Characteristics of Color and COD Removal of Dyeing Wastewater Using Electrolytically Produced NaOCl Solution (I)

전기분해에 의해 제조된 NaOCl을 이용한 염색폐수의 처리 특성(I)

  • Published : 2005.10.01

Abstract

This study was carried out to investigate the feasibility of using electrolytically generated NaOCl solution for treatment of wastewater containing an acid dye(C.I. Acid Red 114). The NaOCl was produced by the electrolysis of aqueous NaCl solution. In order to asses the treatment characteristics, we evaluated the effect of pH and mixing ratio of the NaOCl solution to colored wastewater on the color and chemical oxygen demand$(COD_{Mn})$ removal. The optimum conditions for the dye and $COD_{Mn}$ removal were determined to be pH 5.0 and mixing ratio of 1 :9, at which more than $88\%$ color and $87\%$ $COD_{Mn}$ were removed within 10 min reaction time. Reaction rate constants for the 300 and 500mg/l of artificially prepared dyeing wastewater were estimated as 0.1764 and $0.1737 min^{-1}$ for color removal and 0.1197 and $0.1436 min^{-1}$ for $COD_{Mn}$ removal, respectively.

Keywords

References

  1. 환경부, '환경통계연감', 2004, pp.118-120
  2. K. Muthukumar, P. S. Sundaram, N. Anantharaman, and C. A. Basha, 'Treatment of Textile Dye Wastewater by Using an Electrochemical Bipolar Disc Stack Reactor', J Chem Technol Biotechnol, 2004, 79, 1135-1141 https://doi.org/10.1002/jctb.1104
  3. A. Hamza and M. F. Hamoda, 'Multiprocess Treatment of Textile Wastewater', Proc. of the 35th Industrial Waste Conference, Purdue Univ., 1980, pp.151-159
  4. R. H. Homing, 'Characterization and Treatment of Textile Dyeing Wastewaters', Textile Chemist & Colorist, 1977, 9(3), 73-76
  5. M. A. Sanroman, M. Pazos, M. T. Ricart, and C. Cameselle, 'Decolourisation of Textile Indigo Dye by DC Electric Current', Engineering Geology, 2005, 77, 253-261 https://doi.org/10.1016/j.enggeo.2004.07.016
  6. A. T. Kuhn, 'Electrolytic Decomposition of Cyanides, Phenols and Thiocyanates in Effluent Streams', J Appl, Chem Biotechnol, 1971, 21, 29-34 https://doi.org/10.1002/jctb.5020210201
  7. T. H. Kim, C. H. Park, and J. W. Lee, 'Pilot Scale Treatment of Textile Wastewater by Combined Pracess(Fludized Biofilm Process-Chemical Coagulation Electrochemical Oxidation)', Water Research, 2002, 36, 3979-3988 https://doi.org/10.1016/S0043-1354(02)00113-6
  8. H. Koukichi, 'Physico-chemical Properties of Electrolyzed Functional Water and Its Application', Fragr J, 1999, 3, 18-22
  9. S. Sakai, 'Application and Development of Electrolyzedoxidizing Water', Food Ind, 1995, 30, 35-43
  10. C. Takahashi, 'Improvement and Application of Sodiumhypochlorite', 泠凍, 2004, 79, 610-614
  11. K. Kamiyama, 'Toxicological Studies of Electrolyzed Water', Food Proc, 1998, 33, 8-9
  12. G. C. White, 'Handbook of Chlorination', Van Nostrand Reinhold Company, 1982, pp.190-201
  13. O. Sumita, Y. H. Hong, Y. H. Kim, and P. Kwon, 'Progress and The Machine', Redox Technology Institute, 2001, 1, 1-7