수열처리법에 의한 아프리카산 천연루비의 색상개선 및 특성평가

Color enhancement and characteristics of natural rubies originated in Africa by the hydrothermal treatment method

  • 박춘원 (동신대학교 보석공학과)
  • Park, Chun-Won (Department of Gemological Engineering, Dongshin University)
  • 발행 : 2005.08.01

초록

어두운 적색을 나타내는 아프리카산 천연루비의 색상개선을 열처리법과 수열처리법을 이용하여 행한 결과, 열처리법은 색상이 떨어지는 역효과가 발생하였다. 그러나 수열처리법의 경우에는 색상과 투명도가 향상되었다. 아프리카산 천연루비의 색상개선에 대한 수열처리 조건은 다음과 같다. 즉, 수열용매 1M $Na_2CO_3-0.9M\;K_2CO_3$, 반응온도: $450^{\circ}C$, 반응 시간: 48hrs, 충전율: $30\%$, 압력: 375atm이었다. 이와 같은 조건에서 얻어진 루비의 특성을 평가한 결과, ICP/MS와 XRF 분석결과로부터 수열처리 후 $Cr^{3+},\;Fe^{3+},\;Ti^{4+}$ 등의 함량이 수열처리 전의 루비에 비해 감소됨을 알 수 있었으며, 이로 인하여 적색이 밝아지는 것을 색차계 분석결과로부터 알았다. 이 결과는 수열처리 전과 비교하였을 때 $Cr^{3+}$ 이온의 전자전이에 의해 발생되는 발광피크의 강도가 수열처리 후 감소한 PL분석결과와 잘 일치하였다.

Color enhancement of African rubies with dark red was carried out by the heat treatment and the hydrothermal treatment method respectively. The heat treatment method brought about an adverse effect causing the color to be deteriorated. However, the hydrothermal treatment method enhanced its color and clarity. The hydrothermal treatment conditions for color enhancement of them were as follows: solvent: 0.9M $Na_2CO_3-1M\;K_2CO_3$, temperature: $450^{\circ}C$, duration: 48 hrs, filling: $30\%$, pressure: 375 atm. As the results of characteristics for African rubies obtained under these conditions, it was known that the amount of $Cr^{3+},\;Fe^{3+},\;Ti^{4+}$ was reduced after the hydrothermal treatment from the ICP/MS and XRF analyses. Also, it was found that the red color from the colorimeter analyses was getting lighter. These results were consistent with the PL analysis showing that the intensity of the luminescence peak generated by the electron transition of $Cr^{3+}$ ion became lower after the hydrothermal treatment compared with the non-treated rubies.

키워드

참고문헌

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