DOI QR코드

DOI QR Code

Effect of DyFeO3 Addition on Crystal Structure and Ferrcelectricity of the BiFeO3-PbTiO3 System

  • Kim, Seong-Seog (Department of Digital Display Engineering, Hoseo University) ;
  • Kwon, Jong-Uk (Department of Digital Display Engineering, Hoseo University) ;
  • Cheon, Chae Il (Department of Materials Science add Engineering, Hoseo University)
  • Published : 2005.05.01

Abstract

The crystal structure and ferroelectricity of the $(1-x)BiFeO_3\;(BF)-xPbTiO_3$ (PT) ceramic system with the addition of $DyFeO_3$ (DF) have been investigated for attaining a high temperature piezoelectric material. This study is focused on the relation between crystal structure and ferroelectric property with the addition of DF over the phase boundary in the (1-x)BF-xPT system. Hysteresis curves of polarization-electric field at room temperature have been measured. The X-ray and neutron diffraction data were analyzed by the rietveld refinement method. The addition of 0.1 mole DF into BF-PT system greatly increases the ferroelectric remanant polarization Pr values, e.g. 17 ${\mu}C/cm^2$ in 0.6BF-yDF-(0.4-y)PT and 31${\mu}C/cm^2$ in 0.5BF-yDF-(0.5.y)PT, respectively. The improved Pr value has been discussed in relation with crystal structure and electrical property.

Keywords

References

  1. I. Sosnowska, T. Peterlin-Neumaier, and E. Strichele, 'Spiral Magnetic Ordering in Bismuth Ferrite,' J. Phys. C: Solid State Phys., 15 4835-46 (1982) https://doi.org/10.1088/0022-3719/15/23/020
  2. S. V. Kiselev, R. P. Ozerov, and G. S. Zhdanov, ' Detection of Magnetic Order in Ferroelectric $BiFeO_3$ by Neutron Diffraction,' Sov. Phys.-Doklady, 7 [8] 742-44 (1963).
  3. F. Kubel and H. Schmid, 'Structure of a Ferroelectric and Ferroelastic Monodomain Crystal of the Perovskite $BiFeO_{3}$,' Acta Cryst., B46 698-702 (1990)
  4. J. R. Teague, R. Gerson, and W. J. James, 'Dielectric Hysteresis in Single Crystal $BiFeO_{3}$' Solid State Commun., 8 1073-74 (1970) https://doi.org/10.1016/0038-1098(70)90262-0
  5. J. Wang, J. B. Neaton, H. Zheng, V. Nagarajan, S. B. Ogale, B. Lie, D. Vieland, V. Vaithyanathan, D. G. Sholm, U. V. Waghmare, N. A. Spaldin, K. M. Rabe, M. Wuttig, and R. Ramesh, ' Epitaxial $BiFeO_{3}$ Multiferroic Thin Film Hetero-structures,' Science, 229 1719-22(2003)
  6. S. A. Fedulov, P. B. Ladyzhinskii, I. L. Pyatigorskaya, and Y. N. Venevtsev, ' Complete Phase Diagram of the $PbTiO_{3}$- $BiFeO_{3}$ System,' Sov. Phys.-Sol. St., 6 [2] 375-78 (1964)
  7. R. T. Smith, G. D. Achenbach, R. Gerson, and W. J. James, ' Dielectric Properties of Solid Solutions of $BiFeO_{3}$ with $Pb(Ti, Zr)O_{3}$ at High Temperature and High Frequency,' J. Appl. Phys., 39 [1] 70-4 (1968) https://doi.org/10.1063/1.1655783
  8. J. S. Kim, C. I. Cheon, Y. N. Choi, and P. W. Jang, 'Ferro- electric and Ferromagnetic Properties of $BiFeO_{3}$-$PrFeO_{3}$- $PbTiO_{3}$ Solid Solutions,' J. Appl. Phys., 93 9263-70 (2003) https://doi.org/10.1063/1.1567818
  9. W. P. Wolf and R. L. White, ' Rare-Earth Compounds,' J. Appl. Phys., 40 [3] 1061-69 (1969) https://doi.org/10.1063/1.1657530
  10. C. I. Cheon and J. S. Kim, ' Ferroelectric Properties of Ti-Doped and W-Doped SBT Ceramics(in Korean),' J. Kor. Ceram. Soc., 41 [5] 401-05 (2004) https://doi.org/10.4191/KCERS.2004.41.5.401
  11. C. I. Cheon and H. G. Kim, ' Ferroelectric Domain Structure and Array of Tetragonal and Rhombohedral Phase in PZT Ceramics at MPB Composition(in Korean),' J. Kor. Ceram. Soc., 30 [11] 919-24 (1993)
  12. D. M. Kim, J. S. Kim, and C. I. Cheon, ' Effects of Particle Size on Properties of PZT-Based Thick Films(in Korean),' J. Kor. Ceram. Soc., 41 [5] 375-80 (2004) https://doi.org/10.4191/KCERS.2004.41.5.375
  13. H. T. Chung and H. G. Kim, ' The Effects of Tetragonality to the Physical Properties of PZT(in Korean),' J. Kor. Ceram. Soc., 24 [1] 56-62 (1987)
  14. T. Yamamoto, K. Okazaki, M. L. Dass, and G. Thomas, ' Microstructure and the Dielectric Properties at the Morphotropic Phase Boundary (MPB) of $PbTiO_{3}$-$PbZrO_{3}$ System,' Ferroelectrics, 81 331-34 (1988) https://doi.org/10.1080/00150198808008875