DOI QR코드

DOI QR Code

Case study of ozone photochemistry in the Seoul metropolitan area during the summer 2003

2003년 여름동안 서울지역에서의 오존의 광화학적 특성에 대한 사례 연구

  • Shon Zang-Ho (Department of Environmental Engineering, Dongeui University)
  • Published : 2005.08.01

Abstract

This study examines the local ozone photochemistry in the urban air. The photochemical formation and destruction of ozone was modeled using a photochemical box model. For the model prediction of ozone budget, measurements were carried out from an urban monitoring station in Seoul ($37.6^{\circ}N,\;127^{\circ}E$), Korea for intensive sampling time period (Jun. $1\~15$, 2003). Photochemical process is likely to play significant role in higher ozone concentrations during the sampling period. The results of model simulation indicated that photochemical ozone production pathway was the reaction of NO with $HO_2$ while ozone destruction was mainly controlled by a photochemical destruction pathway, a reaction of $H_2O$ with $O(^1D).$ The contribution of NMHCs to formation and destruction of ozone in the urban was significant. This was entirely different from remote marine environment. The rates of net photochemical ozone production ranged from 0.1 to 1.3 ppbv $h^{-1}$ during the study period.

Keywords

References

  1. Shon, Z. H. and N. Kim, 2002, A modeling study of halogen chemistry's role in marine boundary layer ozone, Atmos. Environ., 36, 4289-4298 https://doi.org/10.1016/S1352-2310(02)00426-0
  2. Shon, Z. H., K. H. Kim, K. Bower, G. Lee and J, Kim, 2004, Assessment of the photochemistry of OH and $NO_3$ on Jeju Island during the Asian Dust-Storm Period in the Spring of 2001, Chemo., 55, 1127-1142 https://doi.org/10.1016/j.chemosphere.2003.10.003
  3. Lurmann, F. W. and A. C. Lloyd, 1986, A chemical mechanism for use in long-range transport/acid deposition computer modeling, J. Geophys. Res., 91, 10905-10936 https://doi.org/10.1029/JD091iD10p10905
  4. Burden, R. L. and J. D. Faires, 1989, Numerical Analysis, PWS Kent, Boston
  5. Sander, S. P., D. M. Golden, M. J. Kurylo, G. K. Moortgat, A. R. Ravishankara, C. E. Kolb, M. J. Molina and B. Finlayson-Pitts, 2002, Chemical kinetics and photochemical data for use in atmospheric studies, Jet Prop. Lab. Pub., Pasadena, California, 02-25
  6. Madronich, S., 1987, Intercomparison of $NO_2$ photodissociation and UV radiometer measurement, Atmos. Environ., 21, 569-578 https://doi.org/10.1016/0004-6981(87)90039-4
  7. Shon, Z. H., 1999, Photochemical assessment of oceanic emissions of DMS and its oxidation to $SO_2$ based on airborne field observations, Ph.D. dissertation, Georgia Institute of Technology; Atlanta, GA, USA
  8. Liu, S. C, D. Kley, M. McFarland, J. D. Mahlman and H. Levy II, 1980, On the origin of tropospheric ozone, J. Geophys. Res., 85, 7546-7552 https://doi.org/10.1029/JC085iC12p07546
  9. Davis, D. J. Crawford, G. Chen, W. Chameides, S. Liu, J. Bradshaw, S. Sandholm, G. Sachse, G. Gregory, B. Anderson, J. Barrick, A. Bachmeider, J. Collins, E. Browell, D. Blake, S. Rowland, Y. Kondo, H. Singh, R. Talbot, B. Heikes, J. Merrill, J. Rodriguez and R E. Newell, 1996, Assessment of ozone photochemistry in the western North Pacific as inferred from PEM-West A observations during the fall 1991, J. Geophys. Res., 101, 2111-2134 https://doi.org/10.1029/95JD02755
  10. Seinfeld, J. H. and S. N. Pandis, 1998, In: Atmospheric Chemistry and Physics, Wiley Interscience, Canada

Cited by

  1. Photochemical Air Pollution of Seoul in the Last Three Decades vol.29, pp.4, 2013, https://doi.org/10.5572/KOSAE.2013.29.4.390