KIEE International Transactions on Electrophysics and Applications

대한전기학회 (The Korean Institute of Electrical Engineers)
권호 표지

Preparation and Electrochemical Characteristics of CNFs/DAAQ Electrode for Energy Storage

  • Kim Hong-Il (Dept. of Industrial Chemical Engineering, Chungbuk National University) ;
  • Kim Han-Joo (Dept. of Industrial Chemical Engineering, Chungbuk National University) ;
  • Choi Weon-Kyung (Engineering administration of Dankuk University) ;
  • Osaka Testuya (Department of Applied Chemisry, Waseda University) ;
  • Park Soo-Gil (Dept. of Industrial Chemical Engineering, Chunbuk National University)
  • 발행 : 2005.08.01
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초록

A new type of supercapacitor was constructed by using carbon nanofibers (CNFs) and DAAQ (l,5-diaminoanthraquinone) oligomer. DAAQ was deposited on the carbon nanofibers by chemical polymerization with ammonium peroxodisulfate (($NH_4)_2S_2O_8$) as oxidant in the 0.1 M $H_2SO_4$. Polymerization reaction was carried out with constant sonication. From the analysis, it is clear that surface of carbon nanofibers was quite uniformly coated with DAAQ. The performance characteristics of the supercapacitors have been evaluated using Cyclic Voltammetry. CNFs/DAAQ based composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system. CNFs/DAAQ composite electrode showed relatively good capacitance (7 Ah/kg) compared to conventional capacitors in the range of $-0.4\~0.4$.

키워드

참고문헌

  1. Y. Matsuda, K. Inoue, H. Takeuchi and Y. Okuhama, 'Gel polymer electrolytes for electric double layer capacitors', Solid-State Ionics, vol. 113-115, p.103, 1998
  2. S. Shiraishi, H. Kurihara, H. Tsubota, A. Oya, Y. Soneda and Y. Yamada, 'Electric Double Layer Capacitance of Highly Porous Carbon Derived from Lithium Metal and Polytetrafluoroethylene', Electrochem. Solid-State Lett., vol. 4, A4, 2001
  3. A. Rudge, I. Raistrick, S. Gottesfeld and J. P. Ferraris, 'A study of the electrochemical properties of conducting polymers for application in electrochemical capacitors', Electrochemica Acta, vol. 39, p. 273, 1994
  4. A. Rudge, J. Davey, I. Raistrick, S. Gottesfeld and J. P. Ferraris, 'Conducting polymers as active materials in electrochemical capacitors', J. Power Sources, vol. 47, p. 89, 1994
  5. S. Suematsu and K. Naoi, 'Quinone-introduced oligomeric supramolecule for supercapacitor', J. of Power Sources, vol. 97-98, p. 816, 2001 https://doi.org/10.1016/S0378-7753(01)00735-2
  6. H. Benaddi, T. J. Bandosz, J. Jagiello, J. A. Schwarz, J. N. Rouzaud, D. Legras and F. Beguin, 'Surface functionality and porosity of activated carbons obtained from chemical activation of wood', Carbon, vol. 38, p. 669, 2000
  7. E. Frackowiak, K. Jurewica, S. Delpeux, F. Beguin, 'Boronated mesophase pitch coke for lithium insertion', J. of Power Sources, vol. 97-98, p. 822, 2001 https://doi.org/10.1016/S0378-7753(01)00736-4
  8. Qiangfeng Xiao and Xiao Zhou, 'The study of multiwalled carbon nanotube deposited with conducting polymer for supercapacitor', Electrochemica Acta, vol. 48, p. 575, 2003 https://doi.org/10.1016/S0013-4686(03)00178-6
  9. Karla L. Strong, David P. Anderson, Khalid Lafdi and John N. Kuhn, 'Purification process for singlewall carbon nanotubes', Carbon, vol. 41, p. 1477, 2003
  10. L. Qian and X. Yang, 'Preparation and characterization of network composite film containing polyoxometallates and carbon nanotubes', Electrochemistry Communications, vol. 7, p. 547, 2005
  11. Xiaofeng Duan, Brahim Akdim and Ruth Pachter, 'A theoretical study of Cs adsorption at tips of singlewall carbon nanotubes: field emission properties', Applied Surface Science, vol. 243, p. 11, 2005
  12. R.K Gupta and I. Dwivedy, 'International patenting activity in the field of carbon nanotubes', Current Applied Physics, vol. 5, p. 163, 2005
  13. V.A. Margulis, O.V. Boyarkina and E.A. Gaiduk, 'Non-degenerate optical four-wave mixing in singlewalled carbon nanotubes', Optics Communications, vol. 249, p. 339, 2005
  14. H. Presting and U. Konig, 'Future nanotechnology developments for automotive applications', Materials Sci. and Eng.:C, vol. 23, p. 737, 2003
  15. S. Serphin, D. Zhou, J. jiao, M.A. Minke, S. Wang, T. Yadav and J. C. Withers, 'Catalytic role of nickel, palladium, and platinum in the formation of carbon nanoclusters', Chem. Phys. Lett., vol. 217, p. 191, 1994
  16. R. T. K. Baker, 'Catalytic growth of carbon filaments', Carbon, vol. 27, p. 315, 1989
  17. J. Hlavaty and L. Kavan, 'Modification of electrochemical carbon by in situ generated carbenes', Carbon, vol. 35, p. 127, 1997
  18. P. Chitrapu, C. R. F. Lund, J. A. Tsamopoulos, 'A model for the catalytic growth of carbon filaments', Carbon, vol. 30, p. 285, 1992
  19. H. S. Youna, H. Ryua, T. H. Cho, W. K. Choi, 'Purity enhancement and electrochemical hydrogen storage property of carbon nanofibers grown at low temperature', International Journal of Hydrogen Energy, vol. 27, p. 937, 2002
  20. W. K. Choi, S. G. Park, H. Takahashi, T. H. Cho, 'Purification of carbon nanofibers with hydrogen peroxide', Synthetic Metals, vol. 139, p. 39, 2003