Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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The Adsorption Properties of Heavy Metal Ions on to Cotton Fabrics Treated with Reactive Anionic Agent

반응형 음이온화제 처리 면직물에 대한 중금속 이온의 흡착특성

  • 김미경 (한국염색기술연구소 염색연구팀) ;
  • 윤석한 (한국염색기술연구소 염색연구팀) ;
  • 김태경 (캘리포니아 주립대학 섬유공학과) ;
  • 임용진 (경북대학교 공과대학 염색공학과)
  • Published : 2005.02.01
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Abstract

Cotton fabric was treated with a reactive anionic agent in order to have anionic sites(-S03-) on it, which made it possible for the fabric to adsorb various cationic materials. In this study, the adsorptivity of various heavy metal ions such as Pb(II), Cd(II), Cr(III), Co(II), Cu(II), Ni (II) and Cr(VI) on the cotton fabrics treated with anionic agent was examined at the various conditions; concentrations of heavy metal ions, pHs of solution, reaction time and temperature. As a result, the adsorptivity of the heavy metal ions on the cotton fabrics treated with the anionic agent was highly increased comparing to that of untreated cotton fabrics. The order of the adsorptivity was as follows: $Pb(II)>Cd(II)>Cu(II)\geqNi(II)\geqCo(II)>Cr(III)\ggCr(VI)$. The adsorption amounts of most heavy metal ions were increased in weak alkaline conditions and were reached to an adsorption equilibrium within 10 ~ 30 minutes. The maximum adsorption ratios of Pb(II) and Cd(II) were respectively 99% and 80% of the initial concentration of heavy metal ions. Therefore the anionized cotton fabrics seem to be utilized as an adsorption fabrics for the removal of heavy metal ions in the waste water.

Keywords

References

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