6th Intern'l Conf. Biotechnol. in the Pulp and Paper Industry. Vienna, Austria, June 1995. pp.205 -210 (1995)
  19. Pashenova, N., Lee, Jong- Kyu, and Cho, Nam-Seok, Decolorization of blue-stain by dual culture of blue staining and basidial Fungi. Mokchae Konghak 33(2): 65-71 (2005)
  20. Lee, Jong- Kyu, and Oh, Eun-Sung. Potentials for biological control of blue stain on woods caused by Ophiostomatoid fungi. Plant Pathol. J. 16(4): 200-205 (2000)
  21. 조남석, 이종규. 고백색도 종이생산을 위한 목재칩의 생물학적 변색방지 기술연구. 한국과학재단 특정연구 최종보고서 (2004)
  22. Bounous, E.P., and Carter, R.M., Wood bleaches and bleaching methods. In: Proc. finishing eastern hardwoods (R.M. Carter ed.). Forest Products Society, Madison, WI, USA, pp.26-36 (1983)
  23. Lee, B.G., Maristany, A., Brunner, C.C., and Morrell, J.J., Removing fungal stain from ponderosa pine by caustic bleaching. Forest Products J. 45(3): 56-60 (1995)
  24. 김규혁, 김형준, 나종범, 김재진. 표백에 의한 라디에타소나무의 청변제거. 목재공학 31(1):46-51 (2003)
  25. Zabel, R.A., and Morrell, J.J., Wood Microbiology: Decay and its prevention. Academic press, Inc. San Diego, CA, USA (1992)
  26. Song, Y.S., Ra, J.B., Kim, H.J., Kim, J.- J., and Kim, G.H., Sapstain and mold control on Korean pine lumber: laboratory and field tests of selected anti-stain chemicals. Proc. IAWPS 2003. Daejeon, Korea, Vol 1, pp.510 -516 (2003)
  27. Gutierrez, A, Rio, J.C. del, Martinez, M.J, and Martinez, A, The biotechological control of pitch in paper pulp manufacturing. Trends in Biotechnology 19(9): 340-348 (2001) https://doi.org/10.1016/S0167-7799(01)01705-X
  28. Wall, M.B., Brecker, J., Fritz, A., Iverson, S., and Noel, Y., Chemical pulping of Ophiostoma pillferum treated woods. Proc. Tappi Biological Sci. Symp. Atlanta, Georgia, USA pp.67 -76 (1994)