Bulletin of the Korean Chemical Society

  • 제26권2호
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  • Pages.292-296
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Studies on the Properties of Thexylboronic Acid and Its Derivatives

  • Cha, Jin-Soon (Department of Chemistry, Yeungnam University) ;
  • Brown, Herbert C. (The H. C. Brown & R. B. Wetherill Laboratories of Chemistry, Purdue University)
  • 발행 : 2005.02.20
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초록

Physical and chemical properties of thexylboronic acid and its derivatives such as thexylboroxine and ethylene glycol or diethanolamine thexylboronic ester have been studied. Thexylboronic acid can be extracted from an organic solution with an aqueous sodium hydroxide solution as an “te”complex. It is readily converted into thexylboroxine in the presence of anhydrous magnesium sulfate in pentane. It reacts with simple alcohols only slowly; however, it reacts readily with excess diethanolamine in the presence of anhydrous magnesium sulfate to give the corresponding ester.

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참고문헌

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피인용 문헌

  1. Thirty Six Years of Research on the Selective Reduction and Hydroboration vol.32, pp.6, 2011, https://doi.org/10.5012/bkcs.2011.32.6.1808
  2. Dioxazaborocanes: old adducts, new tricks vol.9, pp.13, 2011, https://doi.org/10.1039/c1ob05330b
  3. Regioisomeric and Substituent Effects upon the Outcome of the Reaction of 1-Borodienes with Nitrosoarene Compounds vol.80, pp.13, 2015, https://doi.org/10.1021/acs.joc.5b00593