Journal of the Korea Institute of Military Science and Technology (한국군사과학기술학회지)
- Volume 8 Issue 2 Serial No. 21
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- Pages.67-76
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- 2005
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- 1598-9127(pISSN)
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- 2636-0640(eISSN)
A study on the polymerization of energetic prepolymer(GDNPF)
에너지를 함유한 선 폴리머인 Prepolymer(GDNPF) 제조 공정 연구
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Cheun, Young-Gu
(ADD) ;
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Kim, Jin-Seuk
(ADD)
- Published : 2005.06.30
Abstract
We synthesized an energetic prepolymer(glycidyl dinitro propyl formal, GDNPF) for plastic-bonded explosive and measured its thermodynamic parameters. Glycidyl dinitro propyl formal(GDNPF) as an energetic monomer was epoxidized from allyl-2,2-dinitro propyl formal which is reacted with dinitro propyl alcohol and excess allyl alcohol, and then energetic polymer of GDNPF was polymerized by cationic ring opening polymerization. Thermodynamic parameters were obtained from the ceiling temperature(
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