Bulletin of the Korean Chemical Society

  • 제26권5호
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  • Pages.786-790
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis and Structure of a Second Polymorph of Strontium Germanium Nitride: β-Sr2GeN2

  • Park, Dong-Gon (Department of Chemistry, Sookmyung Women's University) ;
  • Gal, Zoltan A. (Baker Laboratory, Department of Chemistry, Cornell University) ;
  • DiSalvo, Francis J. (Baker Laboratory, Department of Chemistry, Cornell University)
  • 발행 : 2005.05.20
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초록

A new ternary strontium germanium nitride, ${\beta}-Sr_2GeN_2$, was obtained as single crystal from constituent elements in molten Na. It crystallizes in space group Cmca (No. 64) with a = 5.441(1) $\AA$, b = 11.377(2) $\AA$, c = 12.229(2) $\AA$, and Z = 8. Its crystal structure is closely related to that of polymorphic companion, ${\alpha}-Sr_2GeN_2$, both of which contain isolated bent anions of ${GeN_2}^{4-}$.

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참고문헌

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