Macromolecular Research

  • 제13권4호
  • /
  • Pages.297-305
  • /
  • 2005
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

The Compatibilizing Effect of Maleic Anhydride in Ethylene-Vinyl Acetate (EVA)/Ethylene-${\alpha}$-Olefin Copolymers Blends

  • Park, Soo-Chul (Department of Chemical Engineering, Inha University) ;
  • Choe, Soon-Ja (Department of Chemical Engineering, Inha University)
  • 발행 : 2005.08.31
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초록

The compatibilizing effect of maleic anhydride (MA) in the immiscible blends of EVA22 (vinyl acetate content 22%)/ethylene-${\alpha}$-olefin copolymers with 1-butene (EtBC) and 1-octene (EtOC)) comonomers was studied. By adding 1, 2, and 3 phr of MA in the presence of dicumylperoxide, the morphology, tensile strength at break, and 100 and 300 % modulus of EVA22/EtBC and EVA22/EtOC blends were significantly enhanced. The melting point and crystallization point depression were observed upon the addition of MA. The changes in the ${\beta}$ transition and glass transition temperature of ethylene-${\alpha}$-olefin copolymers and ethylene-vinyl acetate copolymers, respectively, indicate that MA plays a role of compatibilizer for these immiscible blends. The TGA thermograms, measured from the blends with MA, show that thermal stability is slightly enhanced with MA, indicating that MA acts as a reinforcing agent either by grafting or crosslinking with other copolymers.

키워드

참고문헌

  1. L. A. Utraki, in Polymer Alloys and Blends, New York, Hanser Pub., 1989
  2. U. Sundararaj and C. W. Macosko, Macromolecules, 12, 517 (1995)
  3. A. Arsac, C. Carrot, and J. Guillet, J. Appl. Polym. Sci., 74, 625 (1999)
  4. M. Shimoyama, S. Hayano, K. Matsukawa, H. Innoue, T. Ninomiya, and Y. Ozaki, J. Polym. Sci., Polym. Phys., 36, 1529 (1998) https://doi.org/10.1002/(SICI)1099-0488(19980715)36:9<1529::AID-POLB10>3.0.CO;2-7
  5. M. Xanthos and S. S. Dagli, Polym. Eng. Sci., 31, 929 (1991) https://doi.org/10.1002/pen.760311302
  6. M. A. Lopez-Manchado, M. Valle, R. Sapunar, and R. Quijada, J. Appl. Polym. Sci., 92, 3008 (2004) https://doi.org/10.1002/app.20220
  7. M. A. Rodriguez-Perez, A. Duijsens, and J. A. de Saja, J. Appl. Polym. Sci., 68, 1237(1998) https://doi.org/10.1002/(SICI)1097-4628(19980523)68:8<1237::AID-APP5>3.0.CO;2-E
  8. J. Peon, J. F. Vega, M. Aroca, and J. Martinez-Salaza, Polymer, 44, 8093 (2001)
  9. J. Peon, M. Aguilar, J. F. Vega, B. Del Amo, and J. Martinez-Salazar, Polymer, 44, 1589 (2001) https://doi.org/10.1016/S0032-3861(02)00941-2
  10. J. Peon, J. F. Vega, B. Del Amo, and J. Martinez-Salazar, Polymer, 44, 2911 (2003) https://doi.org/10.1016/S0032-3861(03)00176-9
  11. M. Kontopoulou, L. C. Huang, and J. A. Lee, Adv. Polym. Tech., 22, 209 (2003) https://doi.org/10.1002/adv.10049
  12. M. Kontopoulou and L. C. Huang, J. Appl. Polym. Sci., 94, 881 (2004) https://doi.org/10.1002/app.20913
  13. S. Park, C. Yim, B. H. Lee, and S. Choe, Macromole. Res., 13, 243 (2005) https://doi.org/10.1007/BF03219059
  14. S. J. Kim, C. J. Kang, S. R. Chowdhur, W. J. Cho, and C. S. Ha, J. Appl. Polym. Sci., 89, 1305 (2003) https://doi.org/10.1002/app.12245
  15. S. J. Kim, B. S. Shin, J. L. Hong , W. J. Cho, and C. S. Ha, Polymer, 42, 4073 (2001) https://doi.org/10.1016/S0032-3861(00)00352-9