한국산업융합학회 논문집 (Journal of the Korean Society of Industry Convergence)

  • 제8권1호
  • /
  • Pages.37-45
  • /
  • 2005
  • /
  • 1226-833X(pISSN)
  • /
  • 2765-5415(eISSN)
한국산업융합학회 (The Korean Society of Industry Convergence)
권호 표지

활성탄 고정층에 있어서 유기용제의 흡착평형

Adsorption Equilibria of Organic Solvent in an Activated Carbon Fixed Bed

  • 김정걸 (계명대학교 대학원 화학공학과) ;
  • 방영해 (영남이공대학 물질향장계열) ;
  • 이영세 (상주대학교 화학공학과)
  • 발행 : 2005.02.28
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초록

Adsorption equilibrium data of pure solvent vapors (n-Hexane, Toluene, MEK) as well as their binary mixtures on activated carbon (sorbonorit $B_4$) were experimentally determined in the range of 293.2~323.2 K and beyond saturated vapor pressure corresponding to experimental temperature. Langmuir, Freundlich, LRC, W-VSM, FH-VSM were estimated for the predication of single component as well as binary mixtuer systems. The isosteric heat of adsorption at infinite dilution of pure n-hexane, toluene, MEK on activated carbon were 45.18, 25.85, 34.62 Kcal/mol, respectively, also, n-hexane-toluene binary adsorption of activated carbon formed an azeotrope at 293.2 K and total pressure 5.1~10.3 mmHg.

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