폴리머 (Polymer(Korea))

  • 제29권2호
  • /
  • Pages.216-220
  • /
  • 2005
  • /
  • 0379-153X(pISSN)
  • /
  • 2234-8077(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

폴리(에틸렌 글리콜) 디아크릴레이트/이온성 액체 젤형 고분자전해질의 제조 및 특성 연구

A Study on the Preparation and Characterization of Gel Polymer Electrolyte from Poly(ethylene glycol) Diacrylate in Sonic Liquid

  • 신보라 (성균관대학교 화학공학과) ;
  • 조미숙 (성균관대학교 화학공학과) ;
  • 김덕준 (성균관대학교 화학공학과) ;
  • 심상준 (성균관대학교 화학공학과) ;
  • 김지흥 (성균관대학교 화학공학과) ;
  • 이동현 (성균관대학교 화학공학과) ;
  • 남재도 (성균관대학교 고분자공학과) ;
  • 이영관 (성균관대학교 화학공학과)
  • Shin Bora (Department of Chemical Engineering, Sungkyunkwan University) ;
  • Cho Mi Suk (Department of Chemical Engineering, Sungkyunkwan University) ;
  • Kim Dukjoon (Department of Chemical Engineering, Sungkyunkwan University) ;
  • Sim Sang Jun (Department of Chemical Engineering, Sungkyunkwan University) ;
  • Kim Ji-Heung (Department of Chemical Engineering, Sungkyunkwan University) ;
  • Lee Dong Hyun (Department of Chemical Engineering, Sungkyunkwan University) ;
  • Nam Jae-Do (Department of Polymer Science k Engineering, Sungkyunkwan University) ;
  • Lee Youngkwan (Department of Chemical Engineering, Sungkyunkwan University)
  • 발행 : 2005.03.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

본 연구에서는 폴리(에틸렌 글리콜) 디아크릴레이트(PEGDA) 고분자 매트릭스에 이온성 액체인 1-butyl-3-methyl-imidazolium bis((trifluoromethyl) sulfonyl) amide$(BuMeIm^+Tf_2N^-)$로 구성된 전해질 용액을 함유하는 젤 형태의 고분자 전해질을 제조하였다. 이온성 액체가 고분자 전해질의 이온 전도도에 미치는 영향을 조사하였으며, 기존의 유기 용매를 넣은 고분자 전해질보다 높은 이온 전도도$(ca.\;10^{-3}S/cm)$와 전기 화학적 안정성을 나타냄을 알 수 있었다.

A new type of polymer gel electrolyte was prepared from poly(ethylene glycol) diacrylate(PEGDA) and 1-butyl-3-methylimidazolium bis((trifluorornethyl) sulfonyl) amide$(BuMeIm^+Tf_2N^-)$ ionic liquid. The effect of the ionic liquid on ionic conductivity of the gel polymer electrolyte was investigated. It was observed that the gel polymer electrolyte having the ionic liquid exhibited higher ionic conductivity $(ca.\;10^{-3}S/cm)$ as well as electrochemical stability than that using organic solvent.

키워드

참고문헌

  1. K. Murata, S. Izuchi, and Y. Yoshihisa, Electrochim. Acta, 45, 1501 (2000)
  2. A. M. Voice, J. P. Southall, V. Rogers, and K. H. Matthews, Polymer, 35, 3363 (1994)
  3. K. M. Abraham and M. Alamgir, J. Power Sources, 43, 195 (1993)
  4. M. Kono, M. Nishiura, and E. Ishiko, J. Power Sources, 81, 748 (1999)
  5. M. Kono, M. Nishiura, and E. Ishiko, Electrochim. Acta, 45, 1307 (2000)
  6. M. Alamgir and K. M. Abraham, J. Electrochem. Soc., 140, L96 (1993)
  7. Y. Kang and C. Lee, Polymer Science and Technology, 14, 396 (2003)
  8. H. R. Jung and M. S. Cho, J. H. Ahn, J. D. Nam, and Y. Lee, J. Appl. Polym. Sci., 91, 894 (2004)
  9. M. S. Cho, B. Shin, J. D. Nam, Y. Lee, and K. Song, Polymer International, 53, 1523 (2004) https://doi.org/10.1002/pi.1421
  10. M. S. Cho, B. Shin, S. D. Choi, Y Lee, and K. G. Song, Electrochimica Acta, 50, 331 (2004)
  11. R. Ryati and R. W. Murry, J. Electrochem. Soc., 143, 401 (1996)
  12. M. Watanabe and T. Mizumura, Solid State Ionics, 86, 353 (1996)
  13. A. Noda and M. Watanabe, Electrochim. Acta, 45, 1265 (2000)
  14. J. Sun, D. R. MacFarlane, and M. Forsyth, Solid State Ionics, 147, 333 (2002)
  15. T. Welton, Chem. Rev., 99, 2071 (1999)
  16. J. H. Davis and P. A. Fox, Chem. Comun., 11, 1209 (2003)
  17. K. R. Seddon et al., Chem. Comm., 19, 2097 (1998)
  18. C. Lagrost, D. Carrie, M. Vaultier, and P. Happiot, J. Phys. Chem. A, 107, 745 (2003)
  19. U. Schroder, R. G. Compton, F. Marken, S. D. Bull, S. G. Davies, and S. Gilman, J. Phys. Chem. B, 105, 1344 (2001) https://doi.org/10.1021/jp0035840
  20. B. M. Quinn, Z. Ding, R. Moulton, and A. J. Bard, Langmuir, 18, 1734 (2002)
  21. P. Bonhote, A. P. Dias, N. Papageorgiou, K. Kalyasundaram, and M. Gratzel, Inorg. Chem., 35, 1168 (1996)
  22. C. Tiyapiboonchaiya, D. R. MacFarlane, J. Sun, and M. Forsyth, Macromol Chem. Phys., 203, 1906 (2002)
  23. J. Fuller, A. C. Breda, and R. T. Carlin, J. Electroanal. Chem, 459, 29 (1998)
  24. J. Kim, S. Moon, B. Jin, H. Gu, and M. Yun, J. of KIEEME(in Korean), 8, 487 (1995)
  25. J. H. Shin, W. A. Henderson, and S. Passerini, Electrochem. Commun., 5, 1016 (2003)
  26. D. R. MacFarlane, J. Huang, and M. Forsyth, Nature, 402, 792 (1999)
  27. S. Rajendran, M. Sivakumar, and R. Subadevi, Mater. Lett., 58, 641 (2004)