DOI QR코드

DOI QR Code

Imaging and Manipulation of Benzene Molecules on Si Surfaces Using a Variable-low Temperature Scanning Tunneling Microscope

  • Hahn, J. R. (Department of Chemistry, Chonbuk National University)
  • Published : 2005.07.20

Abstract

A variable-low temperature scanning tunneling microscope (VT-STM), which operates from 77 to 350 K in ultrahigh vacuum, was built and used to study imaging and manipulation of benzene molecules on Si surfaces. Four types of benzene adsorption structures were first imaged on the Si(5 5 12)-2x1 surface. Desorption process of benzene molecules by tunneling electrons was studied on the Si(001)-2xn surface.

Keywords

References

  1. Binnig, G.; Rohrer, H.; Gerber, C.; Weible, E. Phys. Rev. Lett. 1982, 49, 57 https://doi.org/10.1103/PhysRevLett.49.57
  2. Lee, H. J.; Ho, W. Science 1999, 286, 1719 https://doi.org/10.1126/science.286.5445.1719
  3. Stipe, B. C.; Rezaei, M. A.; Ho, W. Science 1998, 280, 1732 https://doi.org/10.1126/science.280.5370.1732
  4. Hahn, J. R.; Lee, H. J.; Ho, W. Phys. Rev. Lett. 2000, 85, 1914 https://doi.org/10.1103/PhysRevLett.85.1914
  5. Stipe, B. C. et al. Phys. Rev. Lett. 1997, 78, 4410 https://doi.org/10.1103/PhysRevLett.78.4410
  6. Dujardin, G.; Walkup, R. E.; Avouris, Ph. Science 1992, 255, 1232 https://doi.org/10.1126/science.255.5049.1232
  7. Hofer, W.; Fisher, A. J.; Lopinski, G. P.; Wolkow, R. A. Phys. Rev. B 2001, 63, 085314 https://doi.org/10.1103/PhysRevB.63.085314
  8. Silvestrelli, P. L.; Ancilotto, F.; Toigo, F. Phys. Rev. B 2000, 62, 1956
  9. Alavi, S. et al. Phys. Rev. Lett. 2000, 85, 5372 https://doi.org/10.1103/PhysRevLett.85.5372
  10. Borovsky, B.; Krueger, M.; Ganz, E. Phys. Rev. B 1998, 57, R4269 https://doi.org/10.1103/PhysRevB.57.R4269
  11. Gokhale, S. et al. J. Chem. Phys. 1998, 108, 5554 https://doi.org/10.1063/1.475945
  12. Lopinski, G. P.; Moffatt, D. J.; Wolkow, R. A. Chem. Phys. Lett. 1998, 282, 305 https://doi.org/10.1016/S0009-2614(97)01317-1
  13. Kong, M. J.; Teplyakov, A. V.; Lyubovitsky, J. G.; Bent, S. F. Surf. Sci. 1998, 411, 286 https://doi.org/10.1016/S0039-6028(98)00336-7
  14. Jeong, S.; Jeong, J.; Cho, S.; Seo, J. M. Surf. Sci. 2004, 557, 183 https://doi.org/10.1016/j.susc.2004.03.040
  15. Cho, S.; Seo, J. M. Surf. Sci. 2004, 565, 14 https://doi.org/10.1016/j.susc.2004.07.004
  16. The STM is a variation of the one described in Stipe, B. C.; Rezaei, M. A.; Ho, W. Rev. Sci. Instrum. 1999, 70, 137 https://doi.org/10.1063/1.1149555
  17. Lauhon, L. J.; Ho, W. Rev. Sci. Instrum. 2001, 72, 216 https://doi.org/10.1063/1.1327311
  18. Besocke, K. Surf. Sci. 1987, 181, 145 https://doi.org/10.1016/0039-6028(87)90151-8
  19. Frohn, J.; Wolf, J. F.; Besocke, K.; Teske, M. Rev. Sci. Instrum. 1989, 60, 1200 https://doi.org/10.1063/1.1140287
  20. Koo, J.-Y. et al. Phys. Rev. B 1995, 52, 17269
  21. Kato, K. et al. Surf. Sci. 1988, 194, L87 https://doi.org/10.1016/0039-6028(94)91238-6
  22. Aruga, T.; Murata, Y. Phys. Rev. B 1986, 34, 5654 https://doi.org/10.1103/PhysRevB.34.5654
  23. Hahn, J. R. to be published
  24. Stroscio, J. A.; Eigler, D. M. Science 1991, 254, 1319 https://doi.org/10.1126/science.254.5036.1319

Cited by

  1. Adsorption Structures of 2,3-Butanediol on Si(001) vol.111, pp.1, 2007, https://doi.org/10.1021/jp064078z
  2. Adsorption Site Selectivity for Thiophene on Reconstructed Si(5 5 12)–2 × 1 Surface vol.117, pp.21, 2013, https://doi.org/10.1021/jp401932r
  3. Direct observation of the conformational transitions of single pyridine molecules on a Ag(110) surface induced by long-range repulsive intermolecular interactions vol.146, pp.1, 2017, https://doi.org/10.1063/1.4973379
  4. Theoretical Study of Scanning Probe Microscope Images of VTe2 vol.28, pp.1, 2005, https://doi.org/10.5012/bkcs.2007.28.1.081
  5. Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007 vol.29, pp.2, 2008, https://doi.org/10.5012/bkcs.2008.29.2.450
  6. Spatially inhomogeneous inelastic electron tunneling in oxygen-ethylene complexes on Ag(110) resolved with a scanning tunneling microscope vol.80, pp.16, 2005, https://doi.org/10.1103/physrevb.80.165428
  7. Role of molecular orientation in vibration, hopping, and electronic properties of single pyridine molecules adsorbed on Ag(110) surface: A combined STM and DFT study vol.604, pp.3, 2005, https://doi.org/10.1016/j.susc.2009.11.014
  8. Role of Coverage and Vacancy Defect in Adsorption and Desorption of Benzene on Si(001)-2×n Surface vol.31, pp.1, 2005, https://doi.org/10.5012/bkcs.2010.31.01.162
  9. Pairing of (R,R)-2,3-Butanediol Molecules on a Si(001) Surface vol.114, pp.41, 2005, https://doi.org/10.1021/jp106099w