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고도정수처리공정에서 오존의 유기물 분해능

Decomposition of Organic Matters by Ozonation in Advanced Water Treatment Process

  • 윤태경 (동의대학교 환경공학과) ;
  • 이강춘 (동의대학교 환경공학과) ;
  • 노병일 (동서대학교 화학공학과)
  • Yoon Taekyung (Department of Environmental Engineering, Dong-eui University) ;
  • Lee Gangchoon (Department of Environmental Engineering, Dong-eui University) ;
  • Noh Byeongjil (Department of Chemical Engineering, Dongseo University)
  • 발행 : 2005.03.01

초록

The performance of ozone contactor in ozone-BAC advanced water treatment process was evaluated by the degree of decomposition of organic matters. The degree was measured by the analyses of $UV_{254}$ absorbance and the concentrations of DOC and BDOC for the sand filtered water and the ozone treated water, respectively. In addition, the ozone concentration in the contactor, required for the maximum BDOC concentration, was selected as the optimum concentration, and the appropriate residential time of ozone treated water in a reservoir was recommended based on the residual ozone concentration in the treated water. The following results were obtained from the pilot scale experiments. By ozonation $UV_{254}$ absorbance was decreased, and BDOC concentration was increased. The change of DOC concentration by ozonation was negligible, but the excess input of ozone resulted in the removal of the small amount of BDOC by complete oxidation. The optimum ozone concentration was 0.58mg $O_3/mg$ DOC. In order to remove residual ozone, 20minutes of the residential time were enough after ozonation.

키워드

참고문헌

  1. 이성우, 이현동, 한명호, 곽동희, 김충한, 2003, 고도상수처리 원리 및 응용, 동화기술, 31pp
  2. Clark, R. M. and B. W. Lykins, Jr., 1998, Granular Activated Carbon: Design, Operation and Cost, Lewis Publishers, Inc., 205-233pp
  3. 한무영, 강창호, 1993, 생물활성탄 (Biological Activated Carbon, BAC) 공정과 이 공정의 음용수처리에의 사용, 대한상하수도학회지, 7(1), 77-103
  4. 김동윤, 1996, 덕산정수장 고도정수처리시 타당성 조사 및 기본계획 보고서, 부산광역시 상수도사업본부
  5. 서연태, 정동환, 임성균, 박규홍, 2001, 막분리를 이용한 정수처리공정의 생산원가에 관한 고찰, 한국물환경학회지, 17(3), 283-297
  6. 환경부 수도정책과, 2003, 고도정수처리 설치사업, 환경부 환경관리분야 자료목록
  7. 宗宮 功 편저, 강준원, 구자용, 최승일, 정재춘, 육운수 공역, 2002, 오존을 이용한 수처리기술, 동화기술, 115-142pp
  8. Servais P., G. Billen, C. Ventresque and G. P. Bablon, 1991, Microbial Activity in GAC Filters at The Choisy-le-roi Treatment Plant, J. AWWA, 83(2), 62-68
  9. Clipparone, L. A., A. C. Diehl and G. E. Speitel, Jr., 1997, Ozonation and BDOC removal: effect on water quality, J. AWWA, 89(2), 84-97
  10. Nishijima, W., T. Mukaidani and M. Okada, 2003, DOC removal by multi-stage ozonation-biological treatment, Water Research, 37, 150-154 https://doi.org/10.1016/S0043-1354(02)00257-9
  11. Calson, K. H. and G. L. Amy, 1997, The Formation of Filter Removable Biodegradable Organic Matter During Ozonation, Ozone Science & Engineering, 19(2), 179-199 https://doi.org/10.1080/01919519708547314
  12. Calson, K. H. and G. L. Amy, 2001, Ozone and biofiltration optimization for multiple objectives, J. AWWA, 93(1), 88-98
  13. Siddiqui M. S., G. L. Amy and B. D. Murphy, 1997, Ozone enhanced removal of natural organic matter from drinking water sources, Water Research, 31(12), 3098-3106 https://doi.org/10.1016/S0043-1354(97)00130-9