Bulletin of the Korean Chemical Society

  • 제26권8호
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  • Pages.1219-1224
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Lead(II)-selective Polymeric Electrode Using a Schiff Base Complex of N,N'-Bis-thiophene-2-ylmethylene-ethane-1,2-diamine as an Ion Carrier

  • Jeong, Tae-Jun (Department of Chemistry and the Institute of Basic Science, Chonnam National University) ;
  • Jeong, Dae-Cheol (Department of Chemistry and the Institute of Basic Science, Chonnam National University) ;
  • Lee, Hyo-Kyoung (Department of Chemistry and the Institute of Basic Science, Chonnam National University) ;
  • Jeon, Seung-Won (Department of Chemistry and the Institute of Basic Science, Chonnam National University)
  • 발행 : 2005.08.20
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초록

We prepared lead ion-selective PVC membranes that were based on N,N'-bis-thiophene-2-ylmethylene-ethane-1,2-diamine as a membrane carrier. The membrane electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-5}$ and 1.0 ${\times}$ $10^{-1}$ M with a Nernstian slope of 29.79 mV per decade, and its detection limit was 2.04 ${\times}$ $10^{-6}$ M at room temperature. The potentiometric response is independent of the pH of the solution in the pH range of 5-7. The proposed electrode revealed good selectivity and response for $Pb^{2+}$ over a wide variety of other metal ions in pH 5.0 buffer solutions, and there was good reproducibility of the base line on the subsequent measurements. The membrane electrode has a relatively fast response time, satisfactory reproducibility and a relatively long life time.

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  2. Developments in the Field of Conducting and Non-conducting Polymer Based Potentiometric Membrane Sensors for Ions Over the Past Decade vol.8, pp.4, 2008, https://doi.org/10.3390/s8042331
  3. Influence of Multiwalled Carbon Paste Nanotubes on Response of ${\rm Pb}^{2+}$ Ion Selective Carbon Paste Electrode Based on 2-((6-(5-Bromo-2-Hydroxybenzylideneamino) Hexylimino) Methyl)-4-Bromophenol as Novel Neutral Carrier vol.11, pp.10, 2011, https://doi.org/10.1109/JSEN.2011.2126042
  4. Coated wire lead(II)-selective electrode based on a Schiff base ionophore for low concentration measurements vol.143, pp.2, 2012, https://doi.org/10.1007/s00706-011-0634-z
  5. Lead(II) ion selective poly(aniline) solid contact electrode based on 1,2-bis(N′-benzoylthioureido)ethane, -propane and -butane ionophores vol.70, pp.5, 2015, https://doi.org/10.1134/S1061934815050172
  6. Determination of lead ions using an diantipyrylmethane-based electrode vol.71, pp.11, 2016, https://doi.org/10.1134/S1061934816110149
  7. Polymeric Lead(II)-selective Electrode Based on N,N'-Bis-thiophen-2-ylmethylene-pyridine-2,6-diamine as an Ion Carrier vol.28, pp.4, 2005, https://doi.org/10.5012/bkcs.2007.28.4.538
  8. Nitrogen-Bearing Organic Compounds as Carriers for Lead Ion-Selective Electrodes with Excellent Response vol.36, pp.12, 2005, https://doi.org/10.1016/s1872-2040(09)60011-6
  9. An organically modified sol–gel membrane for detection of lead ion by using 2-hydroxy-1-naphthaldehydene-8-aminoquinoline as fluorescence probe vol.130, pp.2, 2005, https://doi.org/10.1016/j.snb.2007.10.041
  10. Lead-selective poly(vinyl chloride) electrodes based on some synthesized benzo-substituted macrocyclic diamides vol.172, pp.1, 2009, https://doi.org/10.1016/j.jhazmat.2009.06.145