Dyeing and Fastness Properties of Red Disperse Dyes from Heterocyclic Compounds

헤테로환 아조계 Red 분산염료들의 염색성 및 견뢰도

  • Park Jong Ho (Department of Textile Engineering, NITRI, Konkuk University) ;
  • Lee Kwon Sun (Department of Textile Engineering, NITRI, Konkuk University) ;
  • Koh Joonseok (Department of Textile Engineering, NITRI, Konkuk University) ;
  • Bae Jin-Seok (Korea Dyeing Technology Center) ;
  • Kim Sung Dong (Department of Textile Engineering, NITRI, Konkuk University)
  • 박종호 (건국대학교 공과대학 차세대혁신기술연구원 섬유공학과) ;
  • 이권선 (건국대학교 공과대학 차세대혁신기술연구원 섬유공학과) ;
  • 고준석 (건국대학교 공과대학 차세대혁신기술연구원 섬유공학과) ;
  • 배진석 (한국염색기술연구소 DTP센터) ;
  • 김성동 (건국대학교 공과대학 차세대혁신기술연구원 섬유공학과)
  • Published : 2005.10.01

Abstract

Disperse dyes derived from heterocyclic compounds such as pyridone, diaminopyridine, carbazole, and 2-phenylindole, have been known to possess high light fastness. Four heterocyclic azo disperse dyes were synthesized by using three diaminopyridines and 2-phenylindole as coulping components and their dyeing and fastness properties were compared with an aminoazobenzene disperse dye. The wavelengths of maximum absorption of the synthesized heterocyclic dyes were in the range of 508-528 nm. The molar extinction coefficients of dyes having diaminopyridine were higher than that of an aminoazobenzene disperse dye. The dyes derived from aminopyridine having phenyl group exhibited poor to moderate build-up compared to the aminoazobenzene dye. Wash, light, heat and rubbing fastnesses of heterocyclic azo disperse dyes were good to excellent. The light fastness was improved by 0.5-1 grade by the addition of a UV absorber.

Keywords

References

  1. 특허청, '2002 염.안료 신기술동향 보고서', 2002, pp.34-53
  2. J. H. Park, K. S. Lee, and S. D. Kim, 'Dyeing and Fastness Properties of Alkali Soluble Disperse Dyes Derived from Terephthalic Acid', Text Sci Eng, 2005, 42(1), 41-47
  3. B. Miligan, 'The Degradation of Automotive Upholstery Fabrics by Light and Heat', Rev Prog Coloration, 1986, 16, 1-10 https://doi.org/10.1111/j.1478-4408.1986.tb03738.x
  4. R. D. Wagner, 'Standard Reference Fabrics for Automotive Lightfastness Test Methods', Text Chem Colorist, 1987, 19, 27-30
  5. E. K. Choe, E. J. Son, S. Y. Kim, and C. R. Park, 'The Ecolabelling Scheme for Textile Products-Present Position and Prospects', Fiber Technology and Industry, 1999, 3, 85-103
  6. K. Himeno, Y. Okada, and Z. Morita, 'Photofading of Monoazo Disperse Dyes on Polyester and Polyamide Substrates', Dyes and Pigments, 2000, 45, 109-123 https://doi.org/10.1016/S0143-7208(00)00009-7
  7. S. Abeta, 'Dyes', Dyeing Industry, 1999, 47, 371-385
  8. H. S. Freeman and J. C. Posey, 'An Approach to the Design of Lightfast Disperse Dyes', Dyes and Pigments, 1992, 20, 171-195 https://doi.org/10.1016/0143-7208(92)80044-N
  9. N. S. Allen, 'Developments in Polymer Photochemistry', Applied Science Publisher Ltd., New York, 1980, pp.145-190
  10. A. H. Kehayoglou, E. G. Tsatsaroni, I. C. Eleftheriadis, K. C. Loufakis, and L. E. Kyriazis, 'Effectiveness of Various UV-absorbers in Dyeing of Polyester with Disperse Dyes', Dyes and Pigments, 1997, 34, 207-218 https://doi.org/10.1016/S0143-7208(96)00071-X
  11. S. D. Kim and E. J. Park, 'Relation between Chemical Structure of Yellow Disperse Dyes and Their Lightfastness', Fibers and Polymers, 2001, 2, 159-163 https://doi.org/10.1007/BF02875330
  12. M. A. Weaver and L. Shuttleworth, 'Heterocyclic Diazo Components', Dyes and Pigments, 1982, 3, 81-121 https://doi.org/10.1016/0143-7208(82)80016-8
  13. S. D. Kim, J. H. Park, and E. J. Park, 'Synthesis and Dyeing Properties of Azo Disperse Dyes Using Pyridine Derivatives as Coupling Components', J Korean Fiber Soc, 2000, 37, 293-300
  14. J. H. Park, J. S. Koh, and S. D. Kim, 'Dyeing Properties of Red Disperse Dyes Derived from Pyridine Derivatives', J Korean Soc Dyers Finishers, in press
  15. S. W. Nam, B. Y. Seo, and D. S. Lee, 'Dye Chemistry', Bosungmunhwasa, Seoul, 2004, pp.351-355.