멤브레인 (Membrane Journal)

  • 제15권3호
  • /
  • Pages.187-197
  • /
  • 2005
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  • 1226-0088(pISSN)
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  • 2288-7253(eISSN)
한국막학회 (The Membrane Society of Korea)
권호 표지

분리막 접촉기의 기술 동향

Thends in Membrane Contactors

  • 이규호 (한국화학연구원 분리막 다기능소재 연구센터) ;
  • 김민정 (한국화학연구원 분리막 다기능소재 연구센터) ;
  • 서봉국 (한국화학연구원 분리막 다기능소재 연구센터) ;
  • 박유인 (한국화학연구원 화학공정연구센터) ;
  • 이기섭 (한국화학연구원 분리막 다기능소재 연구센터)
  • Lee Kew-Ho (Membrane & Separation Research Center, Korea Research Institute of Chemical Technology) ;
  • Kim Min-Joung (Membrane & Separation Research Center, Korea Research Institute of Chemical Technology) ;
  • Sea Bongkuk (Membrane & Separation Research Center, Korea Research Institute of Chemical Technology) ;
  • Park You-In (Chemical Engineering Research Center, Korea Research Institute of Chemical Technology) ;
  • Lee Ki-Sub (Membrane & Separation Research Center, Korea Research Institute of Chemical Technology)
  • 발행 : 2005.09.01
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⟨ 이전 논문 다음 논문 ⟩

초록

분리막 접촉기는 액체-액체, 기체-액체와 같이 두 개의 다른 상 사이에 막이 상계면 혹은 상 장벽의 역할을 수행하여 두 상간의 물질전달이 이루어지게 하는 장치이다 분리막 접촉기는 기체-액체 또는 액체-액체 간에 접촉을 통해 안정된 계면을 형성시켜줌으로써 인위적으로 물질전달속도 조절이 가능할 뿐만 아니라 접촉면적이 크고 기존 분리정제 공정의 운전 시 발생할 수 있는 유화(emulsion), 범람(flooding), 편류(channeling), 기포생성(foaming), 그리고 부하(unloading) 등과 같은 기술적 문제점을 보완할 수 있어 이에 대한 연구가 활발히 진행되고 있다. 이에 본 논문에서는 분리막 접촉기가 이용되는 공정과 분리막 접촉기에 사용되는 막의 제조방법, 국내외의 연구동향을 고찰하여 분리공정으로써의 분리막 접촉기에 관한 이해를 높이고자 한다.

A membrane contactor is a device that achieves liquid/liquid or gas/liquid mass transfer without dispersion of one phase within another. This is accomplished by passing the fluids on opposite sides of a microporous membrane. This approach offers a number of important advantages over conventional dispersed phase contactors, including absence of emulsions, no flooding at high flow rates, no unloading at low flow rates, and high interfacial area. This article provides a general review of membrane contactors, including operating principles and applications.

키워드

참고문헌

  1. A. Gableman and S.- T. Hwang, 'Hollow fiber membrane contactors', J. Membrane Sci., 159, 61 . (1999)
  2. A. Kumar and A. M. Sastre, in: A. K. SenGupta, Y. Marcus (Eds.), 'Developments in Non-Dispersive Membrane Extraction-Separation Processes, Ion Exchange and Solvent Extraction', Marcel Dekker, New York (2001)
  3. A. Kumara, R. Haddada, F. J. Alguacilb, and A. M. Sastre, 'Comparative performance of non-dispersive solvent extraction using a single module and the integrated membrane process with two hollow fiber contactors', J. Membrane Sci., 248, 1 (2005)
  4. H. B. Ding, P. W. Carr, and E. L. Cussler, 'Racemic leucine separation by hollow-fiber extraction', AIChE J., 38(10), 1493 (1992)
  5. M. Matsumura and H. Markl, 'Elimination of ethanol inhibition by perstraction', Biotech. Bioeng., 28, 534 (1986)
  6. G. Vatai and M. N. Tekic, 'Membrane-based ethanol extraction with hollow-fiber module', Sep. Sci. Technol., 26(7), 1005 (1991)
  7. R. Prasad and K. K. Sirkar, 'Hollow fiber solvent extraction of pharmaceutical products: a case study', J. Membrane. Sci., 47, 235 (1989)
  8. R.-S. luang and H.-L. Huang, 'Mechanistic analysis of solvent extraction of heavy metals in membrane contactors', J. Membrane Sci., 213, 125 (2003)
  9. Z.-F. Yang, A. K. Guha, and K. K. Sirkar, 'Novel membrane-based synergistic metal extraction and recovery processes', Ind. Eng. Chem. Res., 35, 1383 (1996)
  10. K. Yoshizuka, K. Kondo, and F. Nakashio, 'Effect of interfacial reaction on rates of extraction and stripping in membrane extractor using a hollow fiber', J. Chem. Eng. Jpn., 19(4), 312 (1986)
  11. C. H. Yun, R. Prasad, A. K. Guha, and K. K. Sirkar, 'Hollow fiber solvent extraction removal of toxic heavy metals from aqueous waste streams', Ind. Eng. Chem. Res., 32, 1186 (1993)
  12. F.-X. Pierre, I. Souchon, and M. Marin, 'Recovery of sulfur aroma compounds using membrane-based solvent extraction', J. Membrane Sci., 187, 239 (2001)
  13. F.-X. Pierre, I. Souchon, V. Athes-Dutour, and M. Marin, 'Membrane based solvent extraction of sulfur aroma compounds: influence of operating conditions on mass transfer coefficients in a hollow fiber contactor', Desalination, 148, 199 (2002)
  14. I. Souchon, V. Athes, F.-X. Pierre, and M. Marin, 'Liquid-liquid extraction and air stripping in membrane contactor: application to aroma compounds recovery', Desalination, 163, 39 (2004)
  15. S. Karoor and K. K. Sirkar, 'Gas absorption studies in microporous hollow fiber membrane modules', Ind. Eng. Chem. Res., 32, 674 (1993)
  16. Z. Qi and E. L. Cussler, 'Microporous hollow fibers for gas absorption. I. Mass transfer in the liquid', J. Membrane. Sci., 23, 321 (1985)
  17. Z. Qi and E. L. Cussler, 'Microporous hollow fibers for gas absorption. II. Mass transfer across the membrane', J. Membrane Sci., 23, 333 (1985)
  18. A. Ito, K. Yamagiwa, M. Tamura, and M. Furusawa, 'Removal of dissolved oxygen using non-porous hollow-fiber membranes', J. Membrane Sci., 145(1), III (1998)
  19. A. Sengupta, P. A. Peterson, B. D. Miller, J. Schneider, and C. W. Fulk Jr., 'Large-scale application of membrane contactors for gas transfer from or to ultrapure water', Sep. and Puri. Tech., 14 (1-3), 189 (1998) https://doi.org/10.1016/S1383-5866(98)00074-4
  20. D. Bhaumik, S. Majumdar, Q. Fan, and K. K. Sirkar, 'Hollow fiber membrane degassing III ultrapure water and microbiocontamination', J. Membrane Sci., 235(1-2), 31 (2004) https://doi.org/10.1016/j.memsci.2003.12.022
  21. Y. M. Lee, J. S. Kang, S. Y. Nam, and C. H. Choi, 'Removal of acetic-acid with amine extractants from fermentation broth using hydrophobic hollow-fiber membrane contactor', Sep. Sci. Tech., 36, 457 (2001)
  22. R. S. Juang, J. D. Chen, and H. C. Huan, 'Dispersion-free membrane extraction case studies of metal ion and organic acid extraction', J. Membrane Sci, 165, 59 (2000)
  23. Z. T. Wu and S. T. Yang, 'Extractive fermentation for butyric acid production from glucose by Clostridium Tyrobutyricum', Biotechnol. Bioeng., 82, 93 (2003)
  24. R. S. Juang, J. D. Chen, and H. C. Huan, 'Dispersion-free membrane extraction-ease-studies of metal-ion and organic-acid extraction', J. Membrane Sci., 165, 59 (2000)
  25. R. S. Juang and J. D. Chen, 'Mass transfer modeling of citric and lactic acids in a microporous membrane extractor', J. Membrane Sci, 164, 67 (2000)
  26. Y. Tong, M. Hirata, H. Takanashi, T. Hano, F. Kubota, M. Goto, F. Nakashio, and M. Matsumoto, 'Extraction of lactic acid from fermented broth with microporous hollow fiber membranes', J. Membrane Sci., 143, 81 (1998)
  27. Y. P. Tong, M. Hirata, H. Takanashi, and T. Hano, 'Back-extraction of lactic-acid with microporous hollow-fiber membrane', J. Membrane Sci., 157, 189 (1999)
  28. H. Escalante, A. I. Alonso, I. Ortiz, and A. Irabien, 'Separation of l-phenylalanine by nondispersive extraction and backextraction-equilibrium and kinetic-parameters', Sep. Sci. Tech., 33, 119 (1998)
  29. H. Escalante and A. Irabien, 'Separation/concentration of lphenylalanine in hollow fibre modules. Decrease of the extraction rate', Solvent Extraction for the 21st Century, Soc. Chem. Ind., Eds. M. Valiente, M. Hidalgo, London (2001)
  30. I. M. Coelhoso, M. M. Cardoso, R. M. C. Viegas, and J. P. S. G. Crespo, 'Transport mechanism and modelling in liquid membrane contactors', Sep. Purif. Tech., 19, 183 (2000)
  31. H. Ding, P. Carr, and E. Cussler, 'Racemic leucine separation by hollow-fiber extraction', AIChE J., 38, 1493 (1992)
  32. D. Rindfleisch, B. Syska, Z. Lazarova, and K. Schugerl, 'Integrated membrane extraction, enzymic conversion and electrodialysis for the synthesis of ampicilin from penicilin G', Process. Biochem., 32, 605 (1997)
  33. D. Maass, M. R. Gerigk, A. Kreutzer, D. WeusterBotz, M. Wubbolts, and R. Takors, 'Integrated I-phenylalanine separation in an E. coli fed-batch process: from laboratory to pilot scale', Bioprocess. Biosyst. Eng., 25, 85 (2002)
  34. M. R. Gerigk, D. Maass, A. Kreutzer, G. Sprenger, J. Bongaerts, M. Wubbolts, and R. Takors, 'Enhanced pilot-scale fed-batch I-phenylalanine production with recombinant Escherichia coli by fully integrated reactive extraction', Bioprocess. Biosyst. Eng., 25, 43 (2002)
  35. R. Takors, 'Model-based analysis and optimization of an ISPR approach using reactive extraction for pilot-scale I-phenylalanine production', Biotechnol. Prog., 20, 57 (2004)
  36. P. H. M. Feron and A. E. Jansen, '$Co_2$separation with polyolefin membrane contactors and dedicated absorption liquids: performances and prospects', Sep. Purif. Tech., 27(3), 231 (2002)
  37. P. V. Danckwerts and M. M. Sharma, 'The absorption of carbon dioxide into solutions of alkalis and amines', Chem. Eng., CE244 (1966)
  38. M. Yang and E. L. Cussler, 'Designing hollowfiber contactors', AIChE J., 32, 1910 (1986)
  39. S. Karoor and K. K. Sirkar, 'Gas absorption studies in microporous hollow fiber membrane modules', Ind. Eng. Chem. Res., 32, 674 (1993)
  40. A. Malek, K. Li and W. K. Teo, 'Modelling of microporous hollow fiber membrane modules', Ind. Eng. Chem. Res., 36, 784 (1997)
  41. K Li, D. wang, C. C. Keo, and W. K Teo, 'Use of asymmetric hollow fibre modules for elimination of $H_2S$ from gas streams via a membrane absorption method', Chem. Eng. Sci., 53(6), 1111 (1998)
  42. D. C. Jackman, C. A. Thomas, D. P. Rillema, S. L. Yau, and R. W. Callahan, 'A comparison between chemically and photochemically driven electron transport reactions in immobilized liquid membranes', J. Membrane Sci., 30, 213 (1987)
  43. M. C. Wijers, M. Jin, M. Wessling, and H. Strathmann, 'Supported liquid membranes modification with sulphonated poly( ether ether ketone) Permeability, selectivity and stability', J. Membrane Sci., 147, 117 (1998)
  44. Dongliang Wang, W. K Teo, and K Li, 'Removal of $H_2S$ to ultra-low concentrations using an asymmetric hollow fibre membrane module', Sep. Purif. Tech., 27, 33 (2002)
  45. P. S. Kumara, J. A. Hogendooma, P. H. M. Feronb, and G. F. Versteega, 'New absorption liquids for the removal of $Co_2$ from dilute gas streams using membrane contactors', Chem. Eng. Sci., 57, 1639 (2002)
  46. D. T. Tsou, M. W. Blachman, and J. C. Davis, 'Silver-facilitated olefin/paraffin separation in a liquid membrane contactor system', Ind. Eng. Chem. Res., 33, 3209 (1994)
  47. A. Figoli, W. F. C. Sager, and M. H. V. Mulder, 'Facilitated oxygen transport in liquid membranes: review and new concepts', J. Membrane Sci., 181, 97 (2001) https://doi.org/10.1016/S0376-7388(00)00675-X
  48. P. Lacan, C. Guizard, P. Le Gall, D. Wettling, and L. Cot, 'Facilitated transport of ions through fixed-site carrier membranes derived from hybrid organic-inorganic materials', J. Membrane Sci., 100, 99 (1995)
  49. M.-J. Kim, Y-I. Park, K-H. Youm, and K-H. Lee, 'Facilitated transport of $Co_2$ through ethylenediamine-fixed cation-exchange polysaccharide membranes', J. Membrane Sci., 245, 79 (2004)
  50. J.-S. Yang and G.-H. Hsiue, 'Swollen polymeric complex membranes for olefin/paraffin separation', J. Membrane Sci., 138, 203 (1998)
  51. C. M. Tun, A. G. Fane, J. T. Matheickal, and R. Sheikholeslami, 'Membrane distillation crystallization of concentrated salts-flux and crystal formation', J. Membrane Sci., 257, 144 (2005)
  52. E. Crucio, A. Criscuoli, and E. Drioli, 'Membrane crystallyzer', Ind. Eng. Chem. Res., 40, 2679 (2001) https://doi.org/10.1021/ie000632u
  53. E. Crucio, G. Di Profio, and E. Drioli, 'Recovery of fumaric acid by membrane crystallyzation in the production of L-malic acid', Sep. Purif. Tech., 33, 63 (2003)
  54. G. Di Profio, E. Crucio, A. Cassetta, D. Lamba, and E. Drioli, 'Membrane crystallyzation of lysozyme: kinetic aspects', J. Cryst. Growth., 257, 359 (2003)
  55. M. L. Druin, J. T. Loft, and S. G. Plovan, 'Novel open-celled microporous film', US Patent 3,801,404, (1974)
  56. K. Kamada, S. Minami, and K. Toshida, 'Porous polypropylene hollow filaments and the method making the same', US Patent 4,055,696, (1977)
  57. M. B. Johnson and G. L. Wilkes, 'Microporous membranes of isotacticpoly( 4-methyl-l-pentene )from a melt-extrusion process. II Effects of thermal annealing and stretching on porosity', J. Appl. Polym. Sci., 84, 1076 (2002)
  58. G. H. Shipman, 'Microporous sheet materials, method of making and articles made therewith', US Patent 4,539,256 (1985)
  59. P. S. T. Machado, A. C. Habert, and C. P. Borges, 'Membrane formation mechanism based on precipitation kinetics and membrane morphology: flat and hollow fiber polysulfone membranes', J. Membrane Sci., 155, 171 (1999)
  60. M. L. Yeow, Y. Liu, and K. Li, 'Preparation of porous PVDF hollow fibre membrane via a phase inversion method using lithium perchlorate ($LiCIO_4$) as an additive', J. Membrane Sci., 258, 16 (2005) https://doi.org/10.1016/j.memsci.2005.04.007
  61. D. Wang, K Li, and W. K Teo, 'Preparation of annular hollow fibre membranes', J. Membrane Sci., 166, 31 (2000)
  62. S.-H. Yeon, K-S. Lee, B. Sea, Y-I. Park, and K-H. Lee, 'Absorption of carbon dioxide characterized using the absorbent composed of piperazine and triethanolamine', Sep. Sci. & Tech., 39, 3281 (2004)
  63. S.-H. Yeon, K.-S. Lee, B. Sea, Y-I. Park, and K.-H. Lee, 'Application of pilot-scale membrane contactor hybride system for removal of carbon dioxide from flue gas', J. Membrane Sci., 257, 156 (2005)