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Lead(II)-selective Polymeric Electrode Using a Schiff Base Complex of N,N'-Bis-thiophene-2-ylmethylene-ethane-1,2-diamine as an Ion Carrier

  • Jeong, Tae-Jun (Department of Chemistry and the Institute of Basic Science, Chonnam National University) ;
  • Jeong, Dae-Cheol (Department of Chemistry and the Institute of Basic Science, Chonnam National University) ;
  • Lee, Hyo-Kyoung (Department of Chemistry and the Institute of Basic Science, Chonnam National University) ;
  • Jeon, Seung-Won (Department of Chemistry and the Institute of Basic Science, Chonnam National University)
  • Published : 2005.08.20

Abstract

We prepared lead ion-selective PVC membranes that were based on N,N'-bis-thiophene-2-ylmethylene-ethane-1,2-diamine as a membrane carrier. The membrane electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-5}$ and 1.0 ${\times}$ $10^{-1}$ M with a Nernstian slope of 29.79 mV per decade, and its detection limit was 2.04 ${\times}$ $10^{-6}$ M at room temperature. The potentiometric response is independent of the pH of the solution in the pH range of 5-7. The proposed electrode revealed good selectivity and response for $Pb^{2+}$ over a wide variety of other metal ions in pH 5.0 buffer solutions, and there was good reproducibility of the base line on the subsequent measurements. The membrane electrode has a relatively fast response time, satisfactory reproducibility and a relatively long life time.

Keywords

References

  1. Abbaspour, A.; Khajeh, B. Anal. Sci. 2002, 18, 987 https://doi.org/10.2116/analsci.18.987
  2. Gupta, V. K.; Mangla, R.; Agarwal, S. Electroanalysis 2002, 14, 1127 https://doi.org/10.1002/1521-4109(200208)14:15/16<1127::AID-ELAN1127>3.0.CO;2-7
  3. Rouhollahi, A.; Ganjali, M. R.; Shamsipur, M. Talanta 1998, 46, 1341 https://doi.org/10.1016/S0039-9140(97)00421-9
  4. Zareh, M. M.; Ghoneim, A. K.; Abd El-Aziz, M. H. Talanta 2001, 54, 1049 https://doi.org/10.1016/S0039-9140(01)00340-X
  5. Lu, J.; Chen, R.; He, X. Talanta 2002, 528, 33
  6. Tavakkoli, N.; Khojasteh, Z.; Sharghi, H.; Shamsipur, M. Anal. Chim. Acta 1998, 360, 203 https://doi.org/10.1016/S0003-2670(97)00685-5
  7. Ohki, A.; Kim, J. S.; Suzuki, Y.; Hayashita, T.; Maeda, S. Talanta 1997, 44, 1131 https://doi.org/10.1016/S0039-9140(97)00021-0
  8. Abbaspour, A.; Tavakol, F. Anal. Chim. Acta 1999, 378, 145 https://doi.org/10.1016/S0003-2670(98)00520-0
  9. Mousavi, M. F.; Sahari, S.; Alizadeh, N.; Shamsipur, M. Anal. Chim. Acta 2000, 414, 189 https://doi.org/10.1016/S0003-2670(00)00818-7
  10. Shamsipur, M.; Ganjali, M. R.; Rouhollahi, A. Anal. Sci. 2001, 17, 935
  11. Casado, M.; Daunert, S.; Valiente, M. Electroanalysis 2001, 13, 54 https://doi.org/10.1002/1521-4109(200101)13:1<54::AID-ELAN54>3.0.CO;2-1
  12. Sadeghi, S.; Dashti, G. R.; Shamsipur, M. Sensors and Actuators B 2002, 81, 223 https://doi.org/10.1016/S0925-4005(01)00956-X
  13. Srivastava, S. K.; Gupta, V. K.; Jain, S. Analyst 1995, 120, 495 https://doi.org/10.1039/an9952000495
  14. Riahi, S.; Mousavi, M. F.; Shamsipur, M.; Sharghi, H. Electroanalysis 2003, 19, 1561
  15. Fathi, M. R.; Darviche, F.; Ganjali, M. R. Anal. Lett. 2000, 30, 1025
  16. Mousavi, M. F.; Barzegar, M. B.; Sahari, S. Sensors and Actuators B 2001, 73, 199 https://doi.org/10.1016/S0925-4005(00)00698-5
  17. Xu, D.; Kastu, T. Anal. Chim. Acta 1999, 401, 111 https://doi.org/10.1016/S0003-2670(99)00496-1
  18. Cadogan, F.; Kane, P.; McKervey, M. A.; Diamond, D. Anal. Chem. 1999, 71, 5544 https://doi.org/10.1021/ac990303f
  19. Rouhollahi, A.; Ganjali, M. R.; Shamsipur, M. Talanta 1998, 46, 1341 https://doi.org/10.1016/S0039-9140(97)00421-9
  20. Lee, H. K.; Song, K. J.; Seo, H. R.; Choi, Y.-K.; Jeon, S. Sensors and Actuators B 2004, 99, 323 https://doi.org/10.1016/j.snb.2003.11.029
  21. Liu, J.; Masuda, Y.; Sekido, E. Bull. Chem. Soc. Japan 1990, 63, 2516 https://doi.org/10.1246/bcsj.63.2516
  22. Kormali, E.; Kilic, E. Talanta 2002, 58, 793 https://doi.org/10.1016/S0039-9140(02)00364-8
  23. Ganjali, M. R.; Golmohammadi, M.; Yousefi, M.; Norouzi, P.; Salavati-Niasari, M.; Javanbakht, M. Anal. Sci. 2003, 19, 223 https://doi.org/10.2116/analsci.19.223
  24. Oshima, S.; Hirayama, N.; Kubono, K.; Kokusen, H.; Honjo, T. Anal. Sci. 2002, 18, 1351 https://doi.org/10.2116/analsci.18.1351
  25. Ganjali, M. R.; Emami, M.; Salavati-Niasari, M. Bull. Korean Chem. Soc. 2002, 23, 1394 https://doi.org/10.5012/bkcs.2002.23.10.1394
  26. Alizadeh, N.; Ershad, S.; Naeimi, H.; Sharghi, H.; Shamsipur, M.; Fresenius, J. Anal. Chem. 1999, 365, 511 https://doi.org/10.1007/s002160051514
  27. Gupta, K. C.; D'Arc, M. J. Sensors and Actuators B 2000, 62, 171 https://doi.org/10.1016/S0925-4005(99)00362-7
  28. Gupta, K. C.; D'Arc, M. J. Anal. Chim. Acta 2001, 437, 199 https://doi.org/10.1016/S0003-2670(01)00995-3
  29. Ganjali, M. R.; Poursaberi, T.; Babaei, L. H.; Rouhani, S.; Yousefi, M.; Kargar-Razi, M.; Moghimi, A.; Aghabozorg, H.; Shamsipur, M. Anal. Chim. Acta 2001, 440, 81 https://doi.org/10.1016/S0003-2670(01)01051-0
  30. Poursaberi, T.; Babaei, L. H.; Yousefi, M.; Rouhani, S.; Shamsipur, M.; Kargar-Razi, M.; Moghimi, A.; Aghabozorg, H.; Ganjali, M. R. Electroanalysis 2001, 13, 1513 https://doi.org/10.1002/1521-4109(200112)13:18<1513::AID-ELAN1513>3.0.CO;2-X
  31. Sadeghi, S.; Eslahi, M.; Naseri, M. A.; Naeimi, H.; Sharghi, H.; Shameli, A. Elecroanalysis 2003, 15, 1327 https://doi.org/10.1002/elan.200302807
  32. Abbaspour, A.; Esmaeilbeig, A. R.; Jarrahpour, A. A.; Khajeh, B.; Kia, R. Talanta 2002, 58, 397 https://doi.org/10.1016/S0039-9140(02)00290-4
  33. Mashhadizadeh, M. H.; Sheikhshoaie, I. Talanta 2003, 60, 73 https://doi.org/10.1016/S0039-9140(03)00036-5
  34. Mashhadizadeh, M. H.; Sheikhshoaie, I.; Saeid-Nia, S. Sensors and Actuators B 2003, 94, 241 https://doi.org/10.1016/S0925-4005(03)00449-0
  35. Mahajan, R. K.; Kaur, I.; Kumar, M. Sensors and Actuators B 2003, 91, 26 https://doi.org/10.1016/S0925-4005(03)00062-5
  36. Mahajan, R. K.; Kaur, I.; Sharma, V.; Kumar, M. Sensors 2002, 2, 417 https://doi.org/10.3390/s21000417
  37. Mahajan, R. K.; Kumar, M.; Sharma, V.; Kaur, I. Analyst 2001, 126, 505 https://doi.org/10.1039/b008944n
  38. Ganjali, M. R.; Emami, M.; Rezapour, M.; Shamsipur, M.; Maddah, B.; Salavati-Niasari, M.; Hosseini, M.; Talebpoui, Z. Anal. Chim. Acta 2003, 495, 51 https://doi.org/10.1016/S0003-2670(03)00921-8
  39. Mashhadizadeh, M. H.; Sheikhshoaie, I. Anal. Bioanal. Chem. 2003, 375, 708
  40. Ganjali, M. R.; Daftani, A.; Nourozi, P.; Salavati-Niasari, M. Anal. Lett. 2003, 36, 1511 https://doi.org/10.1081/AL-120021533
  41. Ardakany, M. M.; Ensafi, A. A.; Naeimi, H.; Dastanpour, A.; Shamlli, A. Sensors and Actuators B 2003, 96, 441 https://doi.org/10.1016/S0925-4005(03)00598-7
  42. Arida, H. A.; El-Reefy, S. A.; El-Saied, A. M. Anal. Sci. 2003, 19, 687 https://doi.org/10.2116/analsci.19.687
  43. Jeong, T.; Lee, H. K.; Jeong, D. C.; Jeon, S. Talanta 2005, 65, 543 https://doi.org/10.1016/j.talanta.2004.07.016
  44. Karthikeyan, G.; Pitchaimani, P. Transition Metal Chem. 2003, 28, 482 https://doi.org/10.1023/A:1023661228709
  45. Panda, C. R.; Nayak, S. C.; Chakravorthy, V.; Dash, K. C. Ind. J. Chem. 1985, 24A, 141
  46. Ramesh, R.; Suganthy, P. K.; Natarajan, K. Synth. Reac. Inorg. Met.-Org. Chem. 1996, 26, 47 https://doi.org/10.1080/00945719608004245
  47. Koryta, J.; Stulik, K. Ion-Selective Electrodes; Cambridge University Press: New York, 1983

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