한국섬유공학회지 (Textile Science and Engineering)

  • 제42권4호
  • /
  • Pages.228-234
  • /
  • 2005
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

테레프탈레이트계 폴리에스터의 열분해 거동에 관한 연구

Thermal Degradation Behavior of Poly(alkylene terephthalate)s

  • 김기정 (영남대학교 섬유패션학부) ;
  • 여정섭 (영남대학교 섬유패션학부) ;
  • 윤지영 (영남대학교 섬유패션학부) ;
  • 김준호 (영남대학교 섬유패션학부)
  • 발행 : 2005.08.01
⟨ 이전 논문 다음 논문 ⟩

초록

Thermal degradation behavior of the three homologous polyesters, poly(ethylene terephthalate)(PET), poly(trimethylene terephthalate)(PTT) and poly(butylene terephthalate)(PBT) were investigated by using thermogravimetric analysis(TGA) and pyrolysis-gas chromatography-mass spectrometry(PGC-MS). From the results of isothermal thermogravimetry, it was revealed that PTT has higher activation energy of thermal degradation than the other two polyesters. In PGC-MS analysis, the highly volatile products of the polyesters such as acetaldehyde and acetic acid evolved in the early stage of pyrolysis as common degradation products. Benzoic acid, methyl ester of benzoic acid, terephthalic acid and higher oligomers were produced as the main degradation products of poly(alkylene terephthalate)s at longer pyrolysis times. In isothermal pyrolysis, PTT showed the fastest thermal degradation rate among the three polyesters.

키워드

참고문헌

  1. J. Zhang, 'Study of Poly(trimethylene terephthalate) as an Engineering Thermoplastics Material', J Appl Polym Sci, 2004, 91, 1657-1666 https://doi.org/10.1002/app.13322
  2. B. Wang, C. Y. Li, J. Hanzlicek, S. Z. D. Cheng, P. H. Geli, J. Grebowicz, and R. M. Ho, 'Poly(trimethylene terephthalate) Crystal Structure and Morphology in Different Length Scales', Polymer, 2001, 42, 7171-7180 https://doi.org/10.1016/S0032-3861(01)00046-5
  3. J. C. Kim, T. H. Oh, and J. H. Hyun, 'PTT - New Fibers in 21C', Fiber Technology and Industry, 2002, 6, 29-40
  4. B. S. Seo, 'Next Generation Fiber PTT(I)', Toplon Technical Report, 1999, 2, 26-27
  5. J. H. Kim and W. S. Ha, 'Thermal Degradation Behavior of Poly(ethylene terephthalate)/Poly(butylene terephthalate) Blends System', J Korean Fiber Soc, 1991, 28, 55-64
  6. S. S. Park, D. K. Kim, and S. S. Im, 'Thermal Behavior and Degradation Mechanism of Aromatic', Polymer Degradation and Stability, 2004, 83, 3-10 https://doi.org/10.1016/S0141-3910(03)00166-6
  7. F. Samperi, C. Puglisi, R. Alicata, and G. Montaudo, 'Thermal Degradation of Poly(butylene terephthalate) at the Processing Temperature', Polymer Degradation and Stability, 2004, 83, 11-17
  8. F. Samperi, C. Puglisi, R. Alicata, and G. Montaudo, 'Thermal Degradation of Poly(butylenes terephthalate) at the Processing Temperature', Polymer Degradation and Stability, 2004, 83, 11-17 https://doi.org/10.1016/S0141-3910(03)00167-8
  9. X. S. Wang, X. G. Li, and D. Yan, 'Thermal Decomposition Kinetics of Poly(trimethylene terephthalate)', Polymer Degradation and Stability, 2000, 69, 361-372 https://doi.org/10.1016/S0141-3910(00)00083-5
  10. H. Ohtani and S. Tsuge in 'Applied Pyrolysis Handbook', T. P. Wampler Ed., Marcel Dekker, N. Y., 1995, pp.97-124
  11. C. T. Vijayakumar and J. K. Fink, 'Pyrolysis Studies of Aromatic Polyester', Thermochimica Acta, 1982, 59, 51-61 https://doi.org/10.1016/0040-6031(82)87092-5
  12. Y. Sugimura and S. Tsuge, 'Studies on Thermal Degradation of Aromatic Polyesters by Pyrolysis-gas Chromatography', J Chromatogr Sci, 1979, 17, 269-272 https://doi.org/10.1093/chromsci/17.5.269
  13. H. Zimmermann and E. Leibnitz, 'Chemische Untersuchungen tiber Faserbildende Polyester', Faserforsch Textiltech, 1965, 16, 282-290
  14. L. H. Buxbaum, 'The Degradation of Poly(ethylene terephthalate)', Angew Chem Internat Ed., 1968, 7, 182-190 https://doi.org/10.1002/anie.196801821
  15. J. Devaux, P. Godard, and J. P. Mercier, 'Etude cinetigue de la degradation du Poly(oxytetra methyleneoxyterephtaloyle)', Makromol Chem, 1978, 179, 2201-2209 https://doi.org/10.1002/macp.1978.021790909