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Dielectric and Piezoelectric Properties of Low Temperature Sintering PCW-PMN-PZT Ceramics according to MnO2 Addition

MnO2 첨가에 따른 저온소결 PCW-PMN-PZT세라믹스의 유전 및 압전특성

  • Published : 2005.02.01

Abstract

In this study, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, PCW-PMN-PZT ceramics using Li$_2$CO$_3$, Bi$_2$O$_3$, and CuO as sintering aids were manufactured according to the amount of MnO$_2$ addition. Their microstructural, dielectric and piezoelectric properties were investigated. When the sintering aids were added, specimens could be sintered below 95$0^{\circ}C$, but mechanical qualify factor decreased. Therefore, MnO$_2$ was added excessively to the PCW-PMN-PZT ceramics to increase mechanical quality factor. At the sintering temperature of 95$0^{\circ}C$, the density, dielectric constant($\varepsilon$$_{r}$), electromechanical coupling factor(k$_{p}$), mechanical quality factor(Q$_{m}$) and Curie temperature(T$_{c}$) of 0.1 wt% MnO$_2$ added specimen showed the optimal values of 7.75 g/㎤, 1503, 0.57, 1502, and 337, respectively, for multilayer piezoelectric transformer application.ation.n.

Keywords

References

  1. K. Nagata, J. Thongrueng, and K. Kato, 'Evaluation of the reliability of piezoelectric ceramic transformers', Jpn. J. Appl. Phys., Vol. 36, No. 9B, p. 6103, 1997
  2. O. Ohnishi, Y. Sasaki, T. Zaitsu, H. Kishie, and T. Inoue, 'Piezoelectric ceramic transformer for power supply operating in thickness extensional vibration mode', IEICE Trans. Funda., Vol. E77-A, No. 12, p. 2098, 1994
  3. T. Zaitsu, 'AC/DC converter with a piezoelectric transformer', US Patent, No. 5,969,954, 1999
  4. T. Endow and S. Hirose, 'Multilayered piezoelectric transformers for small power supplies', Jpn. Appl. Phys., Vol. 42, No. 9B, p. 6128, 2003
  5. S. Priya, S. Ural, H. W. Kim, K. Uchino, and T. Ezaki, 'Multilayered unipoled piezoelectric transformers', Jpn. J. Appl. Phys., Vol. 43, No. 6A, p. 3503, 2004
  6. R. Zno, L. Li, and Z. Gui, 'Modified cofiring behaviors between PMN-PNN-PZT piezoelectric ceramics and PZT-doped 70Ag-30Pd alloy metallization', Mat. Sci. Eng., Vol. A326, p. 202, 2002
  7. K. Shiratsuyu, K. Hayashi, A. Ando, and Y. Sakabe, 'Piezoelectric characterization of low temperature-fired $Pb(Zr,Ti)O_3-Pb(Ni,Nb)O_3$ ceramics', Jpn. J. Appl. Phys., Vol. 39, No. 9B, p. 5609, 2000 https://doi.org/10.1143/JJAP.39.5609
  8. D. L. Corker, R. W. Whatmore, E. Ringgaard, and W. W. Wolny, 'Liquid-phase sintering of PZT ceramics', J. Euro. Ceram. Soc., Vol. 20. p. 2039, 2000
  9. 류주현, 우원희, 오동언, 정영호, 정광현, 정문영 , 정희승, 'CuO가 PSN-PZT세라믹스의 저온 소결특성에 미치는 영향', 전기전자재료학회논문지, 16권, 12S호, p. 1200, 2003
  10. 정광현, 이덕출, 류주현, '소결조제 변화에 따른 PCW PMN PZT세라믹스의 저온소결 및 압전특성', 전기전자재료학회논문지, 17권, 12 호, p. 1320, 2004
  11. J. H. Yoo, J. L Hong, and S. Suh, 'Effect of $MnO_2$ impurity on the modified $PbTiO_3$ system ceramics for power supply', Sens. Actu., Vol. 78, p. 168, 1999
  12. Y. Matsuo, M. Fujimura, and H. Sasaki, 'Lead titanate ceramics doped with manganese oxide', J. Am. Ceram. Soc., Vol. 48, No. 2, p. 111, 1965
  13. 이미영, 류성림, 류주현, 정광현, 정영호, 홍재일, 윤현상, '$MnO_2$ 첨가에 따른 무연 $Bi(Na,K)TiO_3-SrTiO_3$ 세라믹스의 유전 및 압전특성', 전기전자재료학회논문지, 17권, 10호, p 1056, 2004
  14. B. Jaffe, W. R. Cook, and H. Jaffe, 'Piezoelectric ceramics', Academic Press London, p. 148, 1971