Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Characterization, and Absorption Spectra of Metallamacrocycles, [Pd{α,ω-bis(diphenylphosphino)oligothienylene}Cl2]2

  • Kang, Dong-Min (Department of Chemistry and Research Institute of Life Science, Gyeongsang National University) ;
  • Kim, Sam-Gon (Department of Chemistry and Research Institute of Life Science, Gyeongsang National University) ;
  • Lee, Sung-Joong (Department of Chemistry and Research Institute of Life Science, Gyeongsang National University) ;
  • Park, Jong-Keun (Department of Chemistry Education and Research Institute of Basic Science, Gyeongsang National University) ;
  • Park, Ki-Min (Research Institute of Basic Science, Gyeongsang National University) ;
  • Shin, Sung-Chul (Department of Chemistry and Research Institute of Life Science, Gyeongsang National University)
  • Published : 2005.09.20
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Abstract

Dimeric metallamacrocycles of 2 : 2 (metal-to-ligand) stoichiometry, [Pd{${\alpha},{\omega}$-bis(diphenylphosphino)oligothienylene}$Cl_2]_2$ 1-3 were prepared from a self-assembly reaction of $[Pd(CH_3CN)_2Cl_2]$ and ${\alpha},{\omega}$-bis-(diphenylphosphino)oligothienylene in 90-94% yields. The structures of metallamacrocycles 1-3 were determined by X-ray diffraction. 1 crystallizes in the monoclinic space group $P2_1$/n with a/$\AA$ = 12.0737(13), b/$\AA$ = 17.1993(18), c/$\AA$ = 13.0951(14) and ${\beta}/^{\circ}$ = 101.505(2). 2 crystallizes in the triclinic space group P with a/$\AA$ = 10.2634(4), b/$\AA$ = 19.7855(9), c/$\AA$ = 21.0851(9), ${\alpha}/^{\circ}$ = 63.1010(10), ${\beta}/^{\circ}$ = 86.5880(10), ${\gamma}/^{\circ}$ = 81.2280(10). 3 crystallizes in the triclinic space group P with a/$\AA$ = 10.4353(19), b/$\AA$ = 13.482(3), c/$\AA$ = 13.816(3), ${\alpha}/^{\circ}$ = 108.027(4), ${\beta}/^{\circ}$ = 90.461(4), ${\gamma}/^{\circ}$ = 93.261(4). The UV spectra of 1-3 were characterized.

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